Method and apparatus for producing dispersion

Patent metadata

Field	Value
Publication number	US-10086353-B2
Application number	US-201515506606-A
Country	US
Kind code	B2
Filing date	Aug 21, 2015
Priority date	Aug 28, 2014
Publication date	Oct 2, 2018
Grant date	Oct 2, 2018

Abstract

A method and an apparatus for producing a dispersion, which enable high-speed and highly-efficient production of a dispersion of a reaction product having desired properties, are provided. The present invention relates to such a method and an apparatus for producing a dispersion. In the method and the apparatus, a first substance is dissolved or dispersed in a first liquid, a second substance is dissolved or dispersed in a second liquid or a low dielectric liquid, a phase of the second liquid and a phase of the low dielectric liquid are one on top of the other in such a manner that the two phases are separated from each other, a spray port of a nozzle is disposed in the low dielectric liquid phase, or is disposed at a position apart from the two phases but close to the low dielectric liquid phase in such a manner that the spray port is oriented to a liquid surface of the low dielectric liquid phase, and an electrode is disposed in the second liquid phase. In these states, droplets of the first liquid in which the first substance is dissolved or dispersed, are charged by generating a potential difference between the nozzle and the electrode, and are electrostatically sprayed from the spray port of the nozzle. In the method and the apparatus, the first liquid which was electrostatically sprayed, passes through the phase of the low dielectric liquid and reaches the phase of the second liquid so that the reaction product is dispersed in the second liquid phase or in the low dielectric liquid phase.

First claim

The invention claimed is:

1. A method for producing a dispersion of a reaction product between first and second substances, the method comprising the step of:
electrostatically spraying the first substance which is dissolved or dispersed in a first liquid, from a spray port of a nozzle which is:
disposed in a phase of a low dielectric liquid out of two phases of a phase of a second liquid and the phase of the low dielectric liquid arranged one on top of the other with two-phase separation; or
disposed at a position apart from the two phases but close to the phase of the low dielectric liquid in such a manner that the spray port of the nozzle is oriented to a liquid surface of the phase of the low dielectric liquid,

while an electrode is disposed in the phase of the second liquid, and the second substance is dissolved or dispersed in any one of a second liquid and a low dielectric liquid,
so that droplets, charged by generating a potential difference between the nozzle and the electrode, of the first liquid in which the first substance has been dissolved or dispersed, are electrostatically sprayed from the spray port of the nozzle, and the first liquid which has been electrostatically sprayed, passes through the phase of the low dielectric liquid and reaches the phase of the second liquid to obtain the reaction product dispersed in the phase of the second liquid or in the phase of the low dielectric liquid.

2. The method for producing a dispersion according to claim 1 , wherein
the first and second liquids are aqueous solution systems miscible with each other.

3. The method for producing a dispersion according to claim 1 , wherein
sizes of the droplets are controlled by adjusting at least one of a type of the low dielectric liquid, a surface tension of the first liquid, an ionic strength of the first liquid, and a relative permittivity of the first liquid, and the potential difference between the nozzle and the electrode.

4. The method for producing a dispersion according to claim 1 , wherein
the second substance is dissolved or dispersed in the second liquid out of the second liquid and the low dielectric liquid.

5. The method for producing a dispersion according to claim 4 , wherein
one of the first and second substances is a metal salt,
the other of the first and second substances is a reducing agent,
a surfactant is further dissolved or dispersed in the second liquid, and
the reaction product is metal nanoparticles dispersed in the phase of the second liquid.

6. The method for producing a dispersion according to claim 5 , wherein
the surfactant is a nonionic surfactant.

7. The method for producing a dispersion according to claim 1 , wherein
the second substance is dissolved or dispersed in the low dielectric liquid out of the second liquid and the low dielectric liquid.

8. The method for producing a dispersion according to claim 7 , wherein
one of the first and second substances is a first monomer,
the other of the first and second substances is a second monomer, and
the reaction product is a polymer.

9. The method for producing a dispersion according to claim 7 , wherein
one of the first and second substances is a monomer,
the other of the first and second substances is a polymerization initiator, and
the reaction product is a polymer.

10. An apparatus for producing a dispersion of a reaction product between first and second substances, the apparatus comprising:
a container configured so as to store a phase of a second liquid and a phase of a low dielectric liquid in such a state that the two phases lie one on top of the other with two-phase separation;
a nozzle having a spray port which is disposed in the phase of the low dielectric liquid, or is disposed at a position apart from the two phases but close to the phase of the low dielectric liquid in such a manner that the spray port of the nozzle is oriented to a liquid surface of the phase of the low dielectric liquid; and
an electrode disposed in the phase of the second liquid, wherein
the first substance has been dissolved or dispersed in a first liquid and the second substance has been dissolved or dispersed in any one of the second liquid and the low dielectric liquid; and
droplets, charged by generating a potential difference between the nozzle and the electrode, of the first liquid in which the first substance has been dissolved or dispersed, are electrostatically sprayed from the spray port of the nozzle, and the first liquid which has been electrostatically sprayed, passes through the phase of the low dielectric liquid and reaches the phase of the second liquid to obtain the reaction product dispersed in the phase of the second liquid or in the phase of the low dielectric liquid.

Assignees

• Aist
• Nicca Chemical Co
• Aist

Inventors

• Wakisaka Akihiro
• Kobara Hitomi
• Banko Hirotomo
• Ueda Kana
• Kounishi Toshiki
• NAKAI Daiki

Classifications

• B22F1/0545

  Dispersions or suspensions of nanosized particles · CPC title

• B01J19/26

  Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles · CPC title

• C08G69/28

  Preparatory processes · CPC title

• B22F2301/255

  Silver or gold · CPC title

• B01J13/003

  Preparation from aqueous sols · CPC title