Cellulose nanocrystal (CNC) films and conductive CNC-based polymer films produced using electrochemical techniques

Patent metadata

Field	Value
Publication number	US-10081880-B2
Application number	US-201414889466-A
Country	US
Kind code	B2
Filing date	May 6, 2014
Priority date	May 6, 2013
Publication date	Sep 25, 2018
Grant date	Sep 25, 2018

Abstract

The present describes a chiral nematic cellulose nanocrystal (CNC) film comprising: cellulose nanocrystals that self-assemble to form an iridescent CNC structure, wherein the self-assembled structure comprises a finger-print pattern of repeating bright and dark regions, defining a pitch of the iridescent film, where the pitch variable. Also described are conductive polymer nanocomposite based on the CNC film. Further described is the electrophoretic method of producing the chiral nematic cellulose nanocrystal film as well as the polymer nanocomposites and the apparatus used.

First claim

The invention claimed is:

1. A method for producing a chiral nematic cellulose nanocrystal film comprising:
providing a functionalized cellulose nanocrystal suspension;
providing an electrophoretic deposition system comprising:
a working electrode;
a counter electrode;
a DC power supply; and
a controller,

wherein the working electrode, the counter electrode, the power supply and the controller are operatively connected to produce a pulsed signal,
immersing the working electrode and the counter electrode in the cellulose nanocrystal suspension; and
applying a voltage of at least 10V across the deposition system to deposit the film on the working electrode.

2. The method of claim 1 , wherein the voltage applied across the deposition system is at least 30 V.

3. The method of claim 2 , wherein the pulsed signal is a constant voltage square-wave pulse.

4. The method of claim 3 , wherein pulsed signal has a pulse width T on from 1 to 10 milliseconds and a T off from 4 to 10 milliseconds.

5. The method of claim 1 , further comprising drying the film for at least 5 minutes at 100° C. to produce a dry chiral nematic cellulose nanocrystal film.

6. The method of claim 1 , further comprising:
providing a conductive monomer solution;
immersing the working electrode in the monomer solution, and
electropolymerizing the conductive monomer by potentiostatic voltammetry.

7. The method of claim 6 , wherein the conductive monomer is an aniline.

8. A method for producing a conductive polymer-cellulose nanocrystal (CNC) composite having a layered cross-section, comprising:
providing a cellulose nanocrystal suspension;
providing an electrophoretic deposition system comprising:
a working electrode;
a counter electrode;
a DC power supply; and
a controller,

wherein the working electrode, the counter electrode, the power supply and the controller are operatively connected to produce a pulsed signal,
immersing the working electrode and the counter electrode in the cellulose nanocrystal suspension/solution, and
applying a voltage of at least 10V across the deposition system to deposit a cellulose nanocrystal film on the working electrode,
providing a conductive monomer solution;
immersing the working electrode with the film in the monomer solution and electropolymerizing the conductive monomer by potentiostatic voltammetry which forms the conductive polymer-CNC composite.

9. The method of claim 8 , wherein the conductive monomer is an aniline.

10. A chiral nematic cellulose nanocrystal film produced by the method of claim 1 , comprising:
self-assembled cellulose nanocrystals (CNC) forming an iridescent CNC structure, and
a conductive polymer;
wherein the structure comprises
a finger-print pattern of repeating bright and dark regions of spherulitic CNC, having a pitch,
wherein the pattern is that of a plurality of distinct pseudo-planes stacked on each other in a vertical direction along an axis through the pseudo-planes and each adjacent pseudo-plane rotating an incremental fixed distance about the axis with regard to the adjacent pseudo-plane, wherein the distance along the axis required to achieve a 360° rotation of pseudo-planes is the pitch, and
wherein the self-assembled cellulose nanocrystals are functionalized and the film has a variable pitch.

11. The film of claim 10 , wherein the self-assembled cellulose nanocrystals are functionalized with Na—CNC, sulfated-CNC or carboxylated-CNC.

12. The film of claim 10 , wherein the conductive polymer is a polyaniline.

13. A conductive polymer-cellulose nanocrystal (CNC) composite having a layered cross-section, comprising:
a chiral nematic cellulose nanocrystal comprising:
a finger-print pattern of repeating bright and dark regions of spherulitic CNC, having a pitch,
wherein the pattern is that of a plurality of distinct pseudo-planes stacked on each other in a vertical direction along an axis through the pseudo-planes and each adjacent pseudo-plane rotating an incremental fixed distance about the axis with regard to the adjacent pseudo-plane, wherein the distance along the axis required to achieve a 360° rotation of pseudo-planes is the pitch, and
wherein the self-assembled cellulose nanocrystals are functionalized and the pitch is variable, and

a conductive polymer.

14. The composite of claim 13 , wherein the conductive polymer is polyaniline.

15. The composite of claim 14 , wherein the conductivity of the composite is from about 0.1 to about 2 S·cm −1 .

Assignees

• Fpinnovations

Inventors

• Hamad Wadood Y
• Atifi Siham
• Stead Neville J

Classifications

• C09K19/02

  characterised by optical, electrical or physical properties of the components, in general · CPC title

• C09D5/44

  for electrophoretic applications (processes for coating by electrophoresis C25D13/00) · CPC title

• C08J2301/02

  Cellulose; Modified cellulose · CPC title

• C09K19/3819

  Polysaccharides or derivatives thereof · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title