Set on demand cement compositions for curing fluid loss

Patent metadata

Field	Value
Publication number	US-10081755-B2
Application number	US-201314758764-A
Country	US
Kind code	B2
Filing date	Dec 31, 2013
Priority date	Dec 31, 2012
Publication date	Sep 25, 2018
Grant date	Sep 25, 2018

Abstract

Cement compositions containing a cement component and an oil-immiscible solvent and methods for using same are provided. In another aspect, methods for sealing subterranean zones are provided that include emplacing a cement composition into a wellbore containing a cement component and an oil-immiscible solvent, contacting the cement composition with a water source, and reacting the cement composition with the water source to form a hardened cement.

First claim

What is claimed:

1. A cement composition comprising:
a magnesium-based cement component present in the cement composition in an amount ranging from greater than 5 to 60 weight percent;
an oil-immiscible solvent, wherein the cement composition comprises less than 15% by volume water; and
one or more ionic polymers wherein the one or more ionic polymer is a copolymer or terpolymer comprising at least one of acrylic acid, itaconic acid, maleic acid, acrylamido-2-methyl-propane sulfonic acid, styrene sulfonic acid, and vinyl phosphonic acid.

2. The cement composition of claim 1 , wherein the oil-immiscible solvent is one or more selected from a group consisting of ethylene glycol, propylene glycol, glycerol, diethylene glycol, triethylene glycol, 1,3-butanediol, and hexylene glycol.

3. The cement composition of claim 1 , further comprising a particulate silica.

4. The cement composition of claim 1 , further comprising polyvinylpyrrolidone.

5. The composition claim 1 , wherein the composition is substantially free of surfactants.

6. The cement composition of claim 1 , wherein the cement composition further comprises a retarder.

7. The cement composition of claim 6 , wherein the retarder is one or more selected from a group consisting of organophosphates, amine phosphonic acids, lignosulfate salts, hydroxycarboxylic acids, carbohydrates, borax, sodium pentaborate, sodium tetraborate, boric acid, and proteins.

8. A cement composition comprising:
a magnesium-based cement component present in the cement composition in an amount ranging from greater than 5 to 60 weight percent;
an oil-immiscible solvent, wherein the cement composition comprises less than 15% by volume water; and
a latent curing agent.

9. The cement composition of claim 8 , wherein the latent curing agent is an encapsulated aqueous fluid.

10. The cement composition of claim 8 , further comprising an ionomer.

11. A method for sealing a subterranean zone comprising:
emplacing a cement composition comprising less than 15% by volume of water into a wellbore, the cement composition comprising:
a magnesium-based cement component present in the cement composition in an amount ranging from greater than 5 to 60 weight percent,
an oil-immiscible solvent; and
one or more ionic polymers wherein the one or more ionic polymer is a copolymer or terpolymer comprising at least one of acrylic acid, itaconic acid, maleic acid, acrylamido-2-methyl-propane sulfonic acid, styrene sulfonic acid, and vinyl phosphonic acid;

contacting the cement composition with a formation water; and
reacting the cement composition with the formation water to form a hardened cement.

12. The method of claim 11 , wherein emplacing the cement composition comprises emplacing the cement composition into at least an interval of an annulus of the wellbore created by two concentric strings of pipe extending into the wellbore.

13. The method of claim 11 , wherein the cement composition is suitable for spot cementing, plug cementing or squeeze cementing.

14. The method of claim 11 , wherein the oil-immiscible solvent is one or more selected from a group consisting of ethylene glycol, propylene glycol, glycerol, diethylene glycol, triethylene glycol, 1,3-butanediol, ethanolamine, and hexylene glycol.

15. The method of claim 11 , wherein the cement composition further comprises a particulate silica.

16. The method of claim 11 , wherein the cement composition further comprises polyvinylpyrrolidone.

17. The method of claim 11 , further comprising at least one of a preflush and an overflush with an aqueous fluid.

18. The method of claim 11 , wherein the cement composition further comprises a retarder.

19. The method of claim 18 , wherein the retarder is one or more selected from a group consisting of organophosphates, amine phosphonic acids, lignosulfate salts, hydroxycarboxylic acids, carbohydrates, borax, sodium pentaborate, sodium tetraborate, boric acid, and proteins.

20. A method for sealing a subterranean zone comprising:
emplacing a cement composition comprising less than 15% by volume of water into a wellbore, the cement composition comprising:
a magnesium based cement component;
an oil-immiscible solvent;
a latent curing agent;

releasing an aqueous fluid stored in the latent curing agent; and
reacting the cement composition with the aqueous fluid released from the latent curing agent to form a hardened cement.

21. The method of claim 20 , wherein the latent curing agent is an aqueous fluid encapsulated in an organic coating.

22. The method of claim 21 , wherein releasing the aqueous fluid stored in the latent curing agent comprises physical disruption of the organic coating.

23. The method of claim 20 , wherein the latent curing agent is an aqueous fluid contained within an inorganic material.

24. The method of claim 20 , wherein the cement composition further comprises particulate silica.

25. The method of claim 20 , wherein the cement composition further comprises an ionic polymer or polyvinylpyrrolidone.

26. The method of claim 20 , wherein the cement composition further comprises a retarder.

27. The method of claim 26 , wherein the retarder is one or more selected from a group consisting of organophosphates, amine phosphonic acids, lignosulfate salts, hydroxycarboxylic acids, carbohydrates, borax, sodium pentaborate, sodium tetraborate, boric acid, and proteins.

Assignees

• M I Drilling Fluids Uk Ltd
• M I Drilling Fluids Uk Ltd

Inventors

• Ballard David

Classifications

• C09K8/487 Primary

  Fluid loss control additives; Additives for reducing or preventing circulation loss · CPC title

• C09K8/467

  containing additives for specific purposes · CPC title

• C09K8/428

  for squeeze cementing, e.g. for repairing · CPC title

• C09K8/426 Primary

  for plugging · CPC title

• C04B28/32

  Magnesium oxychloride cements, e.g. Sorel cement · CPC title