Composition containing trifluoroethylene

Patent metadata

Field	Value
Publication number	US-10081749-B2
Application number	US-201514851473-A
Country	US
Kind code	B2
Filing date	Sep 11, 2015
Priority date	Apr 30, 2013
Publication date	Sep 25, 2018
Grant date	Sep 25, 2018

Abstract

A composition is provided containing HFO-1123 having a low GWP, which is useful as a heat transfer composition, an aerosol sprayer, a foaming agent, a blowing agent, a solvent or the like. A composition containing HFO-1123, and at least one first compound selected from the group consisting of HFO-1132, HFO-1132a, CFO-1113, HCFO-1122, HCFO-1122a, HFC-143 and methane.

First claim

What is claimed is:

1. A method for producing a composition comprising trifluoroethylene by gas-phase hydrogen reduction of chlorotrifluoroethylene, comprising:
reacting chlorotrifluoroethylene and hydrogen in the presence of a palladium catalyst at 80° C. or higher; and
distilling the obtained reaction product to obtain the composition comprising trifluoroethylene and at least one compound selected from the group consisting of E-1,2-difluoroethylene, Z-1,2-difluoroethylene, chlorotrifluoroethylene, 1-chloro-2,2-difluoroethylene and 1,1-difluoroethylene, and wherein a total proportion of the at least one compound in the obtained composition is from 0.0001 mass % to less than 0.5 mass % based on a total amount of the trifluoroethylene and the at least one compound.

2. The production method according to claim 1 , wherein a total proportion of E-1,2-difluoroethylene, Z-1,2-difluoroethylene, chlorotrifluoroethylene, 1-chloro-2,2-difluoroethylene and 1,1-difluoroethylene in the obtained composition is from 0.0001 mass % to less than 0.5 mass % based on a total amount of trifluoroethylene, E-1,2-difluoroethylene, Z-1,2-difluoroethylene and 1,1-difluoroethylene.

3. A method for producing a composition comprising trifluoroethylene by a synthetic reaction, comprising:
subjecting a mixture of chlorodifluoromethane and chlorofluoromethane to heat decomposition in the presence of a heating medium, wherein the synthetic reaction is carried out at a temperature from 400 to 1,200° C., and
distilling the obtained reaction product to obtain the composition comprising trifluoroethylene and at least one compound selected from the group consisting of E-1,2-difluoroethylene, Z-1,2-difluoroethylene, 1,1-difluoroethylene, chlorotrifluoroethylene, tetrafluoroethylene, fluoroethylene, 1,1,1-trifluoroethane, difluoromethane, trifluoromethane and pentafluoroethane.

4. The production method according to claim 3 , wherein a total proportion of any of E-1,2-difluoroethylene, Z-1,2-difluoroethylene, 1,1-difluoroethylene, chlorotrifluoroethylene, tetrafluoroethylene, fluoroethylene, 1,1,1-trifluoroethane, difluoromethane, trifluoromethane and pentafluoroethane in the obtained composition is less than 0.5 mass % based on a total amount of the trifluoroethylene and E-1,2-difluoroethylene, 1,1-difluoroethylene, tetrafluoroethylene, fluoroethylene, 1,1,1-trifluoroethane, difluoromethane, trifluoromethane and pentafluoroethane.

5. The production method according to claim 3 , wherein a total proportion of E-1,2-difluoroethylene, 1,1-difluoroethylene, tetrafluoroethylene, fluoroethylene, 1,1,1-trifluoroethane, difluoromethane, trifluoromethane and pentafluoroethane is less than 0.5 mass % based on a total amount of the trifluoroethylene and E-1,2-difluoroethylene, 1,1-difluoroethylene, tetrafluoroethylene, fluoroethylene, 1,1,1-trifluoroethane, difluoromethane, trifluoromethane and pentafluoroethane.

6. The production method according to claim 1 , wherein the at least one compound in the obtained composition is selected from the group consisting of E-1,2-difluoroethylene, Z-1,2-difluoroethylene, 1,1-difluoroethylene, 1-chloro-2,2-difluoroethylene and 1,1-difluoroethylene.

7. The production method according to claim 1 , wherein the palladium catalyst is a catalyst having palladium and a metal other than palladium supported on a carrier, wherein the metal other than palladium is selected from the group consisting of cobalt, rhodium, iridium, nickel, gold, and combinations thereof.

8. The production method according to claim 7 , wherein a proportion of the metal other than palladium supported on the carrier is from 0.01 to 50 parts by mass per 100 parts by mass of the palladium.

9. The production method according to claim 3 , wherein a molar ratio of chlorofluoromethane to chlorodifluoromethane in the reaction mixture is from 0.01 to 4.0.

10. The production method according to claim 3 , wherein a total proportion of the at least one compound in the obtained composition is from 0.0001 mass % to less than 0.5 mass % based on a total amount of the trifluoroethylene and the at least one compound.

Assignees

• Asahi Glass Co Ltd
• Agc Inc

Inventors

• Taniguchi Tomoaki
• Okamoto Hidekazu
• Furuta Shoji
• Takeuchi Yu

Classifications

• C09K2205/112

  Halogenated ethers · CPC title

• C09K2205/22

  All components of a mixture being fluoro compounds · CPC title

• C07C17/278

  of only halogenated hydrocarbons · CPC title

• C09K2205/126

  Unsaturated fluorinated hydrocarbons · CPC title

• B01F17/0085

  Operations & Transport · mapped topic