Composite comprising a cellulose-based filler

Patent metadata

Field	Value
Publication number	US-10081726-B2
Application number	US-201615747623-A
Country	US
Kind code	B2
Filing date	Aug 11, 2016
Priority date	Aug 14, 2015
Publication date	Sep 25, 2018
Grant date	Sep 25, 2018

Abstract

Composite comprising a heterophasic propylene copolymer (HECO), a high density polyethylene, a cellulose-based filler and a compatibilizer.

First claim

The invention claimed is:

1. A composite comprising
(a) 32 to 89 wt.-%, based on the total weight of the composite, of a heterophasic propylene copolymer (HECO) comprising a (semicrystalline) polypropylene (PP) as a matrix in which an elastomeric propylene copolymer (EC) is dispersed;
(b) 5.0 to 40 wt.-%, based on the total weight of the composite, of a high density polyethylene (HDPE) having a density in the range of 935 to 970 kg/m 3 ;
(c) 5.0 to 30 wt.-%, based on the total weight of the composite, of a cellulose-based filler (CF); and
(d) 1.0 to 8.0 wt.-%, based on the total weight of the composite, of an adhesion promoter (AP),

wherein the composite does not comprise
(i) a further heterophasic propylene copolymer different to the heterophasic propylene copolymer (HECO) and
(ii) a further (semicrystalline) polypropylene different to the (semicrystalline) polypropylene (PP) of the matrix of the heterophasic propylene copolymer (HECO).

2. The composite according to claim 1 consisting of
(a) 32 to 89 wt.-%, based on the total weight of the composite, of a heterophasic propylene copolymer (HECO) comprising a (semicrystalline) polypropylene (PP) as a matrix in which an elastomeric propylene copolymer (EC) is dispersed;
(b) 5.0 to 40 wt.-%, based on the total weight of the composite, of a high density polyethylene (HDPE) having a density in the range of 935 to 970 kg/m 3 ;
(c) 5.0 to 30 wt.-%, based on the total weight of the composite, of the cellulose-based filler (CF);
(d) 1.0 to 8.0 wt.-%, based on the total weight of the composite, of an adhesion promoter (AP), and
(e) optionally, one or more of alpha nucleating agents (NU) or additives (A).

3. The composite according to claim 1 consisting of
(a) 32 to 89 wt.-%, based on the total weight of the composite, of a heterophasic propylene copolymer (HECO) comprising a (semicrystalline) polypropylene (PP) as a matrix in which an elastomeric propylene copolymer (EC) is dispersed;
(b) 5.0 to 40 wt.-%, based on the total weight of the composite, of a high density polyethylene (HDPE) having a density in the range of 935 to 970 kg/m 3 ;
(c) 5.0 to 30 wt.-%, based on the total weight of the composite, of the cellulose-based filler (CF);
(d) 1.0 to 8.0 wt.-%, based on the total weight of the composite, of an adhesion promoter (AP),
(e) optionally up to 5 wt.-%, based on the total weight of the composite, of alpha nucleating agents (NU) and
(f) optionally up to 8.0 wt.-%, based on the total weight of the composite, of additives (A).

4. The composite according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has a melt flow rate MFR 2 (230° C., 2.16 kg) in the range of from 3.0 to 30.0 g/10 min.

5. The composite according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has a xylene cold soluble (XCS) fraction (25° C.) of from 15.0 to 50.0 wt.-%, based on the total weight of the heterophasic propylene copolymer (HECO).

6. The composite according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has a comonomer content of <30.0 mol.-%, based on the heterophasic propylene copolymer (HECO).

7. The composite according to claim 1 , wherein (a) comprises one or more of the (semicrystalline) polypropylene (PP) is a (semicrystalline) propylene homopolymer (H-PP) or the elastomeric propylene copolymer (EC) is an ethylene propylene rubber (EPR).

8. The composite according to claim 1 , wherein the heterophasic propylene copolymer comprises an amorphous fraction (AM), the amorphous fraction (AM) of the heterophasic propylene copolymer (HECO) has a comonomer content in the range of 30.0 to 60.0 mol.-%, based on the amorphous fraction (AM) of the heterophasic propylene copolymer (HECO).

9. The composite according to claim 1 , wherein the heterophasic propylene copolymer comprises an amorphous fraction (AM), the amorphous fraction (AM) of the heterophasic propylene copolymer (HECO) has an intrinsic viscosity (IV) in the range of 1.8 to 3.2 dl/g.

10. The composite according to claim 1 , wherein the high density polyethylene (HDPE) has a melt flow rate MFR 2 (190° C., 2.16 kg) in the range of from 0.1 to 30.0 g/10 min.

11. The composite according to claim 1 , wherein the cellulose-based filler (CF) is selected from the group consisting of wood, flax, hem, jute, straw, rice, hardboard, cardboard, paper, pulp, raw cellulose, cellulose, cellulose acetate, cellulose triacetate, cellulose propionate, cellulose acetate propionate, cellulose acetate butyrate, nitrocellulose, methylcellulose, ethylcellulose, ethyl methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose (HPC), hydroxyethyl methyl cellulose, hydroxypropyl methyl cellulose (HPMC), ethyl hydroxyethyl cellulose, carboxymethyl cellulose (CMC), and any mixtures thereof.

12. The composite according to claim 1 , wherein the cellulose-based filler (CF) has a volume moment mean (D[4.3]) diameter between 1 and 300 μm.

13. The composite according to claim 1 , wherein the adhesion promoter (AP) is selected from the group consisting of an acid modified polyolefin, an anhydride modified polyolefin and a modified styrene block copolymer.

14. The composite according to claim 2 , wherein the nucleating agents (NU) are selected from the group consisting of
(i) Salts of monocarboxylic acids and polycarboxylic acids, and
(ii) dibenzylidenesorbitol and C1-C8-alkyl-substituted dibenzylidenesorbitol derivatives, ethyldibenzylidenesorbitol or dimethyldibenzylidenesorbitol, or substituted nonitol-derivatives, and
(iii) salts or diesters of phosphoric acid, and
(iv) vinylcycloalkane polymer and vinylalkane polymer, and
(v) mixtures thereof.

15. The composite according to claim 2 , wherein the additives (A) are selected from the group consisting of acid scavengers, antioxidants, colorants, light stabilisers, plasticizers, slip agents, anti-scratch agents, dispersing agents, processing aids, lubricants, pigments, and mixtures thereof.

16. A molded article comprising a composite, wherein the composite comprises:
(a) 32 to 89 wt.-%, based on the total weight of the composite, of a heterophasic propylene copolymer (HECO) comprising a (semicrystalline) polypropylene (PP) as a matrix in which an elastomeric propylene copolymer (EC) is dispersed;
(b) 5.0 to 40 wt.-%, based on the total weight of the composite, of a high density polyethylene (HDPE) having a density in the range of 935 to 970 kg/m 3 ;
(c) 5.0 to 30 wt.-%, based on the total weight of the composite, of a cellulose-based filler (CF); and
(d) 1.0 to 8.0 wt.-%, based on the total weight of the composite, of an adhesion promoter (AP),

wherein the composite does not comprise
(i) a further heterophasic propylene copolymer different to the heterophasic propylene copolymer (HECO) and
(ii) a further (semicrystalline) polypropylene different to the (semicrystalline) polypropylene (PP) of the matrix of the heterophasic propylene copolymer (HECO).

17. The molded article according to claim 16 being an automotive article.

18. The composite according to claim 13 , wherein the adhesion promoter (AP) is a maleic anhydride functionalized polypropylene.

19. The composite according to claim 14 ,
wherein the salts of monocarboxylic acids and polycarboxylic acids comprise sodium benzoate or aluminum tert-butylbenzoate,
wherein dibenzylidenesorbitol comprises 1,3:2,4 dibenzylidenesorbitol,
wherein C1-C 8 -alkyl-substituted dibenzylidenesorbitol derivatives comprise methyldibenzylidenesorbitol,
wherein ethyldibenzylidenesorbitol or dim

Assignees

• Borealis Ag

Inventors

• Pukánszky Béla
• Renner Karoly
• Kalmar Szabolcs
• Lummerstorfer Thomas
• Braun Hermann
• Doshev Petar
• Jerabek Michael

Classifications

• C08L2308/00

  Chemical blending or stepwise polymerisation process with the same catalyst · CPC title

• C08L2205/035

  containing four or more polymers in a blend · CPC title

• C08L23/06

  Polyethylene · CPC title

• C08L1/00

  Compositions of cellulose, modified cellulose or cellulose derivatives · CPC title

• C08J2423/26

  modified by chemical after-treatment · CPC title