6-acyl-1,2,4-triazine-3,5-dione derivative and herbicides

Patent metadata

Field	Value
Publication number	US-10081608-B2
Application number	US-201615393850-A
Country	US
Kind code	B2
Filing date	Dec 29, 2016
Priority date	Jun 29, 2010
Publication date	Sep 25, 2018
Grant date	Sep 25, 2018

Abstract

Disclosed are triazine derivative compounds exhibiting sufficient herbicidal activity at low application dosage when they are applied to soils and foliage, and an agrochemical composition using the same, in particular herbicides.

First claim

The invention claimed is:

1. A triazine derivative or a salt thereof represented by following Formula 1:

wherein R 1 represents a hydrogen atom; a C 1 -C 12 alkyl group; a C 2 -C 6 alkenyl group; a C 2 -C 6 alkynyl group; a C 3 -C 6 cycloalkyl group; a C 3 -C 6 cycloalkenyl group; a C 3 -C 6 cycloalkyl C 1 -C 6 alkyl group; a C 1 -C 6 haloalkyl group; a C 2 -C 6 haloalkenyl group; a C 2 -C 6 haloalkynyl group; a C 3 -C 6 halocycloalkyl group; a C 3 -C 6 halocycloalkyl C 1 -C 6 alkyl group; an amino C 1 -C 6 alkyl group; a nitro C 1 -C 6 alkyl group; a C 1 -C 6 alkylamino C 1 -C 6 alkyl group; a di(C 1 -C 6 alkyl)amino C 1 -C 6 alkyl group; a C 1 -C 6 alkylthio C 1 -C 6 alkyl group; a C 1 -C 6 alkylsulfinyl C 1 -C 6 alkyl group; a C 1 -C 6 alkylsulfonyl C 1 -C 6 alkyl group; a C 1 -C 6 haloalkylthio C 1 -C 6 alkyl group; a C 1 -C 6 haloalkylsulfinyl C 1 -C 6 alkyl group; a C 1 -C 6 haloalkylsulfonyl C 1 -C 6 alkyl group; a C 1 -C 6 alkoxy C 1 -C 6 alkyl group; a hydroxy C 1 -C 6 alkyl group; a phenyl C 1 -C 6 alkoxy C 1 -C 6 alkyl group, wherein the phenyl in the group may be substituted with one substituent group selected from substituent group α or 2 to 5 substituent groups that are the same or different from each other and selected from substituent group α; a C 1 -C 6 alkoxy C 1 -C 6 alkoxy C 1 -C 6 alkyl group; a C 3 -C 6 cycloalkyloxy C 1 -C 6 alkyl group; a C 3 -C 6 cycloalkyl C 1 -C 6 alkyloxy C 1 -C 6 alkyl group; a phenyloxy C 1 -C 6 alkyl group, wherein the phenyl in the group may be substituted with 1 to 5 identical or different substituents selected from the substituent group α; a phenylthio C 1 -C 6 alkyl group, wherein the phenyl in the group may be substituted with 1 to 5 identical or different substituents selected from the substituent group α; a phenylsulfinyl C 1 -C 6 alkyl group, wherein the phenyl in the group may be substituted with 1 to 5 identical or different substituents selected from the substituent group α; a phenylsulfonyl C 1 -C 6 alkyl group, wherein the phenyl in the group may be substituted with 1 to 5 identical or different substituents selected from the substituent group α; a C 1 -C 6 haloalkoxy C 1 -C 6 alkyl group; a phenyl group which may be substituted with one or more substituents selected from the substituent group α; a phenyl C 1 -C 6 alkyl group which may be substituted with one or more substituents selected from the substituent group α; a phenyl C 2 -C 6 alkenyl group which may be substituted with one or more substituents selected from the substituent group α; a phenyl C 2 -C 6 alkynyl group which may be substituted with one or more substituents selected from the substituent group α; a C 1 -C 6 alkoxyimino C 1 -C 6 alkyl group; a phenoxyimino C 1 -C 6 alkyl group which may be substituted with one or more substituents selected from the substituent group α; a di(C 1 -C 6 alkoxy)C 1 -C 6 alkyl group; a (R 31 R 32 N—C═O)C 1 -C 6 alkyl group; a C 1 -C 6 alkoxycarbonyl C 1 -C 6 alkyl group; a C 1 -C 6 alkylcarbonyl C 1 -C 6 alkyl group; a C 1 -C 6 alkylcarbonyloxy C 1 -C 6 alkyl group; a C 1 -C 6 alkylidene aminooxy C 1 -C 6 alkyl group; a formyl C 1 -C 6 alkyl group; a C 1 -C 6 alkylthio C 1 -C 6 alkoxy C 1 -C 6 alkyl group; a C 1 -C 6 alkylsulfinyl C 1 -C 6 alkoxy C 1 -C 6 alkyl group; a C 1 -C 6 alkylsulfonyl C 1 -C 6 alkoxy C 1 -C 6 alkyl group; a cyano C 1 -C 6 alkoxy C 1 -C 6 alkyl group; a cyano C 1 -C 6 alkyl group; a C 2 -C 6 alkylidene amino group; a di(C 1 -C 10 alkyl)amino C 1 -C 6 alkylidene amino group; a NR 31 R 32 group; a C 1 -C 6 alkoxy group; a C 2 -C 6 alkenyloxy group; a C 2 -C 6 alkynyloxy group; a C 3 -C 6 cycloalkyloxy group; a C 3 -C 6 cycloalkyl C 1 -C 6 alkyloxy group; a C 1 -C 6 haloalkoxy group; a heterocyclic group comprising 3 to 10 carbon atoms and one or more identical or different heteroatoms selected from an oxygen atom, a sulfur atom, and a nitrogen atom, wherein the group may be substituted with 1 to 5 identical or different substituents selected from the substituent group α, and when the heteroatom in the heterocyclic group is a sulfur atom, the sulfur atom may be oxidized to sulfoxide or sulfone; a C 1 -C 6 alkyl group substituted with a heterocyclic group comprising 3 to 10 carbon atoms and one or more identical or different heteroatoms selected from an oxygen atom, a sulfur atom, and a nitrogen atom, wherein the group may be substituted with 1 to 5 identical or different substituents selected from the substituent group α; a C 1 -C 6 alkoxy C 1 -C 6 alkyl group substituted with a heterocyclic group comprising 3 to 10 carbon atoms and one or more identical or different heteroatoms selected from an oxygen atom, a sulfur atom, and a nitrogen atom, wherein the group may be substituted with 1 to 5 identical or different substituents selected from the substituent group α; or a C 1 -C 6 alkoxy C 1 -C 6 alkyl group substituted with a heterocyclic-oxy group in which the heterocyclic group in the heterocyclic-oxy group comprising 3 to 10 carbon atoms and one or more identical or different heteroatoms selected from an oxygen atom, a sulfur atom, and a nitrogen atom, wherein the group may be substituted with 1 to 5 identical or different substituents selected from the substituent group α;
R 2 represents a hydrogen atom; a C 1 -C 6 alkyl group; a C 2 -C 6 alkenyl group; a C 2 -C 6 alkynyl group; a C 3 -C 6 cycloalkyl group; a C 1 -C 6 haloalkyl group; a C 2 -C 6 haloalkenyl group; a C 2 -C 6 haloalkynyl group; a C 1 -C 6 alkoxy C 1 -C 6 alkyl group; a C 3 -C 6 cycloalkyloxy C 1 -C 6 alkyl group; a di(C 1 -C 6 alkoxy) C 1 -C 6 alkyl group; a heterocyclic group comprising 3 to 10 carbon atoms and one or more identical or different heteroatoms selected from an oxygen atom, a sulfur atom, and a nitrogen atom, wherein the group may be substituted with 1 to 5 identical or different substituents selected from the substituent group α; a phenyl group which may be substituted with one or more substituents selected from the substituent group α; a phenyl C 1 -C 6 alkyl group which may be substituted with one or more substituents selected from the substituent group α; a phenyl C 2 -C 6 alkenyl group which may be substituted with one or more substituents selected from the substituent group α; or a phenyl C 2 -C 6 alkynyl group which may be substituted with one or more substituents selected from the substituent group α,
Y and Z represent an oxygen atom or a sulfur atom,
A represents any one of the following formula A-1 to A-5,

R 4 represents a hydroxyl group; O − M + , wherein the M + represents an alkali metal cation or an ammonium cation; an amino group; a halogen atom; a cyano group; an isothiocyanate group; an isocyanate group; a hydroxycarbonyloxy group; a C 1 -C 6 alkoxycarbonyloxy group; a benzyloxycarbonyloxy group which may be substituted with a substituent group selected from substituent group α; a C 1 -C 6 alkoxy group; a C 2 -C 6 alkenyloxy group; a C 2 -C 6 alkynyloxy group; a C 3 -C 6 cycloalkyloxy group; a cyanomethylene oxy group; a C 3 -C 6 cycloalkyl C 1 -C 6 alkyloxy group; a C 1 -C 6 alkylcarbonyloxy group; a C 1 -C 6 haloalkylcarbonyloxy group; a C 2 -C 6 alkenylcarbonyloxy group; a C 2 -C 6 haloalkenylcarbonyloxy group; a C 2 -C 6 alkynylcarbonyloxy group; a C 2 -C 6 haloalkynylcarbonyloxy group; a C 1 -C 6 alkoxycarbonyl C 1 -C 6 alkoxy group; a phenyloxy group which may be substituted with one or more substituents selected from the substituent group α; a benzyloxy group which may be substituted with one or more substituents selected from the substituent group α; a phenylcarbonyloxy group which may be substituted wi

Assignees

• Fmc Corp

Inventors

• Shibayama Atsushi
• Kajiki Ryu
• Kobayashi Masami
• Mitsunari Takashi
• Nagamatsu Atsushi

Classifications

• C07D403/04

  directly linked by a ring-member-to-ring-member bond · CPC title

• A01N43/64

  having rings with three nitrogen atoms as the only ring hetero atoms · CPC title

• C07D411/14

  containing three or more hetero rings · CPC title

• C07D417/12

  linked by a chain containing hetero atoms as chain links · CPC title

• C07D413/04

  directly linked by a ring-member-to-ring-member bond · CPC title