Process for converting calcium bentonite to sodium bentonite

Patent metadata

Field	Value
Publication number	US-10081574-B2
Application number	US-201715587852-A
Country	US
Kind code	B2
Filing date	May 5, 2017
Priority date	Nov 30, 2015
Publication date	Sep 25, 2018
Grant date	Sep 25, 2018

Abstract

Method of converting calcium bentonite to sodium bentonite that is suitable for use as drilling mud or a cement additive. After the addition of a calcium bentonite sample to a prepared soda ash solution at predetermined soda ash/bentonite weight ratios, the bentonite suspension is continuously heated and stirred for up to 24 h. The heating and stirring are crucial towards enhancing the sodium activation of the bentonite, as well as other rheological properties of the bentonite.

First claim

The invention claimed is:

1. A method of converting calcium bentonite to sodium bentonite, comprising:
mixing a calcium bentonite sample with a sodium carbonate aqueous solution to form a bentonite suspension comprising calcium bentonite, sodium carbonate, and water,
wherein the sodium carbonate aqueous solution comprises no more than 1% by weight of sodium carbonate based on the total weight of the water in the sodium carbonate aqueous solution,
wherein the ratio of the weight of the sodium carbonate present in the sodium carbonate aqueous solution to the total weight of the calcium bentonite sample mixed with the sodium carbonate aqueous solution is 1:7 to 1:23, and
wherein after the mixing, a calcium bentonite concentration in the bentonite suspension is from 5 to 10 wt % based on a total weight of the water in the bentonite suspension; and
heating and stirring the bentonite suspension at below 80° C. for 6-24 hours to form a sodium bentonite product comprising water, sodium bentonite and calcium carbonate,
wherein the sodium bentonite product formed by the heating and stirring has a Na/Ca molar ratio of at least 2.5.

2. The method of claim 1 , wherein the sodium bentonite product formed by the heating and stirring has an apparent viscosity of at least 15 cP.

3. The method of claim 1 , wherein the sodium bentonite product formed by the heating and stirring has a yield point of no more than 30 lb/100 ft 2 .

4. The method of claim 1 , wherein the sodium bentonite product formed by the heating and stirring has a viscometer dial reading of 33-35 lb/100 ft 2 at 300 rpm and 39-40 lb/100 ft 2 at 600 rpm.

5. The method of claim 1 , wherein an average particle size of the sodium bentonite present in the sodium bentonite product is more than 500 times larger than an average particle size of the calcium bentonite sample added to the sodium carbonate aqueous solution.

6. The method of claim 1 , wherein the calcium bentonite sample is a raw bentonite sample.

7. The method of claim 1 , further comprising:
purifying the calcium bentonite sample by at least one method selected from the group consisting of dry-sieving, wet-sieving, dispersion in deionized water with hexametaphosphate, dispersion in deionized water without hexametaphosphate and sedimentation.

8. The method of claim 1 , wherein the sodium carbonate aqueous solution has a sodium carbonate concentration of 0.28-0.86% by weight based on a total weight of water.

9. The method of claim 1 , wherein the ratio of the weight of the sodium carbonate present in the sodium carbonate aqueous solution to the total weight of the calcium bentonite sample added to the sodium carbonate aqueous solution is 1:20 to 1:23.

10. The method of claim 1 , wherein the heating and stirring includes heating the bentonite suspension at 65-70° C.

11. The method of claim 1 , wherein the heating and stirring includes stirring the bentonite suspension for 12-24 hours.

12. The method of claim 1 , wherein the sodium bentonite product formed by the heating and stirring has a Na/Ca molar ratio of 2.8-3.0.

13. A method of converting calcium bentonite to sodium bentonite, comprising:
mixing a calcium bentonite sample with a sodium carbonate aqueous solution to form a bentonite suspension comprising calcium bentonite, sodium carbonate, and water,
wherein the sodium carbonate aqueous solution comprises no more than 1% by weight of sodium carbonate based on the total weight of the water in the sodium carbonate aqueous solution,
wherein the ratio of the weight of the sodium carbonate present in the sodium carbonate aqueous solution to the total weight of the calcium bentonite sample mixed with the sodium carbonate aqueous solution is 1:7 to 1:23, and
wherein after the mixing, a calcium bentonite concentration in the bentonite suspension is from 5 to 10 wt % based on a total weight of the water in the bentonite suspension; and
heating and stirring the bentonite suspension at below 80° C. for 6-24 hours to form a sodium bentonite product comprising water, sodium bentonite and calcium carbonate,
wherein the sodium bentonite present in the sodium bentonite product formed by the heating and stirring has a particle size of 1100-1400 μm.

14. The method of claim 1 , wherein the sodium bentonite product formed by the heating and stirring has a yield point of 12-28 lb/100 ft 2 .

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• Magzoub Musaab Ibrahim
• Nasser Mustafa Saleh
• Hussein Ibnelwaleed Ali
• Mahmoud Mohamed Ahmed Nasr Eldin
• Sultan Abdullah Saad

Classifications

• C09K2208/34

  Lubricant additives · CPC title

• C01B33/40

  Clays · CPC title

• C09K8/032 Primary

  Inorganic additives · CPC title

• C04B2235/349

  Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite · CPC title

• B28C1/04

  Producing suspensions, e.g. by blunging {or mixing; with means for removing stones} · CPC title