Highly functional cellulose composite

Patent metadata

Field	Value
Publication number	US-10080371-B2
Application number	US-201214237688-A
Country	US
Kind code	B2
Filing date	Aug 10, 2012
Priority date	Aug 11, 2011
Publication date	Sep 25, 2018
Grant date	Sep 25, 2018

Abstract

A cellulose composite which contains a cellulose and a polysaccharide and which is characterized in that the median diameter of colloidal cellulose composites contained in the cellulose composite is 0.85 μm or more as measured by a dynamic light scattering method.

First claim

The invention claimed is:

1. A cellulose composite comprising colloidal cellulose composites of cellulose and a polysaccharide, wherein:
the cellulose composite has a storage elastic modulus (G′) of 0.50 Pa or more in a water dispersion of pH 6 to 7 which contains the cellulose composite in an amount of 1 mass %, and
each of the colloidal cellulose composites comprise a cellulose particle having a polysaccharide radially extending from the surface of the cellulose particle, and having a median size of 0.85 μm or more as measured by a dynamic light scattering method
that includes: 1) the cellulose composite is suspended in pure water at 0.5 mass % to obtain a suspension,
2) the suspension is homogenized with a high-shear Excel auto homogenizer at 15000 rpm for 5 minutes,
3) the homogenized suspension is centrifuged in a first centrifugation at 39200 m 2 /s for 10 minutes,
4) a first supernatant from the first centrifugation is collected,
5) the first supernatant is centrifuged in a second centrifugation at 116000 m 2 /s for 45 minutes;
6) a second supernatant from the second centrifugation is collected
7) the second supernatant undergoes ultra-sonication for 10 minutes, and
8) the median size of the colloidal cellulose composite is determined from the product of the ultra-sonication by dynamic light scattering determined at a cumulative 50% scattering intensity in a frequency distribution measured by a zeta potential-particle size measurement system.

2. The cellulose composite according to claim 1 , wherein the cellulose composite comprises the colloidal cellulose composite in an amount of 50 mass % or more.

3. The cellulose composite according to claim 1 , wherein each of the colloidal compositions comprise cellulose of 50 to 99 mass % and a polysaccharide of 1 to 50 mass %.

4. The cellulose composite according to claim 1 , wherein the polysaccharide is an anionic polysaccharide.

5. The cellulose composite according to claim 4 , wherein the anionic polysaccharide comprises sodium carboxymethylcellulose.

6. The cellulose composite according to claim 5 , wherein the anionic polysaccharide further comprises xanthan gum.

7. A food and drink comprising the cellulose composite according to claim 1 .

8. A medicinal product comprising the cellulose composite according to claim 1 .

9. An industrial product comprising the cellulose composite according to claim 1 .

10. A food and drink, a medicinal product or an industrial product comprising the cellulose composite according to claim 1 and a water-insoluble component in an aqueous medium and having a loss tangent tan δ (loss elastic modulus G″/storage elastic modulus G′) of 1.5 or more.

11. The food and drink according to claim 10 , wherein the water-insoluble component is cocoa powder, cereal powder, fruit, or calcium, magnesium, zinc or a salt thereof.

12. The food and drink according to claim 10 , wherein the food and drink is an aqueous beverage, a milk beverage or a fruit beverage.

13. A food and drink, a medicinal product, or an industrial product containing a cellulose composite and a water-insoluble component in an aqueous medium and having a loss tangent, tan δ (loss elastic modulus G″/storage elastic modulus G′) of 1.5 or more.

14. A method for producing the cellulose composite according to claim 1 , comprising treating a mixture containing cellulose, a polysaccharide and an aqueous medium together in a wet process, wherein a solid content is controlled to be 35 mass % or more, and the temperature is 80° C. or less.

15. The method for producing the cellulose composite according to claim 14 , wherein the polysaccharide is sodium carboxymethylcellulose and the sodium carboxymethylcellulose has a molecular-weight distribution, which is obtained by gel permeation chromatography performed in a 0.05 M sodium hydroxide, having two (bimodal) peaks or more.

16. The method for producing the cellulose composite according to claim 15 , wherein the sodium carboxymethylcellulose contains Component A having a viscosity of 100 mPa·s or more and Component B having a viscosity of less than 100 mPa·s in a mass ratio of 5/95 to 95/5.

17. The method for producing the cellulose composite according to claim 15 , wherein the sodium carboxymethylcellulose has a substitution degree of 1 or more.

Assignees

• Enatsu Kouichirou
• Obata Haruko
• Yamasaki Naoaki
• Asahi Kasei Chemicals Corp

Inventors

• Enatsu Kouichirou
• Obata Haruko
• Yamasaki Naoaki

Classifications

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title

• C08L5/00

  Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00 · CPC title

• C08L1/02

  Cellulose; Modified cellulose · CPC title

• A61K47/38

  Cellulose; Derivatives thereof · CPC title

• A23L29/262

  Cellulose; Derivatives thereof, e.g. ethers · CPC title