Method and arrangement for determining at least one pore-related parameter of a porous material

Patent metadata

Field	Value
Publication number	US-10078044-B2
Application number	US-201415027938-A
Country	US
Kind code	B2
Filing date	Oct 3, 2014
Priority date	Oct 8, 2013
Publication date	Sep 18, 2018
Grant date	Sep 18, 2018

Abstract

A method for determining at least one pore-related parameter of a porous material is provided. The method includes supplying a volatile liquid into a chamber, placing a porous material within the chamber, spaced apart from and over the volatile liquid, determining an effective mass of the chamber over a period of time, and determining at least one pore-related parameter of the porous material based on the effective mass determined. An arrangement for determining at least one pore-related parameter of a porous material is also provided.

First claim

The invention claimed is:

1. A method for determining at least one pore-related parameter of a porous material, the method comprising:
supplying a volatile liquid layer comprising a first amount of volatile liquid into a chamber;
placing a porous material comprising one or more tubular porous materials, each of the one or more tubular porous materials comprising a lumen with opposite ends of the lumen sealed, within the chamber, the porous material having pores saturated with a second amount of the volatile liquid and being spaced apart from and over the volatile liquid layer;
determining an evaporation rate of the second amount of the volatile fluid from the pores over a period of time by measuring an effective mass of the chamber comprising a mass of the chamber, a mass of the volatile liquid layer comprising the first amount of volatile liquid, and a mass of the porous material comprising the second amount of the volatile liquid over the period of time; and
determining at least one pore-related parameter of the porous material based on the evaporation rate,
wherein the pore-related parameter is any one selected from a group consisting of a porosity, a pore size, a pore-size distribution, and an internal pore fouling of the porous material.

2. The method as claimed in claim 1 , wherein measuring the effective mass of the chamber comprises measuring the effective mass of the chamber at a series of time intervals.

3. The method as claimed in claim 1 , further comprising determining a start of a pore-liquid evaporation period prior to measuring the effective mass of the chamber.

4. The method as claimed in claim 3 , wherein determining the start of a pore-liquid evaporation period comprises:
determining a porosity of the porous material; and
measuring, based on the determined porosity, a mass of the second amount of the volatile liquid present in the pores of the porous material.

5. The method as claimed in claim 1 , further comprising:
determining a contact angle between the porous material and the second amount of the volatile liquid present in the pores of the porous material, and
wherein determining the at least one pore-related parameter of the porous material further comprises modifying the determined at least one pore-related parameter according to the contact angle determined.

6. The method as claimed in claim 1 ,
wherein the at least one pore-related parameter is a pore-size distribution,
wherein measuring the effective mass of the chamber comprises measuring the effective mass of the chamber at a series of time intervals to generate a plurality of instantaneous masses,
wherein determining the at least one pore-related parameter of the porous material comprises:
relating a respective instantaneous mass of the determined plurality of instantaneous masses to a respective pore diameter of the porous material; and
determining the pore-size distribution based on the instantaneous masses determined and the associated pore diameters.

7. The method as claimed in claim 1 , further comprising saturating the pores of the porous material with the second amount of the volatile liquid prior to placing the porous material in the chamber.

8. The method as claimed in claim 1 , further comprising controlling evaporation of the second amount of the volatile liquid in the chamber.

9. The method as claimed in claim 8 , wherein controlling evaporation of the second amount of the volatile liquid in the chamber comprises arranging a diffusional resistance element spaced apart from and over the porous material, wherein the diffusional resistance element is configured to resist diffusion of vapor of the second amount of the volatile liquid.

10. The method as claimed in claim 9 , wherein arranging the diffusional resistance element spaced apart from and over the porous material comprises arranging a microporous membrane or a microporous filter spaced apart from and over the porous material.

11. The method as claimed in claim 9 , wherein arranging the diffusional resistance element spaced apart from and over the porous material comprises arranging a covering structure spaced apart from and over the porous material, the covering structure having a hole.

12. The method as claimed in claim 9 , wherein arranging the diffusional resistance element spaced apart from and over the porous material comprises arranging a layer of fiberglass within the chamber, spaced apart from and over the porous material.

13. The method as claimed in claim 1 , wherein the one or more tubular porous materials comprises a plurality of tubular porous materials, and wherein the method further comprising laying the plurality of tubular porous materials side-by-side.

Assignees

• Univ Nanyang Tech

Inventors

• Akhondi Ebrahim
• Krantz William Bernard
• Wicaksana Filicia
• Fane Anthony Gordon

Classifications

• G01N15/082 Primary

  Investigating permeability by forcing a fluid through a sample · CPC title

• G01N15/088 Primary

  Investigating volume, surface area, size or distribution of pores; Porosimetry · CPC title

• B01D65/10

  Testing of membranes or membrane apparatus; Detecting or repairing leaks · CPC title

• B01D65/109

  Testing of membrane fouling or clogging, e.g. amount or affinity · CPC title