Low viscosity low volatility lubricating oil base stocks and methods of use thereof

Patent metadata

Field	Value
Publication number	US-10077409-B2
Application number	US-201615384421-A
Country	US
Kind code	B2
Filing date	Dec 20, 2016
Priority date	Dec 28, 2015
Publication date	Sep 18, 2018
Grant date	Sep 18, 2018

Abstract

A lubricating oil base stock including one or more monoesters represented by the formula (I), (II), (III) and (IV) as defined herein. The lubricating oil base stock has a high temperature high shear (HTHS) viscosity of less than about 1.7 cP as determined by ASTM D4683, and a Noack volatility from about 15 to about 90 percent as determined by ASTM D5800. A lubricating oil containing the lubricating oil base stock including one or more monoesters represented by the formula (I), (II), (III) and (IV) as defined herein. A method for improving one or more of thermal and oxidative stability, solubility and dispersancy of polar additives, deposit control and traction control in a lubricating oil by using as the lubricating oil a formulated oil containing the lubricating oil base stock including one or more monoesters represented by the formula (I), (II), (III) and (IV) as defined herein.

First claim

The invention claimed is:

1. A lubricating oil base stock comprising one or more compounds selected from the group consisting of 2-(2-butoxyethoxy)ethyl 2-heptylundecanoate, 2-octyldodecyl 2-(2-methoxyethoxy)acetate, 2-octyldodecyl 2-(2-(2-methoxyethoxy)ethoxy)acetate, 2-(2-butoxyethoxy)ethyl 2-hexyldecanoate, and butyl 3-(2-hexyldecylthio)propionate;
wherein said lubricating oil base stock has a high temperature high shear (HTHS) viscosity of less than about 1.7 cP as determined by ASTM D4683, and a Noack volatility from about 20 to about 90 percent as determined by ASTM D5800.

2. The lubricating oil base stock of claim 1 which has a high temperature high shear (HTHS) viscosity of less than about 1.6 cP as determined by ASTM D4683, and a Noack volatility from about 20 to about 30 percent as determined by ASTM D5800.

3. A lubricating oil comprising a lubricating oil base stock and one or more additives, said lubricating oil base stock comprising one or more compounds selected from the group consisting of 2-(2-butoxyethoxy)ethyl 2-heptylundecanoate, 2-octyldodecyl 2-(2-methoxyethoxy)acetate, 2-octyldodecyl 2-(2-(2-methoxyethoxy)ethoxy)acetate, 2-(2-butoxyethoxy)ethyl 2-hexyldecanoate, and butyl 3-(2-hexyldecylthio)propionate;
wherein said lubricating oil has a high temperature high shear (HTHS) viscosity of less than about 1.7 cP as determined by ASTM D4683, and a Noack volatility from about 20 to about 90 percent as determined by ASTM D5800.

4. The lubricating oil of claim 3 which has a high temperature high shear (HTHS) viscosity of less than about 1.6 cP as determined by ASTM D4683, and a Noack volatility from about 20 to about 30 percent as determined by ASTM D5800.

5. The lubricating oil of claim 3 wherein the one or more additives are selected from the group consisting of a viscosity improver, antioxidant, detergent, dispersant, pour point depressant, corrosion inhibitor, metal deactivator, seal compatibility additive, anti-foam agent, inhibitor, anti-rust additive and combinations thereof.

6. A lubricating oil comprising a lubricating oil base stock component, and a monoester cobase stock component; wherein said monoester cobase stock comprises one or more compounds selected from the group consisting of 2-(2-butoxyethoxy)ethyl 2-heptylundecanoate, 2-octyldodecyl 2-(2-methoxyethoxy)acetate, 2-octyldodecyl 2-(2-(2-methoxyethoxy)ethoxy)acetate, 2-(2-butoxyethoxy)ethyl 2-hexyldecanoate, and butyl 3-(2-hexyldecylthio)propionate;
wherein said lubricating oil has a high temperature high shear (HTHS) viscosity of less than about 1.7 cP as determined by ASTM D4683, and a Noack volatility from about 20 to about 90 percent as determined by ASTM D5800.

7. The lubricating oil of claim 6 wherein the lubricating oil base stock comprises a Group I, II, III, IV or V base oil stock.

8. The lubricating oil of claim 6 wherein the lubricating oil base stock comprises a polyalphaolefin (PAO) or gas-to-liquid (GTL) oil base stock.

9. The lubricating oil of claim 6 wherein the lubricating oil base stock is present in an amount from about 1 weight percent to about 99 weight percent, and the monoester cobase stock is present in an amount from about 1 weight percent to about 99 weight percent, based on the total weight of the lubricating oil.

10. The lubricating oil of claim 6 which has a high temperature high shear (HTHS) viscosity of less than about 1.6 as determined by ASTM D4683, and a Noack volatility from about 20 to about 30 percent as determined by ASTM D5800.

11. The lubricating oil of claim 6 further comprising one or more of a viscosity improver, antioxidant, detergent, dispersant, pour point depressant, corrosion inhibitor, metal deactivator, seal compatibility additive, anti-foam agent, inhibitor, and anti-rust additive.

12. A method for improving one or more of thermal and oxidative stability, solubility and dispersancy of polar additives, deposit control and traction control in a lubricating oil comprising:
providing a lubricating oil including a lubricating oil base stock component, and a monoester cobase stock component; wherein said monoester cobase stock comprises one or more compounds selected from the group consisting of 2-(2-butoxyethoxy)ethyl 2-heptylundecanoate, 2-octyldodecyl 2-(2-methoxyethoxy)acetate, 2-octyldodecyl 2-(2-(2-methoxyethoxy)ethoxy)acetate, 2-(2-butoxyethoxy)ethyl 2-hexyldecanoate, and butyl 3-(2-hexyldecylthio)propionate;
wherein said lubricating oil has a high temperature high shear (HTHS) viscosity of less than about 1.7 cP as determined by ASTM D4683, and a Noack volatility from about 20 to about 90 percent as determined by ASTM D5800, and
using the lubricating oil in a formulated oil to improve one or more of thermal and oxidative stability, solubility and dispersancy of polar additives, deposit control and traction control.

13. The method of claim 12 wherein the lubricating oil base stock comprises a Group I, II, III, IV or V base oil stock.

14. The method of claim 12 wherein the lubricating oil base stock comprises a polyalphaolefin (PAO) or gas-to-liquid (GTL) oil base stock.

15. The method of claim 12 wherein the lubricating oil base stock is present in an amount from about 1 weight percent to about 99 weight percent, and the monoester cobase stock is present in an amount from about 1 weight percent to about 99 weight percent, based on the total weight of the lubricating oil.

16. The method of claim 12 wherein the lubricating oil has a high temperature high shear (HTHS) viscosity of less than about 1.6 cP as determined by ASTM D4683, and a Noack volatility from about 20 to about 30 percent as determined by ASTM D5800.

17. The method of claim 12 wherein the lubricating oil further comprises one or more of a viscosity improver, antioxidant, detergent, dispersant, pour point depressant, corrosion inhibitor, metal deactivator, seal compatibility additive, anti-foam agent, inhibitor, and anti-rust additive.

18. The method of claim 12 wherein the lubricating oil has a MTM traction reduction of 5% versus a diioctyl adipate ester, as determined by MTM (Mini Traction Machine) traction test.

19. The method of claim 12 wherein the lubricating oil has a Noack volatility from about 20 to about 30 percent as determined by ASTM D5800.

20. The method of claim 12 wherein the lubricating oil has a TEOST 33C of less than 30 mg as determined by the TEOST 33C deposition test ASTM D6335.

21. A lubricating oil base stock comprising one or more compounds selected from the group consisting of 2-(2-butoxyethoxy)ethyl 2-heptylundecanoate, 2-octyldodecyl 2-(2-methoxyethoxy)acetate, 2-octyldodecyl 2-(2-(2-methoxyethoxy)ethoxy)acetate, 2-(2-butoxyethoxy)ethyl 2-hexyldecanoate, and butyl 3-(2-hexyldecylthio)propionate;
wherein said base stock has a viscosity (Kv100) from about 1 cSt to about 4 cSt at 100° C. as determined by ASTM D445, a Noack volatility from about 20 to about 90 percent as determined by ASTM D5800 and a viscosity index (VI) from about 100 to about 170 as determined by ASTM D2270.

22. The lubricating oil base stock of claim 21 wherein said lubricating oil base stock has a high temperature high shear (HTHS) viscosity of less than about 1.7 cP as determined by ASTM D4683.

23. The lubricating oil base stock of claim 21 which has a high temperature high shear (HTHS) viscosity of less than about 1.6 cP as determined by ASTM D4683, and a Noack volatility from about 20 to about 30 percent as determined by ASTM D5800.

24.

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Ng Man Kit
• Oumar-Mahamat Halou
• Cheng Hong
• Blain David A
• Cooper Kathleen K
• Carey James T
• Douglass Michael R
• Kanga Percy R
• Patil Abhimanyu O
• Bodige Satish
• Lewis Kyle G
• Hagemeister Mark P

Classifications

• C10M111/02

  at least one of them being a non-macromolecular organic compound · CPC title

• C07C69/708

  Ethers · CPC title

• C07C69/24

  esterified with monohydroxylic compounds · CPC title

• C10M2207/281

  of (cyclo)aliphatic monocarboxylic acids · CPC title

• C10M2207/345

  used as base material · CPC title