Coated metal plate and exterior building material

Patent metadata

Field	Value
Publication number	US-10077367-B2
Application number	US-201415128266-A
Country	US
Kind code	B2
Filing date	Mar 26, 2014
Priority date	Mar 24, 2014
Publication date	Sep 18, 2018
Grant date	Sep 18, 2018

Abstract

This coated metal plate is a chromate-free coated metal plate for exterior applications, which comprises a metal plate and a coating film that is arranged on the metal plate. The coating film contains 0.2-15 vol % of porous particles as a gloss control agent, and contains 0.2-15 vol % of primary particles as a matting agent. If R1 (μm) is the number average particle diameter of the gloss control agent, R2 (μm) is the number average particle diameter of the matting agent, T (μm) is the film thickness of the coating film, σ1 (μm) is the standard deviation of the number-based particle size distribution of the gloss control agent and σ2 (μm) is the standard deviation of the number-based particle size distribution of the matting agent, the coated metal plate satisfies the following formulae.

( R 1+2σ1)/ T ≤0.7

R 1≥2.0

2.0≤( R 2+2σ2)/ T ≤7.0

13≤ T ≤20.

First claim

The invention claimed is:

1. A coated metal sheet being chromate-free and comprising a metal sheet and an overcoat coating film disposed on the metal sheet,
wherein the metal sheet is any one selected from the group consisting of a cold-rolled steel sheet, a galvanized steel sheet, a Zn—Al alloy-plated steel sheet, a Zn—Al—Mg alloy-plated steel sheet, an aluminum-plated steel sheet, a stainless steel sheet, and a copper sheet,
wherein the overcoat coating film comprises a gloss adjusting agent which is particles having micropores and a matting agent which is primary particles,
wherein a content of the gloss adjusting agent in the overcoat coating film is 0.2 to 15 vol %,
wherein a content of the matting agent in the overcoat coating film is 0.2 to 15 vol %, and
wherein the coated metal sheet satisfies the following equations:
( R 1+2σ1)/ T≤ 0.7

R 1≥2.0

2.0≤( R 2+2σ2)/ T≤ 7.0

13 ≤T≤ 20
σ1<0.3 T

 wherein R1 (μm) is a number average particle diameter of the gloss adjusting agent, R2 (μm) is a number average particle diameter of the matting agent, T (μm) is a film thickness of the overcoat coating film, σ1 is a standard deviation of a number particle size distribution of the gloss adjusting agent, and σ2 is a standard deviation of a number particle size distribution of the matting agent.

2. The coated metal sheet according to claim 1 , further comprising an undercoat coating film between the metal sheet and the overcoat coating film.

3. The coated metal sheet according to claim 1 , wherein the gloss adjusting agent is silica.

4. The coated metal sheet according to claim 1 , wherein a value L of the overcoat coating film is 80 or less, and the film thickness T of the overcoat coating film is 15 μm or less.

5. The coated metal sheet according to claim 1 , wherein a value L of the overcoat coating film is more than 80, and the film thickness T of the overcoat coating film is more than 15 μm.

6. The coated metal sheet according to claim 1 , wherein an absolute value ΔL of a difference between a value L of the overcoat coating film and a value L of a color of a surface of the metal sheet before the overcoat coating film is formed is 10 or less, and the film thickness T of the overcoat coating film is 13 μm or less.

7. The coated metal sheet according to claim 1 , wherein an absolute value ΔL of a difference between a value L of the overcoat coating film and a value L of a color of a surface of the metal sheet before the overcoat coating film is formed is 20 or less, and the film thickness T of the overcoat coating film is 15 μm or less.

8. The coated metal sheet according to claim 1 , wherein an absolute value ΔL of a difference between a value L of the overcoat coating film and a value L of a color of a surface of the metal sheet before the overcoat coating film is formed is 50 or less, and the film thickness T of the overcoat coating film is 17 μm or less.

9. The coated metal sheet according to claim 1 , wherein the coated metal sheet has a glossiness at 75 degrees of 1 to 25.

10. The coated metal sheet according to claim 1 , wherein the coated metal sheet is a coated metal sheet for exterior use.

11. An exterior building material composed of the coated metal sheet according to claim 1 .

12. The exterior building material according to claim 11 , further comprising one or more selected from the group consisting of members to fix the exterior building material to a building, members to connect a plurality of the exterior building materials, marks that show a direction of the exterior building material on mounting, and foam sheets or foam layers to improve thermal insulation properties.

13. A coated metal sheet being chromate-free and comprising a metal sheet and an overcoat coating film to be disposed on the metal sheet,
wherein the metal sheet is any one selected from the group consisting of a cold-rolled steel sheet, a galvanized steel sheet, a Zn—Al alloy-plated steel sheet, a Zn—Al—Mg alloy-plated steel sheet, an aluminum-plated steel sheet, a stainless steel sheet, and a copper sheet,
wherein the overcoat coating film comprises a gloss adjusting agent which is particles having micropores and a matting agent which is primary particles,
wherein a content of the gloss adjusting agent in the overcoat coating film is 0.2 to 15 vol %,
wherein a content of the matting agent in the overcoat coating film is 0.2 to 15 vol %, and
wherein the coated metal sheet satisfies the following equations:
R 1≥2.0

2.0≤( R 2+2σ2)/ T≤ 7.0

13 ≤T≤ 20

wherein R1 (μm) is a number average particle diameter of the gloss adjusting agent, R2 (μm) is a number average particle diameter of the matting agent, T (μm) is a film thickness of the overcoat coating film, and σ2 is a standard deviation of a number particle size distribution of the matting agent, and a maximum value of a particle diameter in a number particle size distribution of the gloss adjusting agent is 0.7T or less.

14. The coated metal sheet according to claim 13 , wherein the maximum value of the particle diameter in the number particle size distribution of the gloss adjusting agent is 0.6T or less.

15. The coated metal sheet according to claim 13 , further comprising an undercoat coating film between the metal sheet and the overcoat coating film.

16. The coated metal sheet according to claim 13 , wherein the gloss adjusting agent is silica.

17. The coated metal sheet according to claim 13 , wherein a value L of the overcoat coating film is 80 or less, and the film thickness T of the overcoat coating film is 15 μm or less.

18. The coated metal sheet according to claim 13 , wherein a value L of the overcoat coating film is more than 80, and the film thickness T of the overcoat coating film is more than 15 μm.

19. The coated metal sheet according to claim 13 , wherein an absolute value ΔL of a difference between a value L of the overcoat coating film and a value L of a color of a surface of the metal sheet before the overcoat coating film is formed is 10 or less, and the film thickness T of the overcoat coating film is 13 μm or less.

20. The coated metal sheet according to claim 13 , wherein an absolute value ΔL of a difference between a value L of the overcoat coating film and a value L of a color of a surface of the metal sheet before the overcoat coating film is formed is 20 or less, and the film thickness T of the overcoat coating film is 15 μm or less.

21. The coated metal sheet according to claim 13 , wherein an absolute value ΔL of a difference between a value L of the overcoat coating film and a value L of a color of a surface of the metal sheet before the overcoat coating film is formed is 50 or less, and the film thickness T of the overcoat coating film is 17 μm or less.

22. The coated metal sheet according to claim 13 , wherein the coated metal sheet has a glossiness at 75 degrees of 1 to 25.

23. The coated metal sheet according to claim 13 , wherein the coated metal sheet is a coated metal sheet for exterior use.

24. An exterior building material composed of the coated metal sheet according to claim 23 .

25. The exterior building material according to claim 24 , further comprising one or more selected from the group consisting of members to fix the exterior building material to a building, members to connect a plurality of the exterior building materials, marks that show a direction of the exterior building material on mounting, and f

Assignees

• Nisshin Steel Co Ltd

Inventors

• Hara Taketo
• Yano Hirokazu
• Sakato Kenji
• Takahashi Kazuhiko

Classifications

• C09D7/69

  Particle size larger than 1000 nm · CPC title

• C09D5/08

  Anti-corrosive paints · CPC title

• C09D7/61

  inorganic · CPC title

• C09D5/082

  characterised by the anti-corrosive pigment · CPC title

• C09G1/00

  Polishing compositions (French polish C09F11/00; detergents C11D) · CPC title