Plasticizer compositions and methods for making plasticizer compositions

Patent metadata

Field	Value
Publication number	US-10077355-B2
Application number	US-201615335532-A
Country	US
Kind code	B2
Filing date	Oct 27, 2016
Priority date	Feb 8, 2012
Publication date	Sep 18, 2018
Grant date	Sep 18, 2018

Abstract

The present disclosure is directed to a plasticizer composition, polymeric compositions containing the plasticizer composition, and conductors coated with the polymeric composition. The plasticizer composition includes a first plasticizer comprising epoxidized fatty acid alkyl esters and a second plasticizer comprising an epoxidized natural oil. The plasticizer composition, first plasticizer, and/or second plasticizer can undergo one or more color-reducing treatment processes, such as distillation, filtration, and/or peroxide treatment.

First claim

The invention claimed is:

1. A method for producing a treated plasticizer, said method comprising:
(a) combining a first plasticizer and a second plasticizer to thereby form a plasticizer composition, wherein said first plasticizer comprises epoxidized fatty acid alkyl esters, wherein said second plasticizer comprises an epoxidized natural oil; and
(b) subjecting said first plasticizer, said second plasticizer, and/or said plasticizer composition to one or more color-reducing treatment processes to thereby produce said treated plasticizer,
wherein said color-reducing treatment process is selected from the group consisting of:
(i) contacting at least a portion of said first plasticizer, said second plasticizer, and/or said plasticizer composition with a peroxide;
(ii) filtering at least a portion of said first plasticizer, said second plasticizer, and/or said plasticizer composition;
(iii) distilling at least a portion of said first plasticizer prior to said combining of step (a); and
(iv) mixtures of two or more thereof,
wherein said color-reducing treatment process comprises process (iii), wherein said distillation is performed at a temperature in the range of from 120 to 180° C.

2. The method of claim 1 , wherein said epoxidized fatty acid alkyl esters are epoxidized fatty acid methyl esters, wherein said epoxidized natural oil is an epoxidized soybean oil.

3. The method of claim 1 , wherein said color-reducing treatment process further comprises process (i), wherein said peroxide is hydrogen peroxide.

4. The method of claim 1 , wherein said color-reducing treatment process further comprises process (ii), wherein said filtering is performed by passing at least a portion of said first plasticizer, said second plasticizer, and/or said plasticizer composition through a filter media selected from the group consisting of synthetic magnesium silicate, bleaching clay, montmorillonite clay, fuller's earth clay, activated alumina, perlite, and mixtures of two or more thereof.

5. The method of claim 1 , wherein said first plasticizer has an APHA value of less than 100 upon heat aging at 190° C. for 60 minutes following said color-reducing treatment process.

6. The method of claim 1 , wherein said plasticizer composition has an APHA value that is less than the APHA value of an identical reference plasticizer composition that has not undergone any of said color-reducing treatment processes of step (b) upon heat aging both said plasticizer composition and said reference plasticizer composition at 190° C. for 60 minutes.

Assignees

• Dow Global Technologies Llc

Inventors

• Mundra Manish
• Ghosh-Dastidar Abhijit
• Eaton Robert F
• Fu Lin
• Campbell Robert M
• Bell Bruce M

Classifications

• C08K5/1515

  Three-membered rings · CPC title

• C07D301/32

  Separation; Purification · CPC title

• C08K9/02 Primary

  Ingredients treated with inorganic substances · CPC title

• C08K5/0016 Primary

  Plasticisers · CPC title