Elastomeric compositions comprising cellulose ester additives

Patent metadata

Field	Value
Publication number	US-10077342-B2
Application number	US-201715409644-A
Country	US
Kind code	B2
Filing date	Jan 19, 2017
Priority date	Jan 21, 2016
Publication date	Sep 18, 2018
Grant date	Sep 18, 2018

Abstract

An elastomeric composition is provided comprising at least one elastomer, at least one cellulose ester additive, at least one methylene acceptor, at least one methylene donor, and optionally, at least one filler; wherein the cellulose ester additive comprises at least one cellulose ester. The cellulose ester additive can also comprise at least one compatibilizer and/or plasticizer.

First claim

That which is claimed is:

1. An elastomeric composition comprising at least one elastomer, at least one cellulose ester additive, at least one methylene acceptor, at least one methylene donor, and optionally, at least one filler; wherein said cellulose ester additive comprises at least one cellulose ester; and wherein said cellulose ester additive is not cellulose acetate.

2. The elastomeric composition according to claim 1 wherein said cellulose ester additive further comprises at least one plasticizer.

3. The elastomeric composition according to claim 1 wherein said cellulose ester additive further comprises at least one compatibilizer.

4. The elastomeric composition according to claim 1 wherein said cellulose ester additive further comprises at least one plasticizer and at least on compatibilizer.

5. The elastomeric composition according to claim 1 wherein said elastomer is selected from the group consisting of polyisoprene rubber, poly(styrene-co-butadiene) rubber (SBR), polybutadiene rubber (BR), poly(isoprene-co-butadiene) rubber (IBR), styrene-isoprene-butadiene rubber (SIBR), ethylene-propylene rubber (EPM), ethylene-propylene-diene rubber (EPDM), polysulfide, nitrile rubber, propylene oxide polymers, butyl rubber, halogenated butyl rubber, brominated butyl rubber, chlorinated butyl rubber, star-branched polyisobutylene rubber, star-branched brominated butyl (polyisobutylene/isoprene copolymer) rubber; poly(isobutylene-co-p-methylstyrene) and halogenated poly(isobutylene-co-p-methylstyrene).

6. The elastomeric composition according to claim 1 wherein said elastomer is a non-polar elastomer.

7. The elastomeric composition according to claim 1 wherein said elastomer is a non-nitrile elastomer.

8. The elastomeric composition according to claim 1 wherein said cellulose ester additive in said elastomeric composition ranges from about 0.5 to about 40 phr.

9. The elastomeric composition according to claim 2 wherein said plasticizer is at least one selected from the group consisting of a phosphate plasticizer, benzoate plasticizer, adipate plasticizer, a phthalate plasticizer, a glycolic acid ester, a citric acid ester plasticizer and a hydroxyl-functional plasticizer.

10. The elastomeric composition according to claim 1 wherein said compatibilizer is selected from the group consisting of ethoxylated alcohols, ethoxylated alkylphenols, ethoxylated fatty acids, block polymers of propylene oxide and ethylene oxide, polyglycerol esters, polysaccharide esters, and sorbitan esters.

11. The elastomeric composition according to claim 1 wherein said methylene acceptor is at least one selected from the group consisting of melamine resins urea, polycarbonate resins, phenolic thermosetting resins, epoxy resins, unsaturated polyester resins, acrylic resins, guanamine resins, and polyurethane resins.

12. The elastomeric composition according to claim 11 wherein said phenolic thermosetting resin is at least one selected from the group consisting of modified and unmodified phenolic resins, cashew-modified phenolic resins, oil-modified phenolic resins, cresol modified phenolic resins, cashew-modified cresol resins, oil-modified cresol resins, novolac xylenol resin, novolac resorcinol resins, and polyvinylphenol resins.

13. The elastomeric composition according to claim 1 wherein said methylene acceptor is a resole resin or novolac resin.

14. The elastomeric composition according to claim 1 wherein the amount of said methylene acceptor ranges from about 0.1 to about 50 phr, based on the total weight of said elastomers.

15. The elastomeric composition according to claim 1 wherein the amount of said methylene acceptor ranges from about 2 to about 25 phr, based on the total weight of said elastomers.

16. The elastomeric composition according to claim 1 wherein said methylene donor is a condensation product of melamine and formaldehyde or a condensation produce of melamine, formaldehyde, and methanol.

17. The elastomeric composition according to claim 1 wherein said methylene donor is at least one selected from the group consisting of hexamethylenetetramine, hexamethoxymethylmelamine, hexaethoxymethylmelamine, iminomethoxymethylmelamine, imino-isobutoxymethylmelamine, lauryloxymethylpyridinium chloride, ethoxymethylpyridinium chloride, trioxan hexamethoxymethylmelamine, and polymers of formaldehyde.

18. The elastomeric composition of claim 1 wherein the amount of said methylene donor ranges from about 0.01 to about 10 phr, based on the total weight of said elastomers.

19. An article comprising said elastomeric composition of claim 1 .

20. The article according to claim 19 wherein said article is selected from the group consisting of tire components, blow-out preventers, hoses, weather stripping, belts, injection molded parts, footwear, pharmaceutical closures, plant lining, flooring, power cables, gaskets, seals, rubber rollers, architectural trims, pump pistons, well head seals, valve seals, drilling hoses, pump stators, drill pipe protectors, down-hole packers, inflatable packers, drill motors, o-rings, cable jackets, pressure accumulators, swab cups, and bonded seals.

Assignees

• Eastman Chem Co

Inventors

• An Haining
• Vargantwar Pruthesh Hariharrao
• Helmer Bradley James
• Arigo Mark
• Basu Soumendra Kumar

Classifications

• C08J2309/06

  Copolymers with styrene · CPC title

• C08J3/22 Primary

  using masterbatch techniques · CPC title

• C08L7/00 Primary

  Compositions of natural rubber · CPC title

• C08J2401/10

  Esters of organic acids · CPC title

• C08J2409/06

  Copolymers with styrene · CPC title