Storage stable foamable compositions containing 1,1,1,4,4,4-hexafluoro-2-butene

Patent metadata

Field	Value
Publication number	US-10077330-B2
Application number	US-201414771981-A
Country	US
Kind code	B2
Filing date	Mar 4, 2014
Priority date	Mar 6, 2013
Publication date	Sep 18, 2018
Grant date	Sep 18, 2018

Abstract

In certain non-limiting, aspects, the present invention relates to storage stable premixes of a polyol suitable for polyurethane or polyisocyanurate foam preparation having, at least, 1,1,1,4,4,4-hexafluoro-2-butene (1336mzzm) as the blowing agent and optional one or more additional additives and/or auxiliary blowing agents in amounts suitable for polyurethane or polyisocyanurate foam preparation.

First claim

What is claimed is:

1. A method of forming a foam comprising;
(a) forming at a first point in time a storage stable premix for foam manufacture, said storage stable premix composition comprising: (i) from about 5% to about 25% by weight of a blowing agent composition comprising, based on the components in the blowing agent composition, from about 7% to about 80% by weight of 1,1,1,4,4,4-hexafluoro-2-butene (1336mzzm) and from about 10% to about 95% by weight of water, (ii) from about 60% to about 95% by weight of one or more polyols, (iii) from about 0.5% to about 5% by weight of one or more surfactants, and (iv) from about 0.25% to about 3% by weight of N,N,N′,N″,N″-pentamethyldiethyltriamine as a tertiary amine catalyst;
(b) forming a foam from said storage stable premix at a second point in time at least 7 days after said first point in time, wherein said premix is formed under conditions effective to ensure that substantially no reaction occurs between said blowing agent and said N,N,N′,N″,N″-pentamethyldiethyltriamine catalyst for said at least said 7 days, wherein said said premix composition does not contain 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd).

2. The method of claim 1 , wherein the blowing agent further comprises a co-blowing agent selected from the group consisting of hydrocarbon, fluorocarbon, chlorocarbon, hydrochlorofluorocarbon, hydrofluorocarbon, halogenated hydrocarbon, ether, ester, alcohol, aldehyde, ketone, organic acid, gas generating material, and combinations thereof.

3. The method of claim 2 , wherein the co-blowing agent is selected from the group consisting of 1,3,3,3-tetrafluoropropene, organic acids that produce CO2 and/or CO, a pentane, a butane, methylal, methyl formate, 1,1,1,3,3-pentafluorobutane (HFC-365mfc); 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea), 1,1,1,3,3-pentafluoropropane (HFC-245fa); trans-1,2-dichloroethylene; 1,1-difluoroethane (HFC-152a); and combinations thereof.

4. The method of claim 1 , wherein said premix composition further comprises a non-amine catalyst.

5. The method of claim 1 , wherein said surfactant comprises a silicone surfactant.

6. The method of claim 1 , wherein the foam is formed from said storage stable premix at a second point in time at least 14 days after said first point in time, wherein said premix is formed under conditions effective to ensure that substantially no reaction occurs between said 1,1,1,4,4,4-hexafluoro-2-butene (1336mzzm) and said N,N,N′,N″,N″-pentamethyldiethyltriamine catalyst for said at least said 14 days.

7. The method of claim 1 , wherein the foam is formed from said storage stable premix at a second point in time at least 30 days after said first point in time, wherein said premix is formed under conditions effective to ensure that substantially no reaction occurs between said 1,1,1,4,4,4-hexafluoro-2-butene (1336mzzm) and said N,N,N′,N″,N″-pentamethyldiethyltriamine catalyst for said at least said 30 days.

8. A method of forming a foam comprising;
(a) forming at a first point in time a storage stable premix for foam manufacture, said storage stable premix composition comprising: (i) from about 5% to about 25% by weight a blowing agent composition comprising, based on the components in the blowing agent composition, from about 7% to about 80% by weight of 1,1,1,4,4,4-hexafluoro-2-butene (1336mzzm) and from about 10% to about 95% by weight of water, (ii) from about 60% to about 95% by weight of one or more polyols, (iii) from about 0.5% to about 5% by weight of one or more surfactants, and (iv) from about 0.25% to about 3% by weight of N,N,N′,N″,N″-pentamethyldiethyltriamine as a tertiary amine catalyst;
(b) forming a foam from said storage stable premix at a second point in time at least 7 days after said first point in time, wherein said premix is formed under conditions effective to ensure that substantially no reaction occurs between said blowing agent and said N,N,N′,N″,N″-pentamethyldiethyltriamine catalyst during said 7 days, wherein said premix composition does not contain 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd).

9. The method of claim 8 , further comprising a co-blowing agent that is selected from the group consisting of 1,3,3,3-tetrafluoropropene, organic acids that produce CO2 and/or CO, a pentane, a butane, methylal, methyl formate, 1,1,1,3,3-pentafluorobutane (HFC-365mfc); 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ca), 1,1,1,3,3-pentafluoropropane (HFC-245 fa); trans-1,2-dichloroethylene; 1,1-difluoroethane (HFC-152a); and combinations thereof.

Assignees

• Honeywell Int Inc

Inventors

• Van Der Puy Michael
• Williams David J

Classifications

• C08G2101/0025

  Chemistry & Metallurgy · mapped topic

• C08J9/02

  using blowing gases generated by the reacting monomers or modifying agents during the preparation or modification of macromolecules · CPC title

• C08J2375/04

  Polyurethanes · CPC title

• C08G18/4816

  mixtures of two or more polyetherpolyols having at least three hydroxy groups · CPC title

• C08G18/3206 Primary

  aliphatic · CPC title