Process for converting a heavy feed into middle distillate

Patent metadata

Field	Value
Publication number	US-10077218-B2
Application number	US-201113989590-A
Country	US
Kind code	B2
Filing date	Nov 3, 2011
Priority date	Nov 25, 2010
Publication date	Sep 18, 2018
Grant date	Sep 18, 2018

Abstract

The present invention describes a process for the conversion of a heavy feed which can be used to improve the selectivity for middle distillate. The process employs a catalytic cracking unit followed by one or more units for the oligomerization of C2 to C9 olefins which can preferentially produce an additional cut termed the middle distillate. The light portion of the oligomerate produced which cannot be incorporated into the middle distillate cut is recycled to the FCC unit for cracking into light olefins which are returned to the oligomerization units as a supplement to the olefins of the feed in order to preferentially form heavy oligomerates which can be incorporated into the middle distillate cut.

First claim

The invention claimed is:

1. A process for the conversion of a heavy hydrocarbon feed with an initial boiling point of 340° C. or more into a middle distillate having a distillation range of from 130° C. to 410° C., said process comprising:
catalytically cracking the heavy hydrocarbon feed in a catalytic cracking unit ( 2 ) to obtain a wide cut ( 7 ) containing 2 to 9 carbon atoms and the middle distillate;
optionally hydrotreating the wide cut ( 7 ) in a hydrotreatment unit ( 8 );
oligomerizing the optionally hydrotreated wide cut ( 7 ) in an oligomerization unit ( 12 ) under operating conditions of a temperature in the range of 100° C. to 350° C. and a pressure in the range 1 to 10 MPa to obtain an effluent;
separating the effluent from the oligomerization unit ( 12 ) into three cuts:
a raffinate cut ( 13 ) comprising unconverted olefins and paraffins of the feed ( 7 );
a light oligomerate cut ( 15 ) with a boiling point of less than 180° C.;
a heavy oligomerate cut ( 14 ) with a boiling point of more than 130° C.;

recycling the light oligomerate cut ( 15 ) as a secondary feed to the catalytic cracking unit ( 2 ) for catalytic cracking; and
adding the heavy oligomerate cut ( 14 ) to the middle distillate produced by the catalytic cracking.

2. The process of claim 1 , wherein a cut ( 17 ) which comprises C2 to C9 olefins is added to the catalytic cracking unit ( 2 ) either by mixing the cut ( 17 ) with the light oligomerate cut ( 15 ) before the light oligomerate cut ( 15 ) is recycled or by adding the cut ( 17 ) directly to the catalytic cracking unit ( 2 ).

3. The process of claim 2 , wherein the cut ( 17 ) which comprises C2 to C9 olefins is formed from a C3 to C6 cut and a C8 to C9 cut, wherein each of the C3 to C6 cut and the C8 to C9 cut is derived from a process selected from the group consisting of: a coking process, a visbreasking process, an alcohol to olefins conversion process, a steam cracking process, and a Fischer-Tropsch synthesis process.

4. The process of claim 1 , wherein the catalytic cracking unit ( 2 ) comprises a single riser in an upward flow mode and is operated at a reactor outlet temperature in the range of 450° C. to 650° C. and a C/O ratio in the range of 2 to 20.

5. The process of claim 1 , wherein the catalytic cracking unit ( 2 ) comprises a single riser in an upward flow mode and is operated at a reactor outlet temperature in the range of 470° C. to 620° C. and a C/O ratio in the range of 4 to 15.

6. The process of claim 1 , wherein the catalytic cracking unit ( 2 ) comprises two distinct riser reactors, wherein:
one riser reactor treats the heavy hydrocarbon feed under the following conditions: a reactor outlet temperature in the range of 450° C. to 640° C. and a C/O ratio in the range of 2 to 20; and
the other riser reactor treats the recycled light oligomerate cut under the following conditions: a reactor outlet temperature in the range of 500° C. to 750° C. and a C/O ratio in the range of 8 to 40.

7. The process of claim 1 , wherein the catalytic cracking unit ( 2 ) comprises two distinct riser reactors, wherein:
one riser reactor treats the heavy hydrocarbon feed under the following conditions: a reactor outlet temperature in the range of 470° C. to 620° C. and a C/O ratio in the range of 4 to 15; and
the other riser reactor treats the recycled light oligomerate cut under the following conditions: a reactor outlet temperature in the range of 570° C. to 650° C. and a C/O ratio in the range of 8 to 40.

8. The process of claim 1 , wherein the catalytic cracking unit ( 2 ) comprises a catalyst and the catalyst comprises a zeolite with form selectivity selected from the group consisting of: MEL, MFI, NES, EUO, FER, CHA, MFS and MWW.

9. The process of claim 8 , wherein the zeolite with said form selectivity is selected from the group consisting of: ZSM-11, ZSM-5 and SAPO-34.

10. The process of claim 8 , wherein the proportion of zeolite with said form selectivity, with respect to the weight of the catalyst, is in the range of 5% to 40%.

11. The process of claim 1 , wherein the catalytic cracking unit ( 2 ) comprises a catalyst and the catalyst comprises a zeolite with form selectivity selected from the group consisting of: NU-85, NU-86, NU-88 and IM-5.

12. The process of claim 1 , wherein:
the middle distillate has a distillation range of from 150° C. to 390° C.;
the oligomerization unit ( 12 ) operates at a temperature in the range from 150° C. to 270° C.;
the light oligomerate cut ( 15 ) has a boiling point of less than 150° C.; and
the heavy oligomerate cut ( 14 ) has a boiling point of more than 150° C.

Assignees

• Feugnet Frederic
• Hugues Francois
• Do Mai Phuong
• Roux Romain
• Ifp Energies Now

Inventors

• Feugnet Frederic
• Hugues Francois
• Do Mai Phuong
• Roux Romain

Classifications

• C10G2300/4006

  Temperature · CPC title

• C10G2300/4012

  Pressure · CPC title

• C07C2/06 Primary

  of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• C10G50/00

  Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation · CPC title

• C10G57/02

  with polymerisation · CPC title