Laminated glass structures having high glass to polymer interlayer adhesion
US-2016082705-A1 · Mar 24, 2016 · US
US10077204B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10077204-B2 |
| Application number | US-201514814335-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 30, 2015 |
| Priority date | Jul 31, 2014 |
| Publication date | Sep 18, 2018 |
| Grant date | Sep 18, 2018 |
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A strengthened glass sheet product along with a process and an apparatus for strengthening a glass sheet are provided. The process comprises cooling the glass sheet by non-contact thermal conduction for sufficiently long to fix a surface compression and central tension of the sheet. The process results in thermally strengthened glass sheets having improved breakage properties.
Opening claim text (preview).
What is claimed is: 1. A thermally strengthened glass sheet: the glass sheet having a thickness, expressed in millimeters, of t, a length, expressed in millimeters, of l, and a width, expressed in millimeters, of w, t being less than l and less than w; the glass sheet comprising a glass having a low temperature linear CTE, expressed in 1/° C., of α S CTE , a high temperature linear CTE, expressed in 1/° C., of α L CTE , an elastic modulus, expressed in GPa, of E, a strain temperature, expressed in units of ° C., of T strain , and a softening temperature, expressed in units of ° C., of T soft ; the glass sheet having a thermally induced central tension of less than 300 MPa and greater than P 1 CT ( h CT ) * t 2 ( 2 P 2 CT ( h CT ) + t ) · E · [ T strain · α CTE s + α CTE L · ( T soft - T strain ) ] ; in units of MPa; wherein P 1CT is given by 910.2 - 259.2 · exp ( - h CT 0.143 ) ; P 2CT is given by 2.53 + 23.65 ( 1 + ( h CT 0.00738 ) 1.58 ) ; and wherein h CT is a constant greater than or equal to 0.020, wherein the first major surface has a roughness in the range of from 0.2 to 0.4 nm Ra over an area of 10 μm×10 μm. 2. The glass sheet according to claim 1 wherein h CT is greater than or equal to 0.022. 3. The glass sheet according to claim 1 wherein h CT is greater than or equal to 0.024. 4. The glass sheet according to claim 1 wherein h CT is greater than or equal to 0.026. 5. The glass sheet according to claim 1 wherein h CT is greater than or equal to 0.028. 6. The glass sheet according to claim 1 wherein h CT is greater than or equal to 0.030. 7. The glass sheet according to claim 1 wherein h CT is greater than or equal to 0.0625. 8. The glass sheet according to claim 1 wherein h CT is greater than or equal to 0.065. 9. The glass sheet according to claim 1 wherein the first surface of the sheet is flat to 50 μm total indicator run-out (TIR) along any 50 mm or less profile of the first major surface. 10. The glass sheet according to claim 1 wherein the first major surface has a roughness in the range of from 0.2 to 0.3 nm Ra over an area of 10 μm×10 μm. 11. The glass sheet according to claim 1 wherein the first major surface has a coating. 12. The glass sheet according to claim 1 , l and w each being at least 10 mm. 13. The glass sheet according to claim 1 , l and w each being at least 40 mm. 14. The glass sheet according to claim 1 , wherein the ratio l/t and the ratio w/t each are equal to 10/1 or more. 15. The glass sheet according to claim 13 , wherein the ratio l/t and the ratio w/t each are equal to 20/1 or more. 16. The glass sheet according to claim 1 , wherein the ratio l/t and the ratio w/t each are equal to 100/1 or more. 17. The glass sheet according to claim 1 wherein t is 6 mm or less. 18. The glass sheet according to claim 1 wherein t is 3 mm or less. 19. The glass sheet according to claim 1 wherein t is less than 2 mm. 20. The glass sheet according to claim 1 wherein t is 1 mm or less. 21. The glass sheet according to claim 15 wherein t is 0.7 mm or less. 22. The glass sheet according to claim 1 wherein t is 0.5 mm or less. 23. The glass sheet accordi
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