Multilayered structure, inner liner having the same, and pneumatic tire

Patent metadata

Field	Value
Publication number	US-10076932-B2
Application number	US-201013877126-A
Country	US
Kind code	B2
Filing date	Nov 30, 2010
Priority date	Oct 1, 2010
Publication date	Sep 18, 2018
Grant date	Sep 18, 2018

Abstract

A multilayered structure having a layer A constituted with a resin composition containing a gas barrier resin, and a layer B being adjacent to the layer A and being constituted with a resin composition containing an elastomer. The total number of the layer A and the layer B is at least 7. The average thickness of the layer A in terms of a single layer is no less than 0.001 μm and no greater than 10 μm, and the average thickness of the layer B in terms of a single layer is no less than 0.001 μm and no greater than 40 μm. The multilayered structure is formed by irradiating with an active energy ray. Furthermore, an inner liner having the multilayered structure, and a pneumatic tire provided with the inner liner are provided.

First claim

The invention claimed is:

1. A multilayered structure comprising:
a layer A comprising a resin composition comprising a gas barrier resin; and
a layer B being adjacent to the layer A and comprising a resin composition comprising an elastomer,
a total number of the layer A and the layer B being at least 17,
an average thickness of the layer A in terms of a single layer being no less than 0.02 μm and no greater than 3 μm, and an average thickness of the layer B in terms of a single layer being no less than 0.02 μm and no greater than 10 μm,
the multilayered structure being formed by irradiating with an active energy ray,
the layer A comprising only the gas barrier resin as a polymer, and
the gas barrier resin having an oxygen transmission rate of no greater than 100 mL·20 μm/(m 2 ·day·atm) as determined according to a method described in JIS-K7126 (isopiestic method) under conditions including 20° C. and 65% RH.

2. The multilayered structure of claim 1 , wherein the layer A and the layer B are alternately laminated.

3. The multilayered structure of claim 1 , having a thickness of no less than 0.1 μm and no greater than 1,000 μm.

4. The multilayered structure of claim 1 , wherein the elastomer is a polystyrene based elastomer, a polyolefin based elastomer, a polydiene based elastomer, a polyvinyl chloride based elastomer, a chlorinated polyethylene based elastomer, a polyurethane based elastomer, a polyester based elastomer, a polyamide based elastomer, a fluorocarbon resin based elastomer, or a combination thereof.

5. The multilayered structure of claim 1 , wherein
the resin composition in at least one of the layer A and the layer B comprises a metal salt, and
a content of the metal salt is no less than 1 ppm by mass and no greater than 10,000 ppm by mass in a value of metal element.

6. The multilayered structure of claim 1 , wherein
the resin composition in at least one of the layer A and the layer B comprises a radical cross-linking agent, and
a content of the radical cross-linking agent with respect to the resin composition before irradiation with an active energy ray is no less than 0.01% by mass and no greater than 10% by mass.

7. The multilayered structure of claim 1 , wherein the gas barrier resin is an ethylene-vinyl alcohol copolymer.

8. The multilayered structure of claim 7 , wherein a content of ethylene unit of the ethylene-vinyl alcohol copolymer is no less than 3 mol % and no greater than 70 mol %.

9. The multilayered structure of claim 7 , wherein a degree of saponification of the ethylene-vinyl alcohol copolymer is no less than 80 mol %.

10. The multilayered structure of claim 7 , wherein the ethylene-vinyl alcohol copolymer comprises a structural unit represented by the following formula (I):

wherein, R 1 , R 2 and R 3 each independently represent a hydrogen atom, an aliphatic hydrocarbon group having 1 to 10 carbon atoms, an alicyclic hydrocarbon group having 3 to 10 carbon atoms, an aromatic hydrocarbon group having 6 to 10 carbon atoms or a hydroxyl group, wherein two among R 1 , R 2 and R 3 may bind with one another unless the two among R 1 , R 2 and R 3 both represent a hydrogen atom, and wherein the aliphatic hydrocarbon group having 1 to 10 carbon atoms, the alicyclic hydrocarbon group having 3 to 10 carbon atoms or the aromatic hydrocarbon group having 6 to 10 carbon atoms may have a hydroxyl group, a carboxyl group or a halogen atom,
a structural unit represented by the following formula (II):

wherein, R 4 , R 5 , R 6 and R 7 each independently represent a hydrogen atom, an aliphatic hydrocarbon group having 1 to 10 carbon atoms, an alicyclic hydrocarbon group having 3 to 10 carbon atoms, an aromatic hydrocarbon group having 6 to 10 carbon atoms or a hydroxyl group, wherein R 4 and R 5 or R 6 and R 7 may bind with one another unless both R 4 and R 5 or both R 6 and R 7 represent a hydrogen atom, and wherein the aliphatic hydrocarbon group having 1 to 10 carbon atoms, the alicyclic hydrocarbon group having 3 to 10 carbon atoms or the aromatic hydrocarbon group having 6 to 10 carbon atoms may have a hydroxyl group, an alkoxy group, a carboxyl group or a halogen atom,
or a combination of these structural units,
and wherein a content of the structural unit (I) or (II) with respect to the entire structural units is no less than 0.5 mol % and no greater than 30 mol %.

11. The multilayered structure of claim 1 , wherein the active energy ray is an electron beam.

12. The multilayered structure of claim 11 , wherein the electron beam is irradiated by an electron beam accelerator at an accelerating voltage of no less than 100 kV and no greater than 500 kV, and at an irradiation dose of no less than 5 kGy and no greater than 600 kGy.

13. The multilayered structure of claim 1 , wherein an interlayer peel resistance as determined after heating at 180° C. for 15 min, by a T-shape peel test in accordance with JIS-K6854 at 23° C. in an atmosphere of 50% RH, at a tension rate of 50 mm/min is no less than 25 N/25 mm.

14. An inner liner for pneumatic tires, comprising the multilayered structure of claim 1 .

15. A pneumatic tire, comprising the inner liner of claim 14 .

16. The multilayered structure of claim 1 , wherein the average thickness of the layer A in terms of a single layer is from 0.02 μm to 1.8 μm, and the average thickness of the layer B in terms of a single layer is from 0.02 μm to 1.8 μm.

17. The multilayered structure of claim 1 , wherein the total number of the layer A and the layer B is at least 33.

18. The multilayered structure of claim 1 , wherein a ratio of the average thickness of the layer B in terms of a single layer to the average thickness of the layer A in terms of a single layer (layer B/layer A) is no less than 2.

Assignees

• Takahashi Yuwa
• Tai Shinji
• Hikasa Masao
• Kitano Hideki
• Amamoto Tetsuo
• Tanaka Takatsugu
• Kuraray Co
• Bridgestone Corp

Inventors

• Takahashi Yuwa
• Tai Shinji
• Hikasa Masao
• Kitano Hideki
• Amamoto Tetsuo
• Tanaka Takatsugu

Classifications

• Y10T428/24967

  Absolute thicknesses specified · CPC title

• B32B27/304

  comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF · CPC title

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title

• C08G18/4238

  derived from dicarboxylic acids and dialcohols · CPC title

• B32B27/327

  comprising polyolefins obtained by a metallocene or single-site catalyst · CPC title