Pesticidal mixtures

Patent metadata

Field	Value
Publication number	US-10076119-B2
Application number	US-201314443520-A
Country	US
Kind code	B2
Filing date	Nov 18, 2013
Priority date	Nov 22, 2012
Publication date	Sep 18, 2018
Grant date	Sep 18, 2018

Abstract

The present invention relates to pesticidal mixtures comprising one biological compound and at least one fungicidal, insecticidal or plant growth regulating compound as defined herein and respective agricultural uses thereof.

First claim

The invention claimed is:

1. A mixture comprising:
1) a fungicidal compound IA selected from the group consisting of: Inhibitors of complex III at Qo site: coumethoxystrobin, coumoxystrobin, dimoxy-strobin, enestroburin, fenaminstrobin, fenoxystrobin/flufenoxystrobin, fluoxastrobin, kresoxim-methyl, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyrametostrobin, pyraoxystrobin, and pyribencarb;
inhibitors of complex II: flutolanil, bixafen, boscalid, carboxin, fluopyram, fluxapyroxad, isopyrazam, oxycarboxin, penflufen, penthiopyrad, sedaxane, N-(4′-trifluoromethylthiobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(2-(1,3,3-trimethyl-butyl)-phenyl)-1,3-dimethyl-5-fluoro-1H-pyrazole-4-carboxamide, benzovindiflupyr, 3-(difluoromethyl)-1-methyl-N-(1,1,3-tri-methylindan-4-yl)pyrazole-4-carboxamide, 3-(trifluoromethyl)-1-methyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4-carboxamide, 1,3-dimethyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4-carboxamide, 3-(trifluoromethyl)-1,5-dimethyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4-carboxamide, 3-(difluoromethyl)-1,5-dimethyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4-carboxamide, 1,3,5-trimethyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4-carboxamide;
silthiofam;
C14 demethylase inhibitors: bitertanol, difenoconazole, diniconazole, diniconazole-M, epoxiconazole, fluquinconazole, flutriafol, ipconazole, metconazole, prothioconazole, simeconazole, tebuconazole, tetraconazole, triadimenol, triticonazole, 1-[rel-(2S;3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)-oxiranylmethyl]-5-thio-cyanato-1H-[1,2,4]triazole, 2-[rel-(2S,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)-oxiranylmethyl]-2H-[1,2,4]triazole-3-thiol, imazalil, pefurazoate, prochloraz;
Nucleic acid synthesis inhibitors: benalaxyl, benalaxyl-M, kiralaxyl, metalaxyl, oxadixyl, hymexazole, oxolinic acid,5-fluoro-2-(p-tolylmethoxy)pyrimidin-4-amine, 5-fluoro-2-(4-fluorophenylmethoxy)pyrimidin-4-amine;
Inhibitors of amino acid and protein synthesis: cyprodinil, pyrimethanil;
Signal transduction inhibitors: iprodione, fludioxonil;
Lipid and membrane synthesis inhibitors: quintozene, tolclofos-methyl, etridiazole, dimethomorph, flumorph, pyrimorph, N-(1-(1-(4-cyano-phenyl)-ethanesulfonyl)-but-2-yl) carbamic acid-(4-fluorophenyl) ester, propamocarb, propamo-carb-hydrochloride

or
2) an insecticidal compound IB selected from the group consisting of:
M-2.B fiproles: ethiprole, fipronil, flufiprole, pyrafluprole, or pyriprole;
M-3 sodium channel modulators from the class of pyrethroids: acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cylclopentenyl, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, deltamethrin, momfluorothrin, and tefluthrin;
M-4 nicotinic acteylcholine receptor agonists from the class of neonicotinoids: acetamiprid, chlothianidin, cycloxaprid, dinotefuran, flupyradifurone, imidacloprid, nitenpyram, sulfoxaflor, thiacloprid, thiamethoxam, 1-[(6-chloro-3-pyridyl)methyl]-7-methyl-8-nitro-5-propoxy-3,5,6,7-tetrahydro-2H-imidazo[1,2-a]pyridine or 1-[(6-chlo-ro-3-pyridyl)methyl]-2-nitro-1-[(E)-pentylideneamino]guanidine;
M-6 chloride channel activators from the class of mectins: abamectin, emamectin benzoate;

and
3) Bacillus subtilis MBI600 as compound II having the accession number NRRL B-50595, wherein a combination of compounds IA or IB and compound II exhibits synergy.

2. The mixture of claim 1 comprising compound IA and compound II.

3. The mixture of claim 1 comprising compound IB and compound II.

4. The mixture of claim 2 comprising as compound IA one fungicidal compound selected from the group consisting of dimoxystrobin, kresoxim-methyl, picoxystrobin, pyraclostrobin, boscalid, carboxin, fluopyram, fluxapyroxad, penflufen, penthiopyrad, sedaxane, benzovindiflupyr, 3-(difluoromethyl)-1-methyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4-carboxamide, 3-(trifluoromethyl)-1-methyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4-carboxamide, 1,3-dimethyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4-carboxamide, 3-(trifluoromethyl)-1,5-dimethyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4- carboxamide, 3-(difluoromethyl)-1,5-dimethyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4-carboxamide, 1,3,5-trimethyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4-carboxamide, ametoctradin, silthiofam, difenoconazole, epoxiconazole, fluquinconazole, flutriafol, ipconazole, metconazole, prothioconazole, tebuconazole, tetraconazole, triadimenol, triticonazole, 1-[rel-(2S;3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)-oxiranylmethyl]-5 thiocyanato-1H-[1,2,4]triazole, 2-[rel-(2S;3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)-oxiranylmethyl]-2H-[1,2,4]triazole-3-thiol, prochloraz, metalaxyl, pyrimethanil, fludioxonil, dimethomorph, and N-(1-(1-(4-cyano-phenyl)ethanesulfonyl)-but-2-yl) carbamic acid-(4-fluorophenyl) ester.

5. The mixture of claim 3 comprising as compound IB one insecticidal compound selected from the group consisting of ethiprole, fipronil, bifenthrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, zeta-cypermethrin, acetamiprid, chlothianidin, cycloxaprid, dinotefuran, flupyradifurone, imidacloprid, nitenpyram, sulfoxaflor, thiacloprid, thiamethoxam, 1-[(6-chloro-3-pyridyl)methyl]-7-methyl-8-nitro-5-propoxy-3,5,6,7-tetrahydro-2H-imidazo[1,2-a]pyridine, abamectin, and emamectin benzoate.

6. The mixture of claim 5 , wherein compound IA is selected from the group consisting of pyraclostrobin, picoxystrobin, boscalid, fluoxapyroxad, fluopyram, penflufen, benzovindiflupyr, sedaxane, penthiopyrad, difenoconazole, fluquinconazole, triticonazole, tebuconazole, and tetraconazole.

7. The mixture of claim 1 comprising a further compound III selected from Bradyrhizobium japonicum.

8. The mixture of claim 1 comprising a further compound IV jasmonates or salts or esters thereof.

9. The mixture of claim 8 , wherein the further compound IV is methyl jasmonate.

10. The mixture of claim 1 , wherein the ratio by weight from compound Ito compound II is from 1:500 to 500:1.

11. The mixture of claim 7 comprising compound I, compound II, compound III, in which each combination of two ingredients in the mixture of three ingredients ranges from 500:1 to 1:500.

12. The mixture of claim 8 comprising compound I, compound II, and compound IV, in which each combination of two ingredients in the mixture of three ingredients ranges from 500:1 to 1:500.

13. The mixture of claim 8 comprising compound I, compound II, compound III and compound IV, in which each combination of four ingredients in the mixture of three ingredients ranges from 500:1 to 1:500.

14. A pesticidal composition comprising a liquid or solid carrier and the mixture of claim 1 .

15. A plant propagation material treated with the mixture of claim 1 in an amount of from 0.01 g to 10 kg per 100 kg of plant propagation material.

16. A plant propagation material treated with the composition of claim 14 in an amount of from 0.01 g to 10 kg per 100 kg of the plant propagation material.

17. A kit for preparing a usable pesticidal composition, the kit comprising:
a) a composition comprising component 1) as defined in claim 1 and at least one auxiliary; or
b) a composition comprising component 2) as defined in claim 1 and at least one auxiliary; or
c) a composition comprising component 3) as defined in claim 1 and at least one auxiliary.

18. A method for protection of plant propagation mate

Assignees

• Basf Corp

Inventors

• Brahm Lutz
• Liebmann Burghard
• Wilhelm Ronald
• Gewehr Markus

Classifications

• A01N25/00

  Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application {, e.g. seed treatment or sequential application}; Substances for reducing the noxious effect of the active ingredients to organisms other than pests · CPC title

• A01N47/24

  containing the groups [IMAGE cpc-sch-A01N-0944.gif], [IMAGE cpc-sch-A01N-0945.gif] or[IMAGE cpc-sch-A01N-0946.gif]; Thio analogues thereof · CPC title

• A01N63/00 Primary

  Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates (containing compounds of determined constitution A01N27/00 - A01N59/00; unicellular algae A01N65/03) · CPC title

• A01N2300/00

  Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48 · CPC title

• Y02A50/356

  Cross-Sectional Technologies · mapped topic