Process of manufacturing a catalyst-coated membrane-seal assembly

Patent metadata

Field	Value
Publication number	US-10074860-B2
Application number	US-201515128216-A
Country	US
Kind code	B2
Filing date	Mar 24, 2015
Priority date	Mar 24, 2014
Publication date	Sep 11, 2018
Grant date	Sep 11, 2018

Abstract

Disclosed is a process for the manufacture of a catalyst-coated membrane-seal assembly, including:
(i) providing a carrier material; (ii-i) forming a first layer, the first layer being formed by:
(a) depositing a first catalyst component onto the carrier material such that the first catalyst component is deposited in discrete regions; (b) drying the first layer;
(ii-ii) forming a second layer, the second layer being formed by:
(a) depositing a first seal component, such that the first seal component provides a picture frame pattern having a continuous region and void regions, the continuous region including second seal component and the void regions being free from second seal component; (b) depositing a first ionomer component onto the first layer, such that the first ionomer component is deposited in discrete regions; and (c) drying the second layer.

First claim

The invention claimed is:

1. A process for the manufacture of a catalyst-coated membrane-seal assembly, said process comprising the steps of:
(i) providing a carrier material;
(ii-i) forming a first layer, said first layer being formed by:
(a) depositing a first catalyst component onto the carrier material such that the first catalyst component is deposited in discrete regions;
(b) drying the first layer;

(ii-ii) forming a second layer, said second layer being formed by:
(a) depositing a first seal component, such that the first seal component provides a picture frame pattern having a continuous region and void regions, the continuous region comprising first seal component and the void regions being free from first seal component;
(b) depositing a first ionomer component onto the first layer, such that the first ionomer component is deposited in discrete regions; and
(c) drying the second layer;
wherein the void regions of the first seal component are centrally positioned over the discrete regions of the first ionomer component;
wherein the discrete regions of the first ionomer component are centrally positioned over the discrete regions of the first catalyst component; and
wherein steps (ii-ii) (a) and (ii-ii) (b) are carried out in either order;

(iii) removing the carrier material.

2. A process according to claim 1 , which comprises a further step after step (ii-ii):
(ii-iii) forming a third layer, said third layer being formed by:
(a) depositing a second catalyst component onto the second layer such that the second catalyst component is deposited in discrete regions; and
(b) drying the third layer;
wherein the discrete regions of the second catalyst component are centrally positioned over the discrete regions of first ionomer component.

3. A process according to claim 2 , wherein step (ii-iii) includes a further step prior to step (b):
(a′) depositing a third seal component onto the second layer such that the third seal component provides a picture frame pattern having a continuous region and void regions, the continuous region comprising third seal component and the void regions being free from third seal component;
wherein the void regions of the third seal component and the discrete regions of the second catalyst component are centrally positioned in relation to each other; and

wherein steps (ii-iii) (a) and (ii-iii) (a′) are carried out in either order.

4. A process according to claim 3 , which comprises a further step after step (ii-iii):
(ii-iv) forming a fourth layer, said fourth layer being formed by:
(a) depositing a second adhesive component onto the third layer such that the second adhesive component provides a picture frame pattern having a continuous region and void regions, the continuous region comprising second adhesive component and the void regions being free from second adhesive component;
(b) drying the fourth layer;

wherein the void regions of the second adhesive component and the discrete regions of the second catalyst component are centrally positioned in relation to each other.

5. A process according to claim 3 , wherein a planar reinforcement component is added prior to step (ii-i) (b).

6. A process according to claim 2 , which comprises a further step after step (ii-iii):
(ii-iv) forming a fourth layer, said fourth layer being formed by:
(a) depositing a second adhesive component onto the third layer such that the second adhesive component provides a picture frame pattern having a continuous region and void regions, the continuous region comprising second adhesive component and the void regions being free from second adhesive component;
(b) drying the fourth layer;
wherein the void regions of the second adhesive component and the discrete regions of the second catalyst component are centrally positioned in relation to each other.

7. A process according to claim 2 , wherein one or more of the layers comprises a planar reinforcement component is added prior to step (ii-iii) (b).

8. A process according to claim 2 , wherein step (ii-i) comprises a further step prior to step (b):
(a′) depositing a second seal component onto the carrier material, such that the second seal component provides a picture frame pattern having a continuous region and void regions, the continuous region comprising second seal component and the void regions being free from second seal component;
wherein the void regions of the second seal component and the discrete regions of the first catalyst component are centrally positioned in relation to each other; and

wherein steps (ii-i) (a) and (ii-i) (a′) are carried out in either order.

9. A process according to claim 2 , wherein step (ii-i) optionally includes a further step after step (b):
(d) deposition of discrete regions of a barrier layer onto the discrete regions of first catalyst component, wherein the discrete regions of barrier layer and discrete regions of first catalyst component are centrally positioned in relation to each other.

10. A process according to claim 2 , which further comprises a step (i-a) between step (i) and step (ii-i):
(i-a) forming a preliminary layer, said preliminary layer being formed by:
(a) depositing a first adhesive component onto the carrier material such that the first adhesive component provides a picture frame pattern having a continuous region and void regions, the continuous region comprising first adhesive component and the void regions being free from first adhesive component;
(b) drying the preliminary layer;
wherein the void regions of the first adhesive component and the discrete regions of the first catalyst component are centrally positioned in relation to each other.

11. A process according to claim 2 , wherein a planar reinforcement component is added prior to step (ii-i) (b).

12. A process according to claim 1 , wherein step (ii-i) comprises a further step prior to step (b):
(a′) depositing a second seal component onto the carrier material, such that the second seal component provides a picture frame pattern having a continuous region and void regions, the continuous region comprising second seal component and the void regions being free from second seal component;
wherein the void regions of the second seal component and the discrete regions of the first catalyst component are centrally positioned in relation to each other; and

wherein steps (ii-i) (a) and (ii-i) (a′) are carried out in either order.

13. A process according to claim 12 , wherein a planar reinforcement component is added prior to step (ii-i) (b).

14. A process according to claim 1 , wherein step (ii-i) optionally includes a further step after step (b):
(d) deposition of discrete regions of a barrier layer onto the discrete regions of first catalyst component, wherein the discrete regions of barrier layer and discrete regions of first catalyst component are centrally positioned in relation to each other.

15. A process according to claim 14 , wherein a planar reinforcement component is added prior to step (ii-i) (b).

16. A process according to claim 1 , which further comprises a step (i-a) between step (i) and step (ii-i):
(i-a) forming a preliminary layer, said preliminary layer being formed by:
(a) depositing a first adhesive component onto the carrier material such that the first adhesive component provides a picture frame pattern having a continuous region and void regions, the continuous region comprising first adhesive component and the void regions being free from first adhesive component;
(b) drying the preliminary layer;
wherein the v

Assignees

• Johnson Matthey Fuel Cells Ltd

Inventors

• Barnwell David Edward
• Coleman Robert Jeffrey
• Dickinson Angus
• Soares Jorge Manuel Caramelo
• Sweetland Lee Alan

Classifications

• H01M8/0273

  with sealing or supporting means in the form of a frame · CPC title

• H01M4/928

  Unsupported catalytic particles; loose particulate catalytic materials, e.g. in fluidised state · CPC title

• H01M4/926

  on carbon or graphite · CPC title

• H01M4/9091

  Unsupported catalytic particles; loose particulate catalytic materials, e.g. in fluidised state · CPC title

• H01M4/9075

  Catalytic material supported on carriers, e.g. powder carriers (H01M4/8807, H01M4/881, H01M4/8814, H01M4/925 take precedence) · CPC title