Process for recycling composite materials

Patent metadata

Field	Value
Publication number	US-10072358-B2
Application number	US-201514944723-A
Country	US
Kind code	B2
Filing date	Nov 18, 2015
Priority date	Nov 19, 2014
Publication date	Sep 11, 2018
Grant date	Sep 11, 2018

Abstract

The present patent of invention describes a recycling process to recover fibrous reinforcing material of composite materials, particularly carbon fiber, primary reactor compound ( 101 ), for the controlled pyrolysis and oxidation of the composite material matrix (resin) at low temperature (400° C. to 500° C.) and a system for treating waste gases produced by thermal decomposition of composite material matrixes which employs a secondary reactor ( 201 ), containing within the same a thermal plasma arc ( 211 ). The main characteristic of the process, within the scope of the carbon fiber recycling, is the possibility of maintaining the fabric web, obtaining fabrics made of pure carbon fiber, without a significant amount of residues and preserving their structural characteristics. The thermal plasma allows managing high temperatures (2,000° C. to 15,000° C.) in a controlled atmosphere, which allows the dissociation of long chains of molecules into ions that are recombined to produce combustible gases and other acid or alkaline gases that are easily neutralized and retained in gas cleaning systems.

First claim

The invention claimed is:

1. A process for recycling a composite material, wherein the process comprises the following steps:
(i) providing a composite material comprised of fibers to be recovered and a polymeric matrix;
(ii) placing the composite material into a primary reactor and conducting pyrolysis of the composite material in the primary reactor to obtain the fibers with a soot residue of the polymeric matrix;
(iii) washing the fibers with the soot residue with deionized water to separate the soot residue from the fibers and to allow the deionized water to be absorbed by the fibers; and
(iv) oxidizing the fibers comprising absorbed deionized water by heating the fibers comprising absorbed deionized water in the presence of an oxidizing gas stream to thereby obtain recovered fibers.

2. The process according to claim 1 , wherein the pyrolysis step (ii) comprises confining the composite material in the primary reactor at a controlled atmosphere, and heating the confined composite material at temperatures ranging between 400° C. and 600° C. for a period varying between 30 and 40 minutes.

3. The process according to claim 2 , wherein the pyrolysis step (ii) includes a step of gasifying components of a polymeric matrix of the composite material.

4. The process according to claim 1 , wherein the oxidizing step (iv) is practiced at a temperature ranging between 350° C. and 450° C.

5. The process according to claim 1 , wherein the pyrolysis step (ii) includes expelling waste gases from the primary reactor.

6. The process according to claim 1 wherein the composite material comprises at least one type of fibers selected from the group consisting of carbon fibers, glass fibers and aramid fibers.

7. The process according to claim 6 , wherein the polymeric matrix further comprises a filler.

8. A process for recovering carbon fibers from a carbon fiber-containing composite material, wherein the process comprises the steps of:
(i) placing a composite material comprising carbon fibers in a polymeric matrix into a primary reactor;
(ii) conducting pyrolysis of the composite material in the primary reactor to obtain carbon fibers having a surface residue of pyrolyzed matrix material soot;
(iii) washing the fibers with the surface soot residue with deionized water to remove the soot residue from the surface of the carbon fibers and to allow the deionized water to be absorbed by the carbon fibers; and
(iv) oxidizing the carbon fibers comprising absorbed deionized water by heating the carbon fibers comprising absorbed deionized water in the presence of an oxidizing gas stream to thereby recover the carbon fibers.

9. The process according to claim 8 , wherein the pyrolysis step (ii) comprises confining the composite material in the primary reactor at a controlled atmosphere, and heating the confined composite material at temperatures ranging between 400° C. and 600° C. for a period varying between 30 and 40 minutes.

10. The process according to claim 9 , wherein the pyrolysis step (ii) includes a step of gasifying components of a polymeric matrix of the composite material.

11. The process according to claim 8 , wherein the oxidizing step (iv) is practiced at a temperature ranging between 350° C. and 450° C.

12. The process according to claim 8 , wherein the pyrolysis step (ii) includes expelling waste gases from the primary reactor.

13. The process according to claim 8 , wherein the matrix further comprises a filler.

Assignees

• Embraer Sa

Inventors

• Da Cruz Antônio Carlos
• Da Silva Fábio Santos
• Garcia Rafael Razuk

Classifications

• B01D53/44

  Organic components · CPC title

• B01D2259/818

  Employing electrical discharges or the generation of a plasma · CPC title

• Y02P20/143

  the feedstock being recycled material, e.g. plastics · CPC title

• B01D53/32

  by electrical effects other than those provided for in group B01D61/00 · CPC title

• C10B53/07

  {of solid raw materials consisting} of synthetic polymeric materials, e.g. tyres (recovery or working-up of waste materials of organic macromolecular compounds or compositions based thereon by dry-heat treatment for obtaining partially depolymerised materials C08J11/10; production of liquid hydrocarbon mixtures from rubber or rubber waste C10G1/10) · CPC title