Method for reducing engine wear with lubricants comprising 2-hydroxyalkylamide friction modifying/anti-wear compositions

Patent metadata

Field	Value
Publication number	US-10072230-B2
Application number	US-201615150691-A
Country	US
Kind code	B2
Filing date	May 10, 2016
Priority date	May 23, 2012
Publication date	Sep 11, 2018
Grant date	Sep 11, 2018

Abstract

Lubricant compositions comprising an improved ashless organic friction modifier additive have been found to be capable of reducing both friction and wear. It has been found that mixtures of fatty-alkanolamides containing secondary hydroxyls on the amino alkyl substituent, such as amide mixtures prepared from bis(2-hydroxypropyl)amine and mixtures of at least two different C8-24 fatty acids, provide better oil solubility and friction reduction than alkanolamides with primary, hydroxyl functionality, such as amide mixtures prepared from di-ethanol)amine.

First claim

What is claimed:

1. A method for reducing wear during the operation of a truck or automobile engine, comprising adding to a lubricating oil comprising one or more naturally occurring base stocks or synthetic base stocks, a 1:1 by weight mixture of:
i) one or more zinc dialkyldithiophosphates and
ii) a friction reducing/antiwear additive composition comprising a mixture of two or more fatty acid sec-hydroxylalkyl amides of formula II

wherein R is methyl and
R′ is selected from the group consisting of C 7-19 alkyl and C 7-19 alkenyl,
wherein the mixture of fatty acid sec-hydroxylalkyl amides comprises about 20 to about 35% by weight of the sec-hydroxyalkylamides are compounds where R′ is C 15 alkyl or alkenyl,
wherein about 75% or more of said C 15 alkyl or alkenyl are alkyl,
about 50 to about 75% by weight of the sec-hydroxyalkylamides are compounds where R′ is C 17 alkyl or alkenyl,
wherein about 40% to about 95% of said C 17 alkyl or alkenyl are alkenyl,
wherein the mixture of two or more fatty acid sec-hydroxylalkyl amides is prepared by reacting a secondary hydroxyalkyl amine with a mixture of fatty acids or fatty acid esters obtained from beef tallow,
to prepare a lubricant composition comprising about 1 wt %, based on the total weight of the lubricant composition, of the 1:1 by weight mixture of i) and ii),
which lubricant composition is added to an engine or crankcase of a truck or automobile.

2. The method according to claim 1 , wherein the lubricant composition also comprises one or more additional lubricant additives selected from the group consisting of dispersants, detergents, corrosion/rust inhibitors, antioxidants, other anti-wear agents, anti-foamants, other friction modifiers, seal swell agents, demulsifiers, V.I. improvers and pour point depressants.

3. A lubricant composition comprising:
a) a major portion of a lubricating oil comprising one or more naturally occurring and/or synthetic base stocks, and
b) about 1.0 wt %, based on the total weight of the lubricant composition, of a 1:1 by weight mixture of:
i) one or more zinc dialkyldithiophosphates, and
ii) a friction reducing/antiwear additive composition comprising a mixture of two or more fatty acid sec-hydroxylalkyl amides of formula II

wherein R is methyl and
R′ is selected from the group consisting of C 7-19 alkyl and C 7-19 alkenyl, wherein the mixture of fatty acid sec-hydroxylalkyl amides comprises
about 20 to about 35% by weight of the sec-hydroxyalkylamides are compounds where R′ is C 15 alkyl or alkenyl, wherein about 75% or more of said C 15 alkyl or alkenyl are alkyl,
about 50 to about 75% by weight of the sec-hydroxyalkylamides are compounds where R′ is C 17 alkyl or alkenyl, wherein about 40% to about 95% of said C 17 alkyl or alkenyl are alkenyl,
wherein the mixture of two or more fatty acid sec-hydroxylalkyl amides is prepared by reacting a secondary hydroxyalkyl amine with a mixture of fatty acids or fatty acid esters obtained from beef tallow.

4. The composition according to claim 3 , wherein the lubricant composition also comprises one or more additional lubricant additives selected from the group consisting of dispersants, detergents, corrosion/rust inhibitors, antioxidants, other anti-wear agents, anti-foamants, other friction modifiers, seal swell agents, demulsifiers, V.I. improvers and pour point depressants.

Assignees

• Chemtura Corp

Inventors

• Deblase Frank J

Classifications

• C10N2040/252

  Diesel engines · CPC title

• C10M169/04

  Mixtures of base-materials and additives · CPC title

• C10M137/10

  Thio derivatives · CPC title

• C10N2030/10

  Inhibition of oxidation, e.g. anti-oxidants · CPC title

• C10M141/10

  at least one of them being an organic phosphorus-containing compound · CPC title