Silicone adhesive composition, a method for the preparation thereof and an adhesive film

Patent metadata

Field	Value
Publication number	US-10072189-B2
Application number	US-201514670615-A
Country	US
Kind code	B2
Filing date	Mar 27, 2015
Priority date	Mar 28, 2014
Publication date	Sep 11, 2018
Grant date	Sep 11, 2018

Abstract

One of the purposes of the present invention is to provide an silicone adhesive composition which comprises no antioxidant, has sufficient adhesive, tack properties and excellent heat resistance, and provides a silicone adhesive composition which has no adhesive residue in a test described below. The other purpose of the present invention is to provide an adhesive film and an adhesive tape having a cured layer obtained from the composition. The present invention provides an addition curable or peroxide curable silicone adhesive composition, wherein
the addition curable silicone adhesive composition comprises
(A1) a diorganopolysiloxane having an alkenyl group and a viscosity at 25 degrees C. of 100,000 mPa·s or more, (B) an organopolysiloxane having R 1 3 SiO 0.5 units and SiO 2 units, wherein R 1 is a substituted or unsubstituted, monovalent hydrocarbon group having 1 to 10 carbon atoms, (C) an organchydrogenpolysiloxane having at least three SiH groups, (D) optionally an addition reaction inhibitor, (E) a platinum group metal catalyst for an addition reaction, and (F) an organic solvent, and
the peroxide curable silicone adhesive composition comprises
(A2) a diorganopolysiloxane having a viscosity at 25 degrees C. of 100,000 mPa·s or more and may or may not have an alkenyl group, (B) an organopolysiloxane having R 1 3 SiO 0.5 units and SiO 2 units, wherein R 1 is a substituted or unsubstituted, monovalent hydrocarbon group having 1 to 10 carbon atom, (F) an organic solvent, and (G) an organic peroxide,
and components (A1) and (A2) may be accompanied with octamethylcyclotetrasiloxane and/or decamethylcyclopentasiloxane and each content of octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane is less than 0.1 mass %, based on a total amount of component (A1) or (A2), component (B) and octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane.

First claim

The invention claimed is:

1. An addition curable or peroxide curable silicone adhesive composition, wherein
the addition curable silicone adhesive composition comprises
(A1) a diorganopolysiloxane having an alkenyl group and a viscosity at 25° C. of 100,000 mPa·s or more,
(B) an organopolysiloxane having R 1 3 SiO 0.5 units and SiO 2 units, wherein R 1 is a substituted or unsubstituted, monovalent hydrocarbon group having 1 to 10 carbon atoms, and wherein a ratio of the number of the R 1 3 SiO 0.5 units to the number of the SiO 2 units is 0.6 to 1.7,
(C) an organohydrogenpolysiloxane having at least three SiH groups,
(D) optionally an addition reaction inhibitor,
(E) a platinum group metal catalyst for an addition reaction, and
(F) an organic solvent, and

the peroxide curable silicone adhesive composition comprises
(A2) a diorganopolysiloxane having a viscosity at 25° C. of 100,000 mPa·s or more and may or may not have an alkenyl group,
(B) an organopolysiloxane having R 1 3 SiO 0.5 units and SiO 2 units, wherein R 1 is a substituted or unsubstituted, monovalent hydrocarbon group having 1 to 10 carbon atom, and wherein a ratio of the number of the R 1 3 SiO 0.5 units to the number of the SiO 2 units is 0.6 to 1.7,
(F) an organic solvent, and
(G) an organic peroxide,

and components (A1) and (A2) may be accompanied with octamethylcyclotetrasiloxane and/or decamethylcyclopentasiloxane and each content of octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane is less than 0.1 mass %, based on a total amount of component (A1) or (A2), component (B) and octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane.

2. The silicone adhesive composition according to claim 1 , wherein components (A1) and (A2) are one or more of the compounds represented by the following formula (1), (2) or (3):
R 3 a R 2 (3−a) SiO(R 3 R 2 SiO) m (R 2 2 SiO) n SiR 2 (3−a) R 3 a   (1)

HOR 2 2 SiO(R 3 R 2 SiO) m (R 2 2 SiO) n SiR 2 2 OH  (2)

(R 3 a R 2 (3−a) SiO 1/2 ) o (R 3 R 2 SiO 2/2 ) p (R 2 2 SiO 2/2 ) q (R 4 SiO 3/2 ) r (SiO 4/2 ) s   (3)

wherein R 2 is, independently of each other, a substituted or unsubstituted, monovalent hydrocarbon group having no aliphatic unsaturated bond, R 3 is, independently of each other, a monovalent organic group having an alkenyl group, a is an integer of from 0 to 3, m is an integer of 0 or more, n is an integer of 100 or more, a total of m and n is such that the viscosity of the diorganopolysiloxanes at 25° C. is 100,000 mPa·s or more, R 4 is, independently of each other, selected from the groups defined for R 2 and R 3 , o is an integer of from 3 to 12, p is a integer of 0 or more, q is an integer of 100 or more, a total of r and s is an integer of from 1 to 5, a total of o, p, q, r, and s is such that the viscosity of the diorganopolysiloxane at 25° C. is 100,000 mPa·s or more, provided that for component (A1), m in formula (1) is 2 or more when a is 0; and m in formula (2) is 2 or more; and p in formula (3) is 2 or more when a is 0.

3. The silicone adhesive composition according to claim 1 , wherein
the addition curable silicone adhesive composition comprises
component (A1) in an amount of 99 to 25 parts by mass,
component (B) in an amount of 1 to 75 parts by mass, provided that a total amount of
components (A1) and (B) is 100 parts by mass,
component (C) in an amount such that a ratio of the number of SiH groups in component (C) to the number of the alkenyl groups in components (A1) and (B) is 0.5 to 20,
component (D) in an amount of 0 to 8.0 parts by mass, relative to a total 100 parts by mass of components (A1) and (B),
component (E) in an amount such that an amount of the platinum group metal is 5 to 2,000 ppm, based on a total amount of components (A1) and (B), and
component (F) in an amount of 25 to 900 parts by mass, relative to a total 100 parts by mass of components (A1) and (B), and

the peroxide curable silicone adhesive composition comprises
component (A2) in an amount of 99 to 25 part by mass,
component (B) in an amount of 1 to 75 parts by mass, provided that a total amount of
components (A2) and (B) is 100 parts by mass,
component (F) in an amount of 25 to 900 parts by mass, relative to a total 100 parts by mass of components (A2) and (B), and
component (G) in an effective amount to cure components (A2) and (B).

4. The silicone adhesive composition according to claim 1 , wherein each content of octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane is less than 0.1 mass %, based on a total amount of component (A1) or (A2), octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane.

5. An adhesive film having a substrate, wherein at least one surface of the substrate has a layer obtained by curing the silicone adhesive composition according to claim 1 .

6. An adhesive tape having a substrate, wherein at least one surface of the substrate has a layer obtained by curing the silicone adhesive composition according to claim 1 .

Assignees

• Shinetsu Chemical Co

Inventors

• Kuroda Yasuyoshi
• Kobayashi Yuta

Classifications

• C09J7/28

  Metal sheet (metallised plastics C09J7/22) · CPC title

• C08G77/20

  containing silicon bound to unsaturated aliphatic groups · CPC title

• Y10T428/2852

  Adhesive compositions · CPC title

• C08G77/34

  Purification · CPC title

• C08G77/12

  containing silicon bound to hydrogen · CPC title