Pressure-sensitive adhesive composition, pressure-sensitive adhesive layer, pressure-sensitive adhesive member and image display, and method for peeling off optical film from an image display and method for removing display panel from image display

Patent metadata

Field	Value
Publication number	US-10072187-B2
Application number	US-92103209-A
Country	US
Kind code	B2
Filing date	Mar 12, 2009
Priority date	Mar 13, 2008
Publication date	Sep 11, 2018
Grant date	Sep 11, 2018

Abstract

The pressure-sensitive adhesive composition of the invention includes a base polymer; and amphiphilic molecule particles that have an aggregate structure of amphiphilic molecules having hydrophilic group and hydrophobic group in the same molecule. The pressure-sensitive adhesive has stable adhesive characteristics and can be reduced in adhesive strength in a desired manner depending on how it is to be used.

First claim

The invention claimed is:

1. A pressure-sensitive adhesive composition, comprising:
a pressure sensitive adhesive base polymer; and
amphiphilic molecule particles,
wherein the amphiphilic molecule particles consist of aggregated amphiphilic molecules,
wherein the amphiphilic molecules have at least one hydrophilic group and at least one hydrophobic group in the same molecule,
wherein the amphiphilic molecule particles are in the pressure-sensitive adhesive base polymer,
wherein the base polymer is a (meth) acrylic-based polymer, and
wherein the pressure sensitive adhesive base polymer has a weight average molecular weight in the range of 1,000,000 to 3,000,000.

2. The pressure-sensitive adhesive composition according to claim 1 , wherein the amphiphilic molecules are solid at 23° C. and 1 atm.

3. The pressure-sensitive adhesive composition according to claim 1 , wherein the amphiphilic molecule particles are amphiphilic molecule crystals having a structure in which the aggregated amphiphilic molecules are aligned.

4. The pressure-sensitive adhesive composition according to claim 3 , wherein the amphiphilic molecule crystals have a spherical, hollow spherical, hollow fibrous, or plate-shaped structure formed by self-assembly of the aggregated amphiphilic molecules.

5. The pressure-sensitive adhesive composition according to claim 1 , wherein the amphiphilic molecule particles have an average major-axis length of 2 μm or less.

6. The pressure-sensitive adhesive composition according to claim 1 , wherein the amphiphilic molecule particles have dimensions along XYZ coordinate axes perpendicular to one another, and when the particles have a major axis along the X-axis, the particles have dimensions of 400 nm or less along at least two of the coordinate axes.

7. The pressure-sensitive adhesive composition according to claim 1 , which comprises 0.01 to 10 parts by weight of the amphiphilic molecule particles based on 100 parts by weight of the base polymer.

8. The pressure-sensitive adhesive composition according to claim 1 , further comprising a crosslinking agent.

9. The pressure-sensitive adhesive composition according to claim 1 ,
wherein the hydrophilic group of the amphiphilic molecule contains a polyhydric alcohol moiety, a carboxyl group, a sulfone group, an amino group, a phosphoric acid group, a sulfate ester group, or a phosphate ester group.

10. The pressure-sensitive adhesive composition according to claim 9 , wherein the amphiphilic molecule is selected from the group consisting of a compound having a polyhydric alcohol moiety or a phosphoric acid group as the hydrophilic group and a saturated or unsaturated hydrocarbon chain as the hydrophobic group.

11. The pressure-sensitive adhesive composition according to claim 1 ,
wherein the hydrophilic and hydrophobic groups are attached directly or through an ester bond, an ether bond, an amide bond, an arylene group, or an aryleneoxy group.

12. The pressure-sensitive adhesive composition according to claim 11 ,
wherein the amphiphilic molecule contains N-glycoside glycolipids represented by general formula (2):
G—NHCO—R,

wherein G represents a sugar residue obtained by removing a hemiacetal hydroxyl group attached to an anomeric carbon from a sugar, and R represents an unsaturated hydrocarbon group of 10 to 39 carbon atoms;
asymmetric two-headed lipids (bolalipids) represented by general formula (3):
R′—NHCO—(CH 2 ) n —COOH,

wherein R′ represents a residue obtained by removing a reducing terminal hydroxyl group from an aldopyranose, and n represents a number of 6 to 20;
O-glycoside glycolipids having a structure represented by general formula (4):
G′—O—Ph—R″,

wherein G′ represents a sugar residue, Ph represents a phenyl group, and R″ represents a hydrocarbon group of 6 to 25 carbon atoms;
or a compound composed of a transition metal and a peptide lipid represented by general formula (5):
R′″CO(NHCH 2 CO) m OH,

wherein R′″ represents a hydrocarbon group of 6 to 18 carbon atoms, and m represents an integer of 1 to 3.

13. The pressure-sensitive adhesive composition according to claim 1 , wherein the amphiphilic molecule is selected from the group consisting of fatty acids, straight-chain alkylbenzenes, higher alcohols, alkylphenols, alpha-olefins, alkylglucosides, sucrose fatty acid esters, sorbitan fatty acid esters, or polyoxyethylene sorbitan fatty acid esters.

14. The pressure-sensitive adhesive composition according to claim 13 , wherein the amphiphilic molecule is higher alcohols.

15. The pressure-sensitive adhesive composition according to claim 13 , wherein the higher alcohols are polyoxyethylene alkyl ethers.

16. The pressure-sensitive adhesive composition according to claim 15 , wherein the polyoxyethylene alkyl ethers are represented by general formula (1): C m H 2m+1 —O—(CH 2 —CH 2 —O) n —H, wherein m is the number of carbon atoms in the alkyl group, and n is the mole number of added ethylene oxide, and m is in the range of 10 to 20.

17. The pressure-sensitive adhesive composition according to claim 13 , wherein the amphiphilic molecule is sorbitan fatty acid esters.

18. The pressure-sensitive adhesive composition according to claim 17 , wherein the sorbitan fatty acid esters contain at least one selected from the group consisting of sorbitan monopalmitate, sorbitan monostearate, sorbitan tristearate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan tristearate, and polyoxyethylene cetyl ether.

19. The pressure-sensitive adhesive composition according to claim 1 , wherein the pressure sensitive adhesive base polymer has a weight average molecular weight in the range of 1,500,000 to 2,500,000.

20. The pressure-sensitive adhesive composition according to claim 1 , wherein the pressure sensitive adhesive base polymer has a weight average molecular weight in the range of 1,700,000 to 2,500,000.

21. The pressure-sensitive adhesive composition according to claim 1 , wherein the pressure sensitive adhesive base polymer has a weight average molecular weight in the range of 1,800,000 to 2,500,000.

22. A pressure-sensitive adhesive layer made from the pressure-sensitive adhesive composition according to claim 1 .

23. The pressure-sensitive adhesive layer according to claim 22 , which has a total light transmittance of 88% or more and a haze of 3% or less, when applied with a thickness of 25 μm to a transparent glass plate and measured in a dry state.

24. A pressure-sensitive adhesive member, comprising:
a support base material; and
the pressure-sensitive adhesive layer according to claim 22 provided on one or both sides of the support base material.

25. The pressure-sensitive adhesive member according to claim 24 , wherein when the pressure-sensitive adhesive layer is attached to a glass substrate, the adhesive strength (A) of the pressure-sensitive adhesive layer is reduced to an adhesive strength (B) which is ½ or less of the adhesive strength (A) by an impression of heating the pressure-sensitive adhesive layer at 100° C. or more for 1 minute or more or of immersing the pressure-sensitive adhesive layer in hot water at 80° C. or more for 1 minute or more.

26. The pressure-sensitive adhesive member according to claim 24 , wherein the support base material is an optical film.

27. An image display, comprising at least one piece of the pressure-sensitive adhesive member

Assignees

• Umemoto Seiji
• Fujita Masakuni
• Nitto Denko Corp

Inventors

• Umemoto Seiji
• Fujita Masakuni

Classifications

• C09J7/38

  Pressure-sensitive adhesives [PSA] · CPC title

• Y10T428/283

  Water activated · CPC title

• C09J133/02 Primary

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title

• Y02P20/582

  Recycling of unreacted starting or intermediate materials · CPC title

• Y10T428/28

  Web or sheet containing structurally defined element or component and having an adhesive outermost layer · CPC title