Olefin-based paint containing propylene/α-olefin copolymer

Patent metadata

Field	Value
Publication number	US-10072171-B2
Application number	US-201414896059-A
Country	US
Kind code	B2
Filing date	Jun 6, 2014
Priority date	Jun 7, 2013
Publication date	Sep 11, 2018
Grant date	Sep 11, 2018

Abstract

The present invention relates to an olefin-based paint. The purpose of the present invention is to provide a paint with excellent organic solvent solubility or dispersibility, low paint viscosity, minimal coating irregularities even at high concentrations, excellent handling and storage stability, and excellent blocking resistance and coated film stability. In order to meet this purpose, an olefin-based paint is used that is characterized by containing a solution or dispersion obtained by dissolving or dispersing 0.1-55 parts by mass of a propylene-α-olefin copolymer (A) for 100 parts by mass of an organic solvent. The copolymer (A) is characterized by containing 60-90 mol % of propylene-derived constituent units (a) having a weight-average molecular weight (Mw), measured by GPC, in the range of 3,000 to 40,000, and 10-40 mol % of α-olefin-derived constituent units (b) having 4 or more carbon atoms [wherein (a)+(b)=100 mol %].

First claim

The invention claimed is:

1. An olefin-based coating material comprising a solution or dispersion in which 0.1 to 55 parts by mass of a propylene-α-olefin copolymer (A) which satisfies the following requirements (i) to (iii) is dissolved or dispersed in 100 parts by mass of an organic solvent:
(i) a weight-average molecular weight (Mw) measured by gel permeation chromatography (GPC) is in the range of 3,000 to 40,000;
(ii) the propylene-α-olefin copolymer (A) contains propylene-derived structural units (a) in the range of 60 to 90 mol %, and structural units (b) derived from α-olefin having not less than 4 carbon atoms in the range of 10 to 40 mol % (wherein (a)+(b)=100 mol %); and
(iii) the number of vinylidene groups per 1,000 carbon atoms is 0.5 to 5 as measured by 1 H-NMR;
wherein the propylene-α-olefin copolymer (A) is obtained through thermal decomposition of a propylene-α-olefin copolymer (A-1) which satisfies the following requirements (a) to (c):
(a) a weight-average molecular weight (Mw), measured by GPC is in the range of 50,000 to 1,000,000;
(b) a melting point (Tm) obtained from DSC is in the range of 60 to 120° C.; and
(c) a half-width of the melting peak obtained from DSC is in the range of 1 to 20° C.

2. The olefin-based coating material according to claim 1 , wherein the propylene-α-olefin copolymer (A) further satisfies the following requirements (iv) and (v):
(iv) a half-width of crystal melting peak obtained from differential scanning calorimetry (DSC) is in the range of 1 to 20° C.; and
(v) a melting point (Tm) obtained from DSC is in the range of 60 to 110° C.

3. The olefin-based coating material according to claim 1 , wherein the propylene-α-olefin copolymer (A) further satisfies the following requirement (vi):
(vi) a heat of fusion (ΔH) obtained from DSC is in the range of 40 to 100 J/g.

4. The olefin-based coating material according to claim 1 , wherein the propylene-α-olefin copolymer (A) is completely dissolved in the organic solvent at 50° C. or above.

5. The olefin-based coating material according to claim 1 , wherein a 60 rotational viscosity at 23° C. measured by B-type viscometer is equal to or less than 500 mPa-s when the concentration of the propylene-α-olefin copolymer (A) in the olefin-based coating material is 10 mass %.

6. The olefin-based coating material according to claim 1 , wherein the organic solvent is at least one member selected from a hydrocarbon solvent, an alcohol solvent and an ester solvent.

7. The olefin-based coating material according to claim 1 , wherein an SP value of the organic solvent is between 7.0 and 13.0.

8. An olefin-based coating material comprising a solution or dispersion in which a propylene-α-olefin copolymer (A) and other resin are dissolved or dispersed in an organic solvent, the propylene-α-olefin copolymer (A) satisfies the following requirements (i) to (iii):
(i) a weight-average molecular weight (mw) measured by GPC is in the range of 3,000 to 40,000;
(ii) the propylene-α-olefin copolymer (A) contains propylene-derived structural units (a) in the range of 60 to 90 mol %, and structural units (b) derived from α-olefin having 4 or more carbon atoms in the range of 10 to 40 mol % (wherein (a)+(b)=100 mol %); and
(iii) the number of vinylidene groups per 1,000 carbon atoms is 0.5 to 5 as measured by 1 H-NMR;
wherein the propylene-α-olefin copolymer (A) is obtained through thermal decomposition of a propylene-α-olefin copolymer (A-1) which satisfies the following requirements (a) to (c):
(a) a weight-average molecular weight (Mw) measured by GPC is in the range of 50,000 to 1,000,000;
(b) a melting point (Tm) obtained from DSC is in the range of 60 to 120° C.; and
(c) a half-width of the melting peak obtained from DSC is in the range of 1 to 20° C.

9. The olefin-based coating material according to claim 8 , wherein the propylene-α-olefin copolymer (A) further satisfies the following requirements (iv) and (v):
(iv) a half-width of crystal melting peak obtained from differential scanning calorimetry (DSC) is in the range of 1 to 20° C.; and
(v) a melting point (Tm) obtained from DSC is in the range of 60 to 110° C.

10. The olefin-based coating material according to claim 8 , wherein the propylene-α-olefin copolymer (A) further satisfies the following requirement (vi):
(vi) a heat of fusion (ΔH) obtained from DSC is in the range of 40 to 100 J/g.

Assignees

• Mitsui Chemicals Inc

Inventors

• Kawabe Kuniaki
• Kanaya Hirotaka
• Tanaka Masakazu
• Ito Toshiyuki

Classifications

• C09D123/142 Primary

  at least partially crystalline copolymers of propene with other olefins · CPC title

• C08L51/06

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title

• C09D123/14 Primary

  Copolymers of propene (C09D123/16 takes precedence) · CPC title