Compositions, methods of making the same, and articles prepared from the same

Patent metadata

Field	Value
Publication number	US-10072146-B2
Application number	US-201113991545-A
Country	US
Kind code	B2
Filing date	Dec 29, 2011
Priority date	Dec 30, 2010
Publication date	Sep 11, 2018
Grant date	Sep 11, 2018

Abstract

A composition comprising at least the following components: (A) a first composition comprising the following: i) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin, and a nonconjugated polyene; ii) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has an MWD less than, or equal to, 3.5, a Mooney Viscosity (ML (1+4 @125° C.)) greater than, or equal to, 80, and an [(ML(1+4 @125° C.))/Mw(conv)]*1000 greater than 0.429 mole/g; (B) a thermoplastic polymer; and (C) a vulcanization agent is provided. A crosslinked composition made by heating one or more of the inventive compositions is also provided. Articles made from one or more of the inventive compositions are also provided.

First claim

We claim:

1. A blend composition comprising at least the following components:
(A) a first composition that is oil-free and comprising the following:
i) from 43 to 47 percent weight of a first ethylene/propylene/diene interpolymer having a Mooney viscosity, ML(1+4) at 125° C. in the range of from greater than 80 to 85, a molecular weight distribution (MWD) in the range of from 2.05 to 2.5;
ii) from 53 to 57 percent by weight of a second ethylene/propylene/diene interpolymer having a Mooney viscosity, ML (1+4, 125° C.) in the range of from 80 to 85, wherein the ratio of the ethylene content in the second interpolymer to the ratio of ethylene content in the first interpolymer is greater than or equal to 1.05; and
wherein the first composition has an MWD less than, or equal to 3.5, a Mooney Viscosity (ML (1+4, 125° C.)) in the range of from 80 to 85, an [(ML 1+4, 125° C.)/Mw(conv)]*1000 greater than 0.429 mole/g, an overall ethylene content from 65 to 74 wt % based on the total weight of the first and second ethylene/propylene/diene interpolymers, as measured by FTIR;

(B) a thermoplastic polymer; and
(C) a vulcanization agent;
wherein said blend composition is in a free-flowing pellet form, and the blend composition has a tensile elongation greater than 310%.

2. The blend composition according to claim 1 , wherein the thermoplastic polymer has an MFR from 0.5 to 10 g/10 min.

3. The blend composition of according to claim 1 further comprising an oil.

4. A crosslinked composition formed from the blend composition according to claim 1 .

5. An article comprising at least one component formed from the blend composition according to claim 1 .

6. The article of claim 5 , wherein the article is a profile.

7. The blend composition of claim 1 wherein the first interpolymer is made earlier than the second interpolymer.

8. The blend composition of claim 7 wherein the second ethylene/propylene/diene interpolymer has a MWD less than 3.0.

9. The blend composition of claim 7 wherein the diene content in the second interpolymer to the diene content in the first interpolymer is greater than 1.1.

10. The blend composition of claim 9 wherein the first interpolymer comprises from 2.8 wt % to 4.5 wt % of the diene and the second interpolymer comprises from 4.8 wt % to 8 wt % of the diene.

11. The blend composition of claim 7 wherein the blend composition has a Shore A hardness greater than or equal to 60.

12. The blend composition of claim 11 wherein the blend composition has a tensile strength greater than or equal to 750 psi.

13. The blend composition of claim 12 wherein the blend composition has a compression set (70 hr (@)−20° C.) from 12% to 25%.

14. The blend composition of claim 13 wherein the blend composition has an oil resistance of at least 112%.

15. The blend composition of claim 7 wherein the first composition comprises titanium.

16. The blend composition of claim 7 wherein the first composition comprises boron.

17. The blend composition of claim 16 wherein the first composition comprises titanium.

Assignees

• Wu Xiaosong
• Rego Jose M
• Walton Kim L
• Walther Brian W
• Read Michael D
• Dow Global Technologies Llc

Inventors

• Wu Xiaosong
• Rego Jose M
• Walton Kim L
• Walther Brian W
• Read Michael D

Classifications

• C08L23/16 Primary

  Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title

• Y10T428/139

  Open-ended, self-supporting conduit, cylinder, or tube-type article · CPC title

• C08L23/10

  Homopolymers or copolymers of propene · CPC title

• C08L47/00 Primary

  Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers (C08L45/00 takes precedence; of conjugated diene rubbers C08L9/00 - C08L21/00) · CPC title

• C08L23/08

  Copolymers of ethene (C08L23/16 takes precedence) · CPC title