Propylene-based elastomer

Patent metadata

Field	Value
Publication number	US-10072110-B2
Application number	US-201515025834-A
Country	US
Kind code	B2
Filing date	Jun 10, 2015
Priority date	Jun 10, 2014
Publication date	Sep 11, 2018
Grant date	Sep 11, 2018

Abstract

Provided is a propylene-based elastomer having a narrow molecular weight distribution, a high density in the same comonomer content, and excellent mechanical properties. The propylene-based elastomer includes 50% by weight or more of a propylene-based repeating unit, and satisfies a particular relationship between an ethylene content and a molar ratio of a specific monomer sequence.

First claim

The invention claimed is:

1. A propylene-based elastomer comprising 50% by weight or more of a propylene-based repeating unit, and a residual amount of an olefin-based repeating unit comprising ethylene, wherein an ethylene content x (% by weight) and a molar ratio y (%) of propylene-propylene-ethylene sequence in the propylene-based elastomer satisfy a relationship of y≥0.75x+9.5.

2. The propylene-based elastomer of claim 1 , wherein the ethylene content x (% by weight) and a molar ratio z (%) of propylene-ethylene-ethylene sequence in the propylene-based elastomer satisfy a relationship of 0.69x−0.80≤z≤0.69x+1.15.

3. The propylene-based elastomer of claim 1 , wherein the molar ratio y (%) of propylene-propylene-ethylene sequence in the propylene-based elastomer is 10 to 30.

4. The propylene-based elastomer of claim 2 , wherein the molar ratio z (%) of propylene-ethylene-ethylene sequence in the propylene-based elastomer is 1 to 20.

5. The propylene-based elastomer of claim 1 , wherein the relationships are satisfied in the entire ethylene content range of 10 to 20% by weight.

6. The propylene-based elastomer of claim 1 , wherein the olefin-based repeating unit further comprises alpha-olefin having 4 or more carbon atoms.

7. The propylene-based elastomer of claim 1 , wherein the ethylene content x (% by weight) and the product w of ethylene reactivity ratio constant (Re) and propylene reactivity ratio constant (Rp) satisfy a relationship of −0.10x+2.65≤w≤−0.10x+3.13:Re=k11/k12 and Rc=k22/k21, wherein k11 is a growth reaction rate constant when ethylene comes after ethylene in the chain of the elastomer, k12 is a growth reaction rate constant when propylene comes after ethylene in the chain of the elastomer, k21 is a growth reaction rate constant when ethylene comes after propylene in the chain of the elastomer, and k22 is a growth reaction rate constant when propylene comes after propylene in the chain of the elastomer.

8. The propylene-based elastomer of claim 7 , wherein w is 1.0 or larger.

9. The propylene-based elastomer of claim 1 , wherein the propylene-based elastomer has a density of 0.860 to 0.890 g/cm 3 .

Assignees

• Lg Chemical Ltd

Inventors

• Kim Seul Ki
• Lee Eun Jung
• Park In Sung
• Lee Choong Hoon
• Kim Byoung Soo

Classifications

• C08F4/65912

  in combination with an organoaluminium compound · CPC title

• C08F210/06 Primary

  Propene · CPC title

• C08F2500/12

  Melt flow index or melt flow ratio · CPC title

• C08F4/65927

  two cyclopentadienyl rings being mutually bridged · CPC title

• C08F2500/08

  Low density, i.e. < 0.91 g/cm3 · CPC title