Method for making ceramic matrix composite articles

Patent metadata

Field	Value
Publication number	US-10071936-B2
Application number	US-201715460990-A
Country	US
Kind code	B2
Filing date	Mar 16, 2017
Priority date	Sep 24, 2014
Publication date	Sep 11, 2018
Grant date	Sep 11, 2018

Abstract

A method of forming a composite article includes impregnating an inorganic fiber preform with a slurry composition. The slurry composition includes a particulate, a solvent, and a pre-gellant material. Gelling of the pre-gellant material in the slurry composition is initiated to immobilize the particulate and yield a gelled article, and substantially all solvent is removed from the gelled article to form a green composite article. The green composite article is then infiltrated with a molten infiltrant to form the composite article.

First claim

The invention claimed is:

1. An article comprising an inorganic fiber preform impregnated with a slurry composition, wherein the slurry composition comprises a particulate, a solvent comprising water, and a pre-gellant material, wherein the pre-gellant material comprises a monomer that is polymerizable to form a gel.

2. The article according to claim 1 , wherein the slurry composition further comprises a free radical initiator selected from the group consisting of peroxides, persulfates, perchlorates, amines, azo compounds, and combinations thereof.

3. The article according to claim 1 , wherein the monomer comprises one or more functional groups selected from the group consisting of acrylates, acrylamides, vinyls, allyls, and combinations thereof.

4. The article according to claim 1 , where the particulate in the slurry is selected from the group consisting of aluminum nitride, aluminum diboride, boron carbide, aluminum oxide, mullite, zirconium oxide, carbon, silicon carbide, silicon nitride, transition metal nitrides, transition metal borides, rare earth oxides, and combinations thereof.

5. The article according to claim 1 , wherein slurry composition is at a temperature of about 30° C. to about 80° C.

6. The article according to claim 1 , wherein the inorganic fiber preform comprises fibers made from a material chosen from aluminum oxide (Al 2 O 3 ), mullite (Al 6 Si 2 O 13 ), zirconium oxide (ZrO 2 ), carbon (C), graphite, silicon carbide, silicon carbonitride, silicon nitride, and combinations thereof.

7. The article according to claim 6 , wherein the fibers of the inorganic fiber comprise at least one protective coating chosen from carbon, aluminum nitride, boron nitride, silicon nitride, silicon carbide, boron carbide, metal borides, transition metal silicides, transition metal oxides, transition metal silicates, rare earth metal silicates, and combinations thereof.

8. The article according to claim 1 , wherein the solvent is water.

9. An article comprising an inorganic fiber preform impregnated with a slurry composition, wherein the slurry composition comprises a particulate, an aqueous solvent, a pre-gellant material, wherein the pre-gellant material comprises a polysaccharide chosen from methyl cellulose, carboxymethyl cellulose, hydroxypropyl methyl cellulose, gellan gum, agarose, carrageenan, and combinations thereof; and an amine compound to aid gelation of the pre-gellant material.

10. The article according to claim 9 , wherein the slurry composition further comprises a monovalent or divalent salt.

11. The article according to claim 9 , where the particulate in the slurry is selected from the group consisting of aluminum nitride, aluminum diboride, boron carbide, aluminum oxide, mullite, zirconium oxide, carbon, silicon carbide, silicon nitride, transition metal nitrides, transition metal borides, rare earth oxides, and combinations thereof.

12. The article according to claim 9 , wherein the solvent comprises water.

13. The article according to claim 9 , wherein slurry composition is at a temperature of about 30° C. to about 80° C.

14. The article according to claim 9 , wherein the inorganic fiber preform comprises fibers made from a material chosen from aluminum oxide (Al 2 O 3 ), mullite (Al 6 Si 2 O 13 ), zirconium oxide (ZrO 2 ), carbon (C), graphite, silicon carbide, silicon carbonitride, silicon nitride, and combinations thereof.

15. The article according to claim 14 , wherein the fibers comprise at least one protective coating chosen from carbon, aluminum nitride, boron nitride, silicon nitride, silicon carbide, boron carbide, metal borides, transition metal silicides, transition metal oxides, transition metal silicates, rare earth metal silicates, and combinations thereof.

16. The article according to claim 9 , wherein the amine compound is polyethyleneimine.

17. The article according to claim 9 , wherein the slurry composition further comprises N,N-dimethylacrylamide and N,N′-methylenebisacrylamide.

18. A ceramic fiber preform impregnated with a slurry composition, wherein the slurry composition comprises:
at least one ceramic material;
a monomeric pre-gellant material comprising at least one of N,N-dimethylacrylamide and N,N′-methylenebisacrylamide; and
a solvent.

19. The preform according to claim 18 , wherein the ratio of N,N-dimethylacrylamide to N,N′-methylenebisacrylamide in the slurry composition is about 1:1 to about 1:30.

20. The preform according to claim 18 , wherein the slurry composition is at a temperature of about 30° C. to about 80° C.

21. The preform according to claim 18 , wherein the inorganic fiber preform comprises fibers made from a material chosen from aluminum oxide (Al 2 O 3 ), mullite (Al 6 Si 2 O 13 ), zirconium oxide (ZrO 2 ), carbon (C), graphite, silicon carbide, silicon carbonitride, silicon nitride, and combinations thereof.

22. The preform according to claim 21 , wherein the fibers comprise at least one protective coating chosen from carbon, aluminum nitride, boron nitride, silicon nitride, silicon carbide, boron carbide, metal borides, transition metal silicides, transition metal oxides, transition metal silicates, rare earth metal silicates, and combinations thereof.

23. The preform according to claim 18 , wherein the solvent comprises water.

24. The preform according to claim 18 , wherein the solvent is water.

Assignees

• Rolls Royce Corp
• Rolls Royce High Temperature Composites Inc

Inventors

• Goetz Anthony Martin
• Shinavski Robert
• Harris Stephen Isaiah
• Landwehr Sean E

Classifications

• C04B35/6286

  Carbides · CPC title

• C04B2235/5248

  Carbon, e.g. graphite · CPC title

• C04B2235/5232

  Silica or silicates other than aluminosilicates, e.g. quartz · CPC title

• C04B2235/3826

  Silicon carbides · CPC title

• C04B35/62868

  Boron nitride · CPC title