Catalyst preparation method

Patent metadata

Field	Value
Publication number	US-10071366-B2
Application number	US-201615258090-A
Country	US
Kind code	B2
Filing date	Sep 7, 2016
Priority date	Oct 27, 2010
Publication date	Sep 11, 2018
Grant date	Sep 11, 2018

Abstract

A method is described for preparing a catalyst including the steps of:
(i) impregnating a calcined support comprising a metal aluminate with a solution of nickel acetate at a temperature ≥40° C. and drying the impregnated support, (ii) calcining the dried impregnated support, to form nickel oxide on the surface of the support and (iii) optionally repeating steps (i) and (ii) on the nickel oxide coated support.

The method provides an eggshell catalyst in which the metal oxide is concentrated in an outer layer on the support.

First claim

What is claimed:

1. A catalyst comprising nickel or nickel oxide impregnated into a metal aluminate support in the form of a shaped pellet, extrudate, or granule, the form having a length, width and height in a range of from 3 to 50 mm, wherein the nickel or nickel oxide is present only in an eggshell layer, the eggshell layer including a surface of the support and having a thickness in a range of from 150 microns to 1000 microns.

2. The catalyst according to claim 1 wherein the metal aluminate is selected from the group consisting of calcium aluminate, magnesium aluminate and nickel aluminate.

3. The catalyst according to claim 1 wherein the metal aluminate is calcium aluminate and the calcined support is formed by shaping a calcium aluminate cement powder into a shaped support, curing the cement, and subsequently calcining the shaped support.

4. The catalyst according to claim 3 wherein the support is alkalised by impregnation with a solution of an alkali.

5. The catalyst according to claim 1 wherein the support is in the form of a cylindrical pellet having between 1 and 12 holes extending therethough.

6. The catalyst according to claim 1 wherein the nickel is present as nickel (II) oxide.

7. The catalyst according to claim 1 having a nickel oxide content in a range of from 2 to 25% wt.

8. The catalyst according to claim 1 wherein one or more promoter compounds are impregnated into the support.

9. The catalyst according to claim 1 wherein the metal aluminate is calcium aluminate and the support is formed by:
shaping a mixture of calcium aluminate cement powder and one or both of alumina and lime into a shaped support,
curing the shaped support, and
subsequently calcining the shaped support.

10. The catalyst according to claim 1 obtained by a method comprising the steps of:
(i) impregnating a calcined support comprising a metal aluminate with a solution comprising nickel acetate at a temperature ≥40° C. to form an impregnated support and drying the impregnated support to form a dried impregnated support, and
(ii) calcining the dried impregnated support, to form a nickel oxide coated support.

11. The catalyst according to claim 10 , wherein the method further comprises repeating steps (i) and (ii) on the nickel oxide coated support.

12. The catalyst according to claim 10 , wherein the method further comprises reducing the nickel oxide on the nickel oxide coated support with a hydrogen-containing gas mixture.

13. The catalyst according to claim 1 wherein the support is in the form of a cylindrical pellet having a diameter of 4 to 40 mm and an aspect ratio ≤2.

14. The catalyst according to claim 1 wherein the support is in the form of a domed cylindrical pellet having a cylindrical section having a length C and diameter D and domed ends of lengths A and B, such that (A+B+C)/D is 0.50 to 2.00 and (A+B)/C is 0.40 to 5.00.

15. The catalyst according to claim 1 having a total surface area in a range of from 0.5 to 40 m 2 g −1 .

16. The catalyst according to claim 1 having a pore volume in a range of from 0.1 to 0.3 cm 3 g −1 .

17. The catalyst according to claim 3 wherein the support has a calcium:aluminium atomic ratio in a range of from 1:3 to 1:12.

18. The catalyst according to claim 1 wherein the support has a silica content less than 1% by weight, based on the weight of the support composition.

19. The catalyst according to claim 1 wherein the nickel is present as nickel metal.

Assignees

• Johnson Matthey Plc

Inventors

• Forrest Sebastian John Kipling
• Oliver Jonathan Geoffrey
• French Samuel Arthur
• Carlsson Mikael Per Uno

Classifications

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• B01J37/18

  with gases containing free hydrogen · CPC title

• C01B2203/1058

  Nickel catalysts · CPC title

• C01B2203/047

  the impurity being carbon monoxide · CPC title

• B01J37/0205

  in several steps · CPC title