Polymers for use as protective layers and other components in electrochemical cells

Patent metadata

Field	Value
Publication number	US-10069135-B2
Application number	US-201314068372-A
Country	US
Kind code	B2
Filing date	Oct 31, 2013
Priority date	Nov 2, 2012
Publication date	Sep 4, 2018
Grant date	Sep 4, 2018

Abstract

Electrode structures and electrochemical cells are provided. The electrode structures and/or electrochemical cells described herein may include one or more protective layers comprising a polymer layer and/or a gel polymer electrolyte layer. The polymer layer may be formed from the copolymerization of an olefinic monomer comprising at least one electron withdrawing group and an olefinic comonomer comprising at least one electron donating group. Methods for forming polymer layers are also provided.

First claim

What is claimed is:

1. A method for forming a component for use in an electrochemical cell, the method comprising:
providing an electroactive layer;
depositing onto a surface of the electroactive layer:
a) an olefinic monomer comprising a maleimide which includes at least one double bond and at least one electron withdrawing group and at least one olefinic comonomer, different than the olefinic monomer, comprising at least one double bond and at least one electron donating group; or
b) an olefinic monomer comprising a maleimide which includes at least one double bond and at least one electron withdrawing group, the olefinic monomer further comprising at least one additional double bond and at least one electron donating group, and at least one olefinic comonomer, different than the olefinic monomer;
polymerizing the monomer(s) using a free radical mechanism to form a polymer;
wherein the polymer includes structural units comprising the at least one electron withdrawing group that alternate with structural units comprising the at least one electron donating group;
wherein the electron withdrawing group is selected from the group consisting of CON(R 1 ) 2 and —CONR 1 H;
wherein two electron withdrawing groups attached in the 1,2-position to the double bond may form together with the double bond of a 5- to 6-membered substituted or unsubstituted, unsaturated cycle or heterocycle;
wherein R 1 may be linked to at least one further electron donating or electron withdrawing group;
wherein each occurrence of R 1 is independently selected from the group consisting of hydrogen; halogen; substituted or unsubstituted, branched or unbranched acyl; substituted or unsubstituted aryl; substituted or unsubstituted heteroaryl; a metal ion, and a lithium-containing group; and
wherein a gel state ion conductivity of the polymer is greater than or equal to 10 −4 S/cm.

2. A method as in claim 1 , wherein the comonomer comprising the at least one electron donating group comprises a vinyl ether.

3. A method as in claim 1 , wherein depositing the olefinic monomer and the olefinic comonomer of a), or depositing the olefinic monomer of b), comprises using at least one of doctor blading, spray coating, spin coating, solution casting, and vapor deposition.

4. A method as in claim 1 , wherein depositing the olefinic monomer and the olefinic comonomer of a), or depositing the olefinic monomer of b), comprises using flash evaporation.

5. A method as in claim 1 , wherein polymerizing comprises applying at least one of UV light, an electron beam, or thermal energy to the olefinic monomer and olefinic comonomer, or to the olefinic monomer having at least two double bonds, to activate the free radical mechanism.

6. A method as in claim 1 , wherein polymerizing the monomers occurs within less than or equal to 5 seconds.

7. A method as in claim 1 , further comprising forming an ion conductive layer on the electroactive layer.

8. A method as in claim 7 , wherein the ion conductive layer is positioned between the electroactive layer and the layer comprising the polymer.

9. A method as in claim 7 , comprising depositing the monomer and the comonomer on a surface of the ion conductive layer.

10. A method as in claim 1 wherein the electron donating group comprises at least one group selected from the group consisting of an alkylamino, a heteroaryl, a cycloalkyl, a cycloalkenyl, a cycloalkynyl, —OCOR 2 , —NR 2 COR 2 , —OR 2 , —SR 2 , —Si(OR 2 ) 3 , —Si(OR 2 ) 2 H, —Si(OR 2 )H 2 , —Si(R 2 ) 3 , —Si(R 2 ) 2 H, —Si(R 2 )H 2 ,

and wherein each occurrence of R 2 is independently selected from the group consisting of hydrogen; substituted or unsubstituted, branched or unbranched aliphatic; substituted or unsubstituted cyclic; substituted or unsubstituted, branched or unbranched acyclic; substituted or unsubstituted, branched or unbranched heteroaliphatic; substituted or unsubstituted, branched or unbranched acyl; substituted or unsubstituted aryl; substituted or unsubstituted heteroaryl; substituted or unsubstituted, branched or unbranched alkylene oxide or poly(alkylene oxide); a metal ion; an anionic group; and a lithium-containing group;
wherein n is 1, 2 or 3; and
wherein R 2 may optionally be linked to at least one further electron donating or electron withdrawing group attached to an olefinic double bond.

11. A method as in claim 1 , wherein a molar ratio of the olefinic monomer comprising at least one electron withdrawing group to the at least one olefinic comonomer comprising at least one electron donating group is approximately one to one.

12. A method as in claim 1 , wherein a molar ratio of double bonds attached to the olefinic monomer comprising at least one electron withdrawing group to double bonds attached to the at least one olefinic comonomer comprising at least one electron donating group is approximately one to one.

13. A method as in claim 1 , wherein the electron withdrawing group is attached to a double bond.

14. A method as in claim 13 , wherein the electron donating group is attached to a double bond.

15. A method as in claim 1 , wherein R 1 may be linked to at least one further electron donating or electron withdrawing group attached to an olefinic double bond.

16. A method as in claim 1 , wherein the olefinic monomer is N-phenyl maleimide or N-triethylene glycol maleimide, and the olefinic comonomer is diethylene glycol divinyl ether, triethylene glycol divinyl ether, or 1,4-cyclohexanedimethanoldivinylether.

17. A method for forming a component for use in an electrochemical cell, the method comprising:
providing an electroactive layer;
depositing a monomer comprising a maleimide which includes at least one double bond and at least one electron withdrawing group, and a comonomer comprising a vinyl ether, on a surface of the electroactive layer, wherein the comonomer is different than the monomer comprising the maleimide;
wherein the electron withdrawing group is selected from the group consisting of CON(R 1 ) 2 and —CONR 1 H;
wherein two electron withdrawing groups attached in the 1,2-position to the double bond may form together with the double bond of a 5- to 6-membered substituted or unsubstituted, unsaturated cycle or heterocycle;
wherein R 1 may be linked to at least one further electron donating or electron withdrawing group; and
wherein each occurrence of R 1 is independently selected from the group consisting of hydrogen; halogen; substituted or unsubstituted, branched or unbranched acyl; substituted or unsubstituted aryl; substituted or unsubstituted heteroaryl; a metal ion, and a lithium-containing group; and
polymerizing the monomer and comonomer using a free radical mechanism to form a polymer, wherein the polymer includes structural units comprising the at least one electron withdrawing group that alternate with structural units comprising at least one electron donating group,
wherein a gel state ion conductivity of the polymer is greater than or equal to 10 −4 S/cm.

18. A method as in claim 17 , wherein the electron withdrawing group is attached to a double bond.

19. A method as in claim 18 , wherein R 1 may be linked to at least one further electron donating or electron withdrawing group attached to an olefinic double bond.

20. A method as in claim 17 , wherein the olefinic monomer is N-phenyl maleimide or N-triethylene glycol maleimide, and the olefinic comonomer is diethylene glycol d

Assignees

• Sion Power Corp
• Basf Se

Inventors

• Fleischmann Sven
• Petsch Tobias
• Misske Andrea
• Schmidt Ruediger
• Viner Veronika G
• Sankaran Bala

Classifications

• H01M50/414

  Synthetic resins, e.g. thermoplastics or thermosetting resins · CPC title

• H01M4/622

  being polymers · CPC title

• H01M4/13

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M2300/0085

  Immobilising or gelification of electrolyte · CPC title

• H01M10/0565

  Polymeric materials, e.g. gel-type or solid-type · CPC title