Ethylene-vinyl alcohol resin composition, multilayer structure, multilayer sheet, container, and packaging material

Patent metadata

Field	Value
Publication number	US-10066095-B2
Application number	US-201314407136-A
Country	US
Kind code	B2
Filing date	Jun 12, 2013
Priority date	Jun 13, 2012
Publication date	Sep 4, 2018
Grant date	Sep 4, 2018

Abstract

The present invention provides a resin composition containing: an ethylene-vinyl alcohol copolymer (A) having an ethylene content of 20 mol % or more and 60 mol % or less; a polyamide resin (B); a carboxylic acid metal salt (C); and an unsaturated aldehyde (D), the mass ratio (A/B) of the ethylene-vinyl alcohol copolymer (A) to the polyamide resin (B) being 60/40 or more and 95/5 or less, the content of the carboxylic acid metal salt (C) with respect to a resin content in terms of a metal element equivalent being 1 ppm or more and 500 ppm or less, and the content of the unsaturated aldehyde (D) with respect to the resin content being 0.05 ppm or more and 50 ppm or less.

First claim

The invention claimed is:

1. A resin composition, comprising:
an ethylene-vinyl alcohol copolymer (A) comprising an ethylene content of from 20 mol % to 60 mol %;
a polyamide resin (B);
a carboxylic acid metal salt (C); and
an unsaturated aldehyde (D),
wherein:
a mass ratio (A/B) of the ethylene-vinyl alcohol copolymer (A) to the polyamide resin (B) is from 60/40 to 95/5,
a content of the carboxylic acid metal salt (C) with respect to a resin content in terms of a metal element equivalent is from 1 ppm to 500 ppm, and
a content of the unsaturated aldehyde (D) with respect to the resin content is from 0.05 ppm to 50 ppm.

2. The resin composition according to claim 1 wherein the content of the carboxylic acid metal salt (C) with respect to the resin content in terms of a metal element equivalent is from 5 ppm to 500 ppm.

3. The resin composition according to claim 1 , wherein the carboxylic acid metal (C) comprises a metal element, the metal element being at least one selected from the group consisting of magnesium, calcium and zinc.

4. The resin composition according to claim 1 , wherein the unsaturated aldehyde (D) is an unsaturated aliphatic aldehyde.

5. The resin composition according to claim 4 , wherein the unsaturated aliphatic aldehyde is at least one selected from the group consisting of crotonaldehyde, 2,4-hexadienal and 2,4,6-octatrienal.

6. A multilayer structure, comprising:
a barrier layer comprising the resin composition according to claim 1 ; and
a thermoplastic resin layer laminated on at least one face of the barrier layer.

7. A multilayer sheet, comprising:
the multilayer structure according to claim 6 .

8. The multilayer sheet according to claim 7 , wherein the barrier layer and the thermoplastic resin layer are laminated using a coextrusion molding process.

9. A container, comprising:
the multilayer sheet according to claim 7 ,
wherein the container is obtained by molding the multilayer sheet using a vacuum-pressure forming process.

10. A method of processing food, the method comprising:
boiling or retort sterilizing the food in the container according to claim 9 .

11. A packaging material, comprising:
the multilayer sheet according to claim 7 ,
wherein the packaging material is obtained by molding the multilayer sheet using a heat-stretching process.

12. The resin composition according to claim 1 , wherein
the content of the carboxylic acid metal salt (C) is from 5 ppm to 500 ppm,
the content of the unsaturated aldehyde (D) is from 0.15 ppm to 50 ppm, and
the unsaturated aldehyde (D) is crotonaldehyde.

Assignees

• Kuraray Co

Inventors

• Nakazawa Shogo
• Kawai Hiroshi

Classifications

• Y10T428/1383

  Vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit is sandwiched between layers [continuous layer] · CPC title

• B29K2995/0069

  non-permeable · CPC title

• B29K2995/0067

  non-permeable · CPC title

• Y10T428/31725

  Of polyamide · CPC title

• C08K5/098

  Metal salts of carboxylic acids · CPC title