Reactivating propane dehydrogenation catalyst

Patent metadata

Field	Value
Publication number	US-10065905-B2
Application number	US-201715799398-A
Country	US
Kind code	B2
Filing date	Oct 31, 2017
Priority date	Jul 13, 2011
Publication date	Sep 4, 2018
Grant date	Sep 4, 2018

Abstract

Increase propane dehydrogenation activity of a partially deactivated dehydrogenation catalyst by heating the partially deactivated catalyst to a temperature of at least 660° C., conditioning the heated catalyst in an oxygen-containing atmosphere and, optionally, stripping molecular oxygen from the conditioned catalyst.

First claim

What is claimed is:

1. A process for dehydrogenating an alkane, the process comprising:
a. placing an alkane in operative contact with a heated alkane dehydrogenation catalyst in a reactor, the alkane dehydrogenation catalyst comprising a Group VIII noble metal and a Group IIIA metal;
b. removing from the reactor a partially deactivated catalyst, wherein at least a portion of the partially deactivated catalyst has coke deposited thereon;
c. rejuvenating at least a portion of the partially deactivated catalyst, yielding a rejuvenated dehydrogenation catalyst, by:
(1) heating at least a portion of the partially deactivated catalyst in a regenerator to a temperature of at least 660 degrees Celsius using heat at least partially generated by combusting a fuel source, wherein the fuel source is not the coke, said heating yielding a heated, further deactivated dehydrogenation catalyst which has an alkane dehydrogenation activity that is less than that of the partially deactivated catalyst; and
(2) subjecting at least a portion of the heated, further deactivated catalyst to a conditioning step which comprises maintaining at least a portion of the heated, further deactivated dehydrogenation catalyst at a temperature of at least 660 degrees Celsius while exposing at least a portion of the heated, further deactivated dehydrogenation catalyst to a flow of an oxygen-containing gas for a period of time greater than two minutes to yield an oxygen-containing reactivated dehydrogenation catalyst that has an activity for dehydrogenating alkane that is greater than that of either the partially deactivated catalyst or the heated, further deactivated catalyst.

2. The process of claim 1 , further comprising a step c.(3) of maintaining the oxygen-containing reactivated dehydrogenation catalyst at a temperature of at least 660 degrees Celsius while exposing the oxygen-containing reactivated dehydrogenation catalyst to a flow of stripping gas, which is substantially free of both molecular oxygen and combustible fuel, for a period of time to remove from the oxygen-containing reactivated dehydrogenation catalyst at least a portion of molecular oxygen trapped within or between catalyst particles and physisorbed oxygen that is desorbable at said temperature during that period of time.

3. The process of claim 1 , further comprising a step d. of transporting at least a portion of the rejuvenated dehydrogenation catalyst from the regenerator to the reactor, with transport from the regenerator to the reactor being effected by a combination of gravity and motive force imparted by an inert transport gas.

4. The process of claim 1 , wherein the oxygen-containing gas has an oxygen content within a range of from 5 mole percent to 100 mole percent, each mole percent being based upon total moles of oxygen-containing gas.

5. The process of claim 2 , wherein the period of time in step c.(3) is within a range of from at least three minutes to no more than 14 minutes.

6. The process of claim 1 , wherein the temperature for each of steps c.(1) and c.(2) lies within a range of from 660 degrees Celsius to 850 degrees Celsius.

7. The process of claim 1 , wherein the partially deactivated catalyst comprises a Group VIII noble metal and a Group IIIA metal, wherein the Group VIII noble metal is platinum and the Group IIIA metal is gallium.

8. The process of claim 1 , wherein one or more of steps c.(1) and c.(2) are physically separated from one another.

9. The process of claim 2 , wherein steps c.(2) and c.(3) are physically separated from one another and an oxygen-containing atmosphere with an oxygen content within a range of from 5 mole percent to 100 mole percent, each mole percent being based upon total moles of oxygen-containing atmosphere, is used to effect catalyst transfer between steps c.(2) and c.(3).

10. The process of claim 1 , wherein the partially deactivated catalyst comprises a promoter metal.

11. The process of claim 1 , wherein, in step c.(1), heating the partially deactivated catalyst to a temperature of at least 660 degrees Celsius comprises using heat at least partially generated by combusting at least a portion of the coke contained on the partially deactivated catalyst.

12. The process of claim 11 , wherein combusting the fuel source occurs at least partially concurrent with combusting the coke contained on the partially deactivated catalyst.

Assignees

• Dow Global Technologies Llc

Inventors

• Pretz Matthew
• Luo Lin
• Domke Susan
• Clark Howard W
• Pierce Richard A
• Malek Andrzej M
• Stewart Mark W
• Stears Brien A
• Schweizer Jr Albert E
• Capone Guido
• Coffey Duncan P
• Mbaraka Isa K

Classifications

• C07C2523/46

  Ruthenium, rhodium, osmium or iridium · CPC title

• B01J23/62

  with gallium, indium, thallium, germanium, tin or lead · CPC title

• B01J2523/828

  Platinum · CPC title

• B01J38/12

  Treating with free oxygen-containing gas · CPC title

• C07C2523/42

  Platinum · CPC title