Polymer interlayers comprising a blend of two or more resins

Patent metadata

Field	Value
Publication number	US-10065399-B2
Application number	US-201715474105-A
Country	US
Kind code	B2
Filing date	Mar 30, 2017
Priority date	Jun 10, 2013
Publication date	Sep 4, 2018
Grant date	Sep 4, 2018

Abstract

An interlayer comprised of a blend of thermoplastic resins and at least one high refractive index having improved acoustic and optical quality is disclosed. The use of a blend thermoplastic resins and a high refractive index plasticizer improves transparency and acoustic properties without sacrificing other characteristics of the interlayer.

First claim

The invention claimed is:

1. A multilayer polymer interlayer comprising:
a first polymer layer comprising a blend of resins, the blend comprising:

a first poly(vinyl butyral) resin having a first residual hydroxyl content;
a second poly(vinyl butyral) resin having a second residual hydroxyl content; and
a first plasticizer;
wherein the difference between the first residual hydroxyl content and the second residual hydroxyl content is at least 2.0 weight percent; and
wherein the refractive index of the blend is at least 1.480; and
a second polymer layer adjacent the first polymer layer, wherein the second polymer layer is stiffer than the first polymer.

2. The polymer interlayer of claim 1 , wherein the first poly(vinyl butyral) resin and the second poly(vinyl butyral) resin are present in a ratio of between about 95:5 and 5:95.

3. The polymer interlayer of claim 1 , wherein the blend has at least one glass transition temperature (T g ) greater than 25° C.

4. The polymer interlayer of claim 1 , wherein the first plasticizer is a high refractive index plasticizer having a refractive index of at least 1.460.

5. The polymer interlayer of claim 4 , wherein the blend further comprises an additional plasticizer, wherein the additional plasticizer has a refractive index of less than about 1.450.

6. The polymer interlayer of claim 1 , wherein the polymer interlayer has a percent haze of less than 5.0%, as measured by ASTM D1003-61 (Re-approved 1977)-Procedure A using Illuminant C, at an observer angle of 2 degrees.

7. The polymer interlayer of claim 1 , wherein the blend has at least two different glass transition temperatures (T g ) and the difference between the at least two different glass transition temperatures (T g ) is at least 5° C.

8. The polymer interlayer of claim 1 , further comprising a third polymer layer adjacent to the first polymer layer, wherein the first polymer layer is between the second polymer layer and the third polymer layer, and wherein the third polymer layer is stiffer than the first polymer.

9. A multilayer polymer interlayer comprising:
a first polymer layer comprising a blend of resins, the blend comprising:
a first poly(vinyl butyral) resin having a first residual hydroxyl content;
a second poly(vinyl butyral) resin having a second residual hydroxyl content; and
a first plasticizer, wherein the first plasticizer is a high refractive index plasticizer having a refractive index of at least 1.460;
wherein the difference between the first residual hydroxyl content and the second residual hydroxyl content is at least 2.0 weight percent; and
a second polymer layer adjacent the first polymer layer, wherein the second polymer layer is stiffer than the first polymer layer;
wherein the polymer interlayer has a percent haze of less than 5.0%, as measured by ASTM D1003-61 (Re-approved 1977)-Procedure A using Illuminant C, at an observer angle of 2 degrees.

10. The polymer interlayer of claim 9 , wherein the first poly(vinyl butyral) resin and the second poly(vinyl butyral) resin are present in a ratio of between about 95:5 and 5:95.

11. The polymer interlayer of claim 9 , wherein the blend has at least one glass transition temperature (T g ) greater than 25° C.

12. The polymer interlayer of claim 9 , wherein the high refractive index plasticizer is selected from dipropylene glycol dibenzoate, tripropylene glycol dibenzoate, polypropylene glycol dibenzoate, isodecyl benzoate, 2-ethylhexyl benzoate, diethylene glycol benzoate, butoxyethyl benzoate, butoxyethyoxyethyl benzoate, butoxyethoxyethoxyethyl benzoate, propylene glycol dibenzoate, 2,2,4-trimethyl-1,3-pentanediol dibenzoate, 2,2,4-trimethyl-1,3-pentanediol benzoate isobutyrate, 1,3-butanediol dibenzoate, diethylene glycol di-o-toluate, triethylene glycol di-o-toluate, dipropylene glycol di-o-toluate, 1,2-octyl dibenzoate, tri-2-ethylhexyl trimellitate, di-2-ethylhexyl terephthalate, bis-phenol A bis(2-ethylhexaonate), di-(butoxyethyl) terephthalate, di-(butoxyethyoxyethyl) terephthalate, and mixtures thereof.

13. The polymer interlayer of claim 9 , wherein the refractive index of the blend is at least 1.480.

14. The polymer interlayer of claim 12 , wherein the blend further comprises an additional plasticizer, wherein the additional plasticizer has a refractive index of less than about 1.450.

15. The polymer interlayer of claim 9 , wherein the blend has at least two different glass transition temperatures (T g ) and the difference between at least two different glass transition temperatures (T g ) is at least 5° C.

16. The polymer interlayer of claim 9 , further comprising a third polymer layer adjacent to the first polymer layer, wherein the first polymer layer is between the second polymer layer and the third polymer layer, and wherein the third polymer layer is stiffer than the first polymer layer.

17. A multilayer polymer interlayer comprising:
a first polymer layer comprising a blend of resins, the blend comprising:
a first poly(vinyl butyral) resin having a first residual hydroxyl content;
a second poly(vinyl butyral) resin having a second residual hydroxyl content; and
a first plasticizer, wherein the first plasticizer has a refractive index of at least 1.460;
wherein the blend has at least one glass transition temperature (T g ) greater than 25° C.; and
a second polymer layer adjacent the first polymer layer, wherein the second polymer layer is stiffer than the first polymer;
wherein the refractive index of the polymer interlayer is at least 1.480.

18. The polymer interlayer of claim 17 , wherein the refractive index of the polymer interlayer is at least 1.485.

19. The polymer interlayer of claim 17 , wherein the first poly(vinyl butyral) resin and the second poly(vinyl butyral) resin are present in a ratio of between 95:5 and 5:95.

20. The polymer interlayer of claim 17 , wherein the blend further comprises an additional, wherein the additional plasticizer has a refractive index of less than about 1.450.

Assignees

• Solutia Inc

Inventors

• Lu Jun

Classifications

• B32B2419/00

  Buildings or parts thereof · CPC title

• B32B27/306

  comprising vinyl acetate or vinyl alcohol (co)polymers · CPC title

• C08K5/13

  Phenols; Phenolates · CPC title

• B32B2307/558

  Impact strength, toughness · CPC title

• C08K5/0016

  Plasticisers · CPC title