Modification of layered double hydroxides

Patent metadata

Field	Value
Publication number	US-10065172-B2
Application number	US-201314432019-A
Country	US
Kind code	B2
Filing date	Sep 27, 2013
Priority date	Sep 28, 2012
Publication date	Sep 4, 2018
Grant date	Sep 4, 2018

Abstract

The present invention relates to a process for modifying a layered double hydroxide (LDH), the process comprising,
a. providing a water-wet layered double hydroxide of formula:

[M z+ 1-x M′ y+ x (OH) 2 ] a+ (X n− ) a/r .b H 2 O  (1)
wherein M and M′ are metal cations, z=1 or 2; y=3 or 4, x is 0.1 to 1, preferably x<1, more preferably x=0.1-0.9, b is 0 to 10, X is an anion, r is 1 to 3, n is the charge on the anion X and a is determined by x, y and z, preferably a=z(1−x)+xy−2;
b. maintaining the layered double hydroxide water-wet, and c. contacting the water-wet layered double hydroxide with at least one solvent, the solvent being miscible with water and preferably having a solvent polarity (P′) in the range 3.8 to 9,

as well as to a layered double hydroxide prepared according to that process.

First claim

The invention claimed is:

1. A process for modifying a layered double hydroxide (LDH), the process comprising:
a. providing a layered double hydroxide that is water-wet and of formula:
[M z+ 1-x M′ y+ x (OH) 2 ] a+ (X n− ) a/r· b H 2 O  (a)

wherein M and M′ are metal cations, z=1 or 2; y=3 or 4, x is 0.1 to 1, b is 0 to 10, X is an anion, r is 1 to 3, n is the charge on the anion X and a=z(1−x)+xy-2;

b. maintaining the layered double hydroxide water-wet,
c. dispersing the layered double hydroxide that is water-wet in at least one solvent, the solvent being miscible with water; and
d. filtering and washing the layered double hydroxide that has been dispersed, with the at least one solvent.

2. The process as claimed in claim 1 , wherein M is Mg, Zn, Fe, Ca or a mixture of two or more thereof.

3. The process as claimed in claim 1 , wherein M′ is Al, Ga, Fe or a mixture of Al and Fe.

4. The process as claimed in claim 1 , wherein z is 2 and M is Ca, Mg, or Zn.

5. The process as claimed in claim 1 , wherein M′ is Al.

6. The process as claimed in claim 1 , wherein M is Zn, Mg or Ca, and M′ is Al.

7. The process as claimed in claim 1 , wherein X is selected from a halide, inorganic oxyanions, anionic surfactants, anionic chromophores, anionic UV absorbers, or a combination of anionic UV absorbers and any of the foregoing.

8. The process as claimed in claim 7 , wherein the inorganic oxyanions include carbonate, bicarbonate, hydrogenphosphate, dihydrogenphosphate, nitrite, borate, nitrate, sulphate or phosphate or a mixture of two or more thereof.

9. The process as claimed in claim 1 the at least one solvent is an organic solvent selected from acetone, acetonitrile, dimethylformamide, dimethyl sulfoxide, dioxane, ethanol, methanol, n-propanol, 2-propanol, tetrahydrofuran or a mixture of two or more thereof.

10. The process as claimed in claim 1 , further comprising drying the layered double hydroxide after filtering and washing the layered double hydroxide that has been dispersed, with the at least one solvent.

11. The process as claimed in claim 1 , further comprising subjecting the layered double hydroxide to a thermal treatment after filtering and washing the layered double hydroxide that has been dispersed, with the at least one solvent.

12. The process as claimed in claim 1 wherein x=0.1−0.9.

13. The process as claimed in claim 1 wherein the at least one solvent has a solvent polarity (P′) in the range 3.8 to 9.

14. The process as claimed in claim 11 wherein the thermal treatment is a heat treatment performed in a temperature range from about 50 to about 600° C.

15. The process as claimed in claim 1 , wherein dispersing the layered double hydroxide that is water-wet in at least one solvent includes dispersing the layered double hydroxide in the at least one solvent for a time sufficient to cause the layered double hydroxide to exhibit a 34% to 11,000% increase in surface area.

16. The process as claimed in claim 1 , wherein dispersing the layered double hydroxide that is water-wet in at least one solvent includes dispersing the layered double hydroxide in the at least one solvent for 1 hour to 2 hours.

Assignees

• Scg Chemicals Co Ltd

Inventors

• O'Hare Dermot
• Wang Qiang

Classifications

• B01J27/25

  Nitrates · CPC title

• C01P2004/04

  obtained by TEM, STEM, STM or AFM · CPC title

• C01P2002/82

  by IR- or Raman-data · CPC title

• B01J20/08 Primary

  comprising aluminium oxide or hydroxide; comprising bauxite · CPC title

• B01J37/04

  Mixing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title