Methods for removing contaminants from gas streams

Patent metadata

Field	Value
Publication number	US-10065151-B2
Application number	US-201615353853-A
Country	US
Kind code	B2
Filing date	Nov 17, 2016
Priority date	Dec 21, 2015
Publication date	Sep 4, 2018
Grant date	Sep 4, 2018

Abstract

A method for the partial removal of contaminants such as nitrogen oxides from a process gas stream is described. The process gas stream is separated into at least two process gas streams by means of a partition, baffle, damper or other device. Ozone is fed into contact with at least one of the separated process gas streams to oxidize the contaminants therein and the at least one of the process gas streams contacted by ozone is fed to a scrubber for removal of the oxidized contaminants from the gas streams. The separation is proportional to the percentage removal of contaminants desired.

First claim

Having thus described the invention, what we claim is:

1. A method for the partial removal of contaminants from a process gas stream comprising the steps of: separating a process gas stream into at least three process gas streams by means of a separating mechanism, wherein the process gas stream is heated before separating wherein a ratio of total flow rates of the at least three process gas streams to a total flow rate of the process gas stream is variable and is proportional to an amount of contaminants that are to be removed from the at least three process gas streams, feeding ozone into contact with at least one of the at least three process gas streams to oxidize the contaminants in the gas stream, and feeding at least one of the at least three process gas streams contacted by ozone to a scrubber for removal of the oxidized contaminants from the at least three process gas streams wherein an additional reaction chamber is provided for at least one of the at least three process gas streams that are treated with ozone.

2. The method as claimed in claim 1 wherein the separating mechanism is selected from the group consisting of a partition, baffle and variable damper.

3. The method as claimed in claim 1 wherein the separating mechanism is a variable speed blower and is used to divert a variable portion of the process gas stream to either a treated or an untreated stream.

4. The method as claimed in claim 3 wherein a reaction zone is enlarged to provide for more residence time.

5. The method as claimed in claim 1 wherein the contaminants are selected from the group consisting of nitrogen oxides, sulfur oxides, acid gases, particulate matter and mercury.

6. The method as claimed in claim 1 wherein the process gas stream is an exhaust gas stream from an industrial process selected from the group consisting of industrial boilers, power generation systems, chemical processing, kilns, furnace sand combustion processes.

7. The method as claimed in claim 1 wherein the at least three process gas streams are separated proportionally based on the amount of contaminants removal desired.

8. The method as claimed in claim 1 wherein the scrubber is selected from the group consisting of dry, semi-dry and wet scrubbing equipment.

9. The method as claimed in claim 1 wherein the amount of ozone that is added to the at least one of the three process gas streams is an amount of greater stoichiometry than the amount of nitrogen oxides present in the at least one of the three process gas streams.

10. The method as claimed in claim 1 wherein at least one of the process gas streams is not treated with ozone.

11. The method as claimed in claim 1 further comprising feeding the at least one process gas stream treated with ozone to a fan.

Assignees

• Gusberti Ambrogio
• Fitch Frank R
• Obermeyer Heinz Dieter
• Linde Ag

Inventors

• Gusberti Ambrogio
• Fitch Frank R
• Obermeyer Heinz-Dieter

Classifications

• B01D2252/103

  Water · CPC title

• B01D53/75

  Multi-step processes · CPC title

• B01D53/56 Primary

  Nitrogen oxides (B01D53/60 takes precedence) · CPC title

• B01D2258/0283

  Flue gases · CPC title

• B01D2251/104

  Ozone · CPC title