Surface coating method and method for improving electrochemical performance of an electrode for a lithium based battery

Patent metadata

Field	Value
Publication number	US-10062898-B2
Application number	US-201414321418-A
Country	US
Kind code	B2
Filing date	Jul 1, 2014
Priority date	Jul 10, 2013
Publication date	Aug 28, 2018
Grant date	Aug 28, 2018

Abstract

In an example of the surface coating method, an aromatic resin or a polycyclic aromatic hydrocarbon is dissolved in an organic solvent to form a solution. A film precursor is formed on a surface of an electrode material by immersing the electrode material into the solution, and evaporating the organic solvent. The electrode material is selected from the group consisting of an electrode active material particle and a pre-formed electrode. The film precursor is exposed to i) a thermal treatment having a temperature equal to or less than 500° C., or ii) ultraviolet light irradiation, or iii) both i and ii, to carbonize the film precursor to form a carbon film on the surface of the electrode material. Also disclosed herein is a method for improving electrochemical performance of an electrode for a lithium based battery.

First claim

The invention claimed is:

1. A surface coating method, comprising:
dissolving a polycyclic aromatic hydrocarbon selected from the group consisting of Anthracene, Benzo[a]pyrene, Chrysene, Coronene, Corannulene, Tetracene, Naphthalene, Pentacene, Phenanthrene, Pyrene, Triphenylene, Ovalene, and mixtures thereof in an organic solvent to form a solution;
forming a film precursor on a surface of an amorphous electrode material selected from the group consisting of a silicon-based amorphous material and a tin-based amorphous material by:
immersing the amorphous electrode material into the solution, the amorphous electrode material being selected from the group consisting of an amorphous electrode active material particle and a pre-formed electrode including an amorphous electrode active material particle; and
evaporating the organic solvent; and

exposing the film precursor to ultraviolet (UV) light irradiation or a combination of a thermal treatment at a temperature less than 200° C. and UV light irradiation, thereby carbonizing the film precursor to form a carbon film on the surface of the amorphous electrode material and retaining an amorphous structure of the amorphous electrode material.

2. The surface coating method as defined in claim 1 wherein the organic solvent is selected from the group consisting of toluene, xylene, tetrahydrofuran, ethylbenzene, mesitylene, durene, 2-phenylhexane, biphenyl, aniline, nitrobenzene, acetylsalicylic acid, paracetamol, and mixtures thereof.

3. The surface coating method as defined in claim 1 wherein:
the dissolving step includes heating the organic solvent to a temperature up to 100° C.;
prior to forming the film precursor, the method further includes allowing the solution to sit for a predetermined time to allow the organic solvent to break molecular interaction between atoms of the polycyclic aromatic hydrocarbon to form a 2D single molecular layer; and
immersing the amorphous electrode material into the solution includes:
mixing the amorphous electrode active material particle with the solution to form a mixture; and
allowing the mixture to sit for a predetermined time to allow the 2D single molecular layer to interact with and bond to functional groups on a surface of the amorphous electrode active material particle.

4. The surface coating method as defined in claim 3 , further comprising exposing the carbon film coated amorphous electrode active material particle to an electrode forming process, which includes mixing the carbon film coated amorphous electrode active material particle with a polymer binder and a conductive additive.

5. The surface coating method as defined in claim 3 wherein the amorphous electrode active material particle is a tin based amorphous material.

6. The surface coating method as defined in claim 1 wherein:
prior to immersing the electrode material into the solution, the method further includes allowing the solution to sit for a predetermined time to allow the organic solvent to break molecular interaction between atoms of the polycyclic aromatic hydrocarbon to form a 2D single molecular layer; and
immersing the amorphous electrode material into the solution includes:
dipping the pre-formed electrode into the solution; and
allowing the pre-formed electrode to sit in the solution for a predetermined time to allow the 2D single molecular layer to interact with and bond to functional groups on a surface of the pre-formed electrode.

7. The surface coating method as defined in claim 6 wherein the pre-formed electrode includes a tin based amorphous electrode active material particle.

8. The surface coating method as defined in claim 1 wherein the ultraviolet light irradiation is accomplished for a time ranging from about 5 minutes to about 24 hours.

9. The surface coating method as defined in claim 1 wherein the combination of the thermal treatment and the ultraviolet light irradiation is accomplished for a time ranging from about 5 minutes to about 24 hours.

10. A carbon film coated amorphous electrode material formed by the method as defined in claim 1 .

11. A method for improving electrochemical performance of an electrode for a lithium ion battery, the method comprising:
dissolving a polycyclic aromatic hydrocarbon selected from the group consisting of Anthracene, Benzo[a]pyrene, Chrysene, Coronene, Corannulene, Tetracene, Naphthalene, Pentacene, Phenanthrene, Pyrene, Triphenylene, Ovalene, and mixtures thereof in an organic solvent to form a solution;
forming a film precursor on a surface of an amorphous electrode active material particle selected from the group consisting of a silicon-based amorphous material and a tin-based amorphous material by:
immersing the amorphous electrode active material particle into the solution; and
evaporating the organic solvent;

exposing the film precursor to ultraviolet (UV) light irradiation or a combination of a thermal treatment at a temperature less than 200° C. and UV light irradiation, thereby carbonizing the film precursor to form a carbon film on the surface of the amorphous electrode active material particle and retaining an amorphous structure of the amorphous electrode active material particle;: and
using the carbon film coated amorphous electrode active material particle to form the electrode.

12. The method as defined in claim 11 wherein using the carbon film coated amorphous electrode active material particle to form the electrode includes:
mixing the carbon film coated amorphous electrode active material particle with a conductive additive and a polymeric binder to form a mixture;
forming a slurry of the mixture;
spreading the slurry into a sheet form; and
drying the sheet form to generate the electrode.

13. The method as defined in claim 12 wherein the mixture includes up to 95 wt. % of the carbon film coated amorphous electrode active material particle, up to 30 wt. % of the conductive additive, and up to 30 wt. % of the polymeric binder.

14. The method as defined in claim 11 wherein the electrode active material particle is a tin based amorphous electrode active material particle.

15. The method as defined in claim 11 wherein:
the dissolving step includes heating the organic solvent to a temperature up to 100° C.;
prior to forming the film precursor, the method further includes allowing the solution to sit for a predetermined time to allow the organic solvent to break molecular interaction between atoms of the polycyclic aromatic hydrocarbon to form a 2D single molecular layer; and
immersing the amorphous electrode active material particle into the solution includes:
mixing the amorphous electrode active material particle with the solution to form a mixture; and
allowing the mixture to sit for a predetermined time to allow the 2D single molecular layer to interact with and bond to functional groups on a surface of the amorphous electrode active material particle.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Xiao Xingcheng

Classifications

• H01M4/366

  as layered products · CPC title

• H01M4/1397

  of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• H01M4/0471 Primary

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• H01M4/136

  Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• H01M10/052

  Li-accumulators · CPC title