Microcapsules

Patent metadata

Field	Value
Publication number	US-10059907-B2
Application number	US-201414908278-A
Country	US
Kind code	B2
Filing date	Jul 28, 2014
Priority date	Jul 29, 2013
Publication date	Aug 28, 2018
Grant date	Aug 28, 2018

Abstract

A novel microcapsule which is endowed for example with reduced leakage of encapsulated materials. The microcapsule contains one or more fragrances and is suitable for inclusion in non-edible consumer goods products, laundry products, personal care products and cosmetic products. The microcapsule can be obtained in an economic and efficient manner by polymerizing an emulsion so that emulsion droplets are encapsulated into a subsequently cured polymeric shell.

First claim

The invention claimed is:

1. A microcapsule comprising a perfume composition enclosed within a polymeric shell, wherein:
the perfume composition includes a fragrance,
the polymeric shell includes solid colloidal particles having an average primary particle size comprised between 5 nm and 1 μm,
the polymeric shell further includes in polymerized form a blend including:
i) between 20% and 75% by weight over the combined weight of compounds (I) to (III) in the blend of a compound (I) which is a monoethylenically unsaturated monomer and/or dimethyldiallyl ammonium chloride,
ii) between 20% and 70% by weight over the combined weight of compounds (I) to (III) in the blend of a compound (II) which is a polyethylenically unsaturated monomer selected from the group consisting of a C 2 -C 24 alkyl di- or polyester of (meth)acrylic acid, a C 2 -C 24 alkyl di- or polyamide of (meth)acrylic acid and mixtures thereof, and
iii) between 0.01% and 10% by weight over the combined weight of compounds (I) to (III) in the blend of a compound (III) which comprises methacryloxypropyltrimethoxysilane and/or methacryloxypropyltriethoxysilane; and
wherein the microcapsule has a shell thickness of 100 nm to 800 nm, and
the microcapsule has an average particle size of 20 μm or more.

2. The microcapsule according to claim 1 , wherein the compound (II) is such that the microcapsule provides for a fragrance leakage of less than about 35% when tested upon storage for 4 weeks at 40° C. in a test liquid base, according to a leakage test method, when the microcapsule is prepared according to a leakage test manufacturing procedure, and the microcapsule encapsulates fragrance no. 5, the test liquid base, the leakage test method, the leakage test manufacturing procedure and the fragrance no. 5 being as defined in the examples.

3. The microcapsule according to claim 1 , wherein the compound (II):
A1. contains two or more (meth)acrylate ester groups or two or more (meth)acrylate amide groups per monomer, and
B1. has a molecular weight which, once divided by the number of (meth)acrylate ester or amide groups, gives a value of more than 85 and lower than 135.

4. The microcapsule according to claim 1 , wherein the compound (I) is selected from the group consisting of methacrylic acid, methyl methacrylate, ethyl methacrylate, isopropyl methacrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate, 3-hydroxypropyl methacrylate and mixtures thereof.

5. The microcapsule according to claim 1 , wherein the compound (I) is a combination of:
ia) between 50% and 100% by weight over the weight of the combination of a neutral monomethacrylate monomer (Ia) having a solubility in water at pH 7 and 20° C. equal to, or more than 2 g/100 ml,
ib) between 0% and 50% by weight over the weight of the combination of another neutral monoethylenically unsaturated monomer (Ib), and
ic) between 0% and 15% by weight over the weight of the combination of an ionized or ionizable monoethylenically unsaturated monomer (Ic).

6. The microcapsule according to claim 5 , wherein the neutral monomethacrylate monomer (Ia) is selected from the group consisting of 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate, 3-hydroxypropyl methacrylate, glycidyl methacrylate, poly(ethylene glycol) methyl ether methacrylate and mixtures thereof.

7. The microcapsule according to claim 1 , wherein the compound (II) is a di- or polyester resulting from the esterification of (meth)acrylic acid with a linear or branched polyhydric C 2 -C 24 alcohol and/or C 2 -C 24 polyethylene glycols.

8. The microcapsule according to claim 7 , wherein the compound (II) comprises one or more of 1,4-butylene glycol dimethacrylate, ethylene glycol dimethacrylate and 1,3-propylene glycol dimethacrylate.

9. A water-based dispersion comprising the microcapsule as defined according to claim 1 .

10. The water-based dispersion according to claim 9 , which is substantially free of latex particles.

11. A product comprising the microcapsule as defined according to claim 1 , and which is a non-edible consumer goods product, a household cleaner or laundry product, a personal care product or a cosmetic product.

12. A process for the manufacture of the microcapsule as defined in claim 1 , which comprises the following steps:
a) providing an oil-in-water emulsion having an oil phase and a water phase, said oil-in-water emulsion being obtainable by mixing:
colloidal silica particles having an average primary particle size comprised between 5 nm and 1 μm,
an oil soluble polymerization initiator,
a perfume composition including a fragrance,
the blend as defined by claim 1 , and
a protective colloid,

b) triggering polymerization within the oil phase of the oil-in-water emulsion obtained in step a),
c) letting the polymerization propagate thereby obtaining microcapsules.

13. The microcapsule according to claim 1 , wherein compound (III) is present between 0.5 and 10% by weight over the combined weight of compounds (I) and (III).

14. The microcapsule according to claim 1 , wherein compound (III) is present between 0.5 and 5% by weight over the combined weight of compounds (I) to (III).

15. The microcapsule according to claim 1 , wherein compound (III) is present between 1 and 5% by weight over the combined weight of compounds (I) to (III).

16. The microcapsule according to claim 1 , wherein the microcapsule has a shell thickness of 200 nm to 700 nm.

17. The microcapsule according to claim 1 , wherein the microcapsule has a shell thickness of 300 nm to 600 nm.

18. The microcapsule according to claim 1 , wherein the microcapsule has an average particle size of 25 μm or more.

Assignees

• Takasago Perfumery Co Ltd

Inventors

• Ribaut Tiphaine
• Warr Jonathan
• Fraser Stuart
• Anthony Olivier

Classifications

• C11D3/505

  encapsulated or adsorbed on a carrier, e.g. zeolite or clay · CPC title

• A61K2800/56

  Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms · CPC title

• A61Q13/00

  Formulations or additives for perfume preparations (essential oils or perfumes per se C11B9/00) · CPC title

• B01J13/14

  Polymerisation; cross-linking · CPC title

• A61K2800/412

  Microsized, i.e. having sizes between 0.1 and 100 microns · CPC title