Process for in situ synthesis of dispersion ZnO nanoparticles in oil

Patent metadata

Field	Value
Publication number	US-10059902-B2
Application number	US-201615017554-A
Country	US
Kind code	B2
Filing date	Feb 5, 2016
Priority date	Feb 14, 2015
Publication date	Aug 28, 2018
Grant date	Aug 28, 2018

Abstract

The present invention relates to a process for synthesizing dispersion of ZnO nanoparticles in an oil medium. Particularly, the invention relates to a process for in-situ synthesis of dispersion of ZnO nanoparticles in oil medium. Additionally, the present invention relates to a lubricant oil composition, wherein the composition comprises a base oil, a dispersant and the dispersion of ZnO as obtained by the process of the present invention.

First claim

We claim:

1. A process for in situ synthesis of dispersion of ZnO nanoparticles in an oil additive composition, wherein the process comprises the steps of:
a) dissolving a zinc salt in an alcoholic solvent and heating to 60-120° C. for 6-48 hours to obtain a suspension;
b) centrifuging the suspension as obtained in step (a) and washing with deionized water to obtain a precipitate of layered base zinc (LBZ);
c) dispersing the layered base zinc precipitate as obtained step (b) in an alcohol and adding to base oil containing a dispersant;
d) refluxing the mixture to obtain a colloidal suspension; and
e) evacuating the colloidal suspension at room temperature and heating at 60-90° C., followed by heating to 90-140° C. for 45 to 120 minutes to obtain a dispersion of ZnO in the oil medium.

2. The process as claimed in claim 1 , wherein the zinc salt is selected from hydrous or anhydrous form of zinc salt, selected from zinc acetate, zinc nitrate, zinc chloride, zinc sulfate, zinc hydroxide (hydrotalcite), zinc hydroxy carbonate or hydrozincite, zincite and wurtzite.

3. The process as claimed in claim 1 , wherein the alcoholic solvent is selected from C 1 to C 3 alcohols.

4. The process as claimed in claim 1 , wherein the ratio of zinc salt and the alcoholic solvent ranges from 0.05 to 15:1 to 740.

5. The process as claimed in claim 1 , wherein heating in step (a) is performed to 90° C. in an autoclave or refluxing in a glass reactor.

6. The process as claimed in claim 1 , wherein washing in step (b) is performed twice with deionized water.

7. The process as claimed in claim 1 , wherein the alcohol in step (c) is selected from C 1 -C 3 alcohols.

8. The process as claimed in claim 1 , wherein the amount of the dispersant in the base oil ranges from 40-78%.

9. The process as claimed in claim 1 , wherein the layered basic zinc salt is selected from layered basic zinc acetate, layered basic zinc nitrate, layered basic zinc chloride, layered basic zinc sulfate, layered zinc hydroxide (hydrotalcite), zinc hydroxy carbonate or hydrozincite, zincite and wurtzite.

10. The process as claimed in claim 1 , wherein the dispersant is selected from PIB dispersants, Phosphorodithioic acid; Ethyl hexanoic acid or fatty acids like stearic, oleic acids, sorbitane mono oleate (SPAN 80), sorbitane mono laurate (SPAN 20), sorbitane mono stearate (SPAN 60), Tween 20 (polyoxyethylenesorbitane mono laurate), Tween 60 (polyoxyethylenesorbitane mono stearate), Tween 80 (polyoxyethylenesorbitane mono oleate), diethanolamide fatty acid and fatty acid mono glyceride.

11. The process as claimed in claim 1 , wherein the base oil is a mineral oil selected from the group consisting of group I, group II, group III, group IV, group V and synthetic oils.

Assignees

• Indian Oil Corp Ltd

Inventors

• VIJAYARAJ Munusamy
• Hait Samik Kumar
• Sastry Madhira Indu Sekhara
• RAMAKUMAR Sankara Sri Venkata

Classifications

• C10N2040/25

  Internal-combustion engines · CPC title

• C10N2030/64

  Environmental friendly compositions · CPC title

• C10N2030/42

  Phosphor free or low phosphor content compositions · CPC title

• C10N2030/06

  Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure · CPC title

• C10N2030/00

  Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives · CPC title