Systems and methods for producing propylene

Patent metadata

Field	Value
Publication number	US-10059645-B2
Application number	US-201615190964-A
Country	US
Kind code	B2
Filing date	Jun 23, 2016
Priority date	Jul 2, 2015
Publication date	Aug 28, 2018
Grant date	Aug 28, 2018

Abstract

According to one embodiment described in this disclosure, a process for producing propylene may comprise at least partially metathesizing a first stream comprising at least about 10 wt. % butene to form a metathesis-reaction product, at least partially cracking the metathesis-reaction product to form a cracking-reaction product comprising propylene, and at least partially separating propylene from the cracking-reaction product to form a product stream comprising at least about 80 wt. % propylene.

First claim

What is claimed is:

1. A process for producing propylene, the process comprising:
at least partially metathesizing a first composition comprising at least 10 wt. % butene to form a metathesis-reaction product, where the first composition is metathesized with a metathesis catalyst comprising a mesoporous silica catalyst impregnated with metal oxide, where the mesoporous silica catalyst includes a pore size distribution of about 2.5 nm to about 40 nm and a total pore volume of at least about 0.600 cm 3 /g;
at least partially cracking the metathesis-reaction product to form a cracking-reaction product comprising propylene, where the metathesis-reaction product is cracked with a cracking catalyst comprising a mordenite framework inverted (MFI) structured silica catalyst, where the MFI structured silica catalyst includes total acidity of 0.001 mmol/g to 0.1 mmol/g; and
at least partially separating propylene from the cracking-reaction product to form a product composition comprising at least 80 wt. % propylene.

2. The process of claim 1 , where the MFI structured silica catalyst has a pore size distribution of at least 1.5 nm to 3 nm.

3. The process of claim 1 , where the MFI structured silica catalyst is free of acidity modifiers selected from the group consisting of rare earth modifiers, phosphorus modifiers, potassium modifiers, and combinations thereof.

4. The process of claim 1 , where the metathesis catalyst is positioned generally upstream of the cracking catalyst.

5. The process of claim 1 , where the metal oxide of the mesoporous silica catalyst comprises one or more oxides of molybdenum, rhenium, tungsten, or combinations thereof.

6. The process of claim 1 , where the metal oxide of the mesoporous silica catalyst is tungsten oxide (WO 3 ).

7. The process of claim 6 , where the mesoporous silica catalyst has a molar ratio for silica/tungsten oxide of 5 to 60 .

8. The process of claim 1 , where the mesoporous silica catalyst includes a surface area of 250 m 2 /g to 600 m 2 /g.

9. The process of claim 1 , where the mesoporous silica catalyst has a particle size of 20 nm to 200 nm, and an individual crystal size ranging from 1 to 100 μm.

10. The process of claim 1 , where the MFI structured silica catalyst is alumina free.

11. The process of claim 1 , where the MFI structured silica catalyst comprises alumina.

12. The process of claim 11 , where the MFI structured silica catalyst has a molar ratio of silica to alumina of 200 to 3000.

13. The process of claim 1 , where the MFI structured silica catalyst has a surface area of 300 m 2 /g to 425 m 2 /g, and a crystal size of 10 μm to 40 μm.

14. The process of claim 1 , where the metathesis and cracking occur in the same reactor.

15. The process of claim 1 , where the cracking-reaction product comprises at least 4 wt. % propylene.

16. The process of claim 1 , where the metathesis occurs in a first reactor and the cracking occurs in a second reactor, the first reactor and second reactor arranged in series.

17. A process for producing propylene, the process comprising:
at least partially metathesizing a first composition comprising at least 10 wt. % butene to form a metathesis-reaction product, where the first composition is metathesized with a metathesis catalyst comprising an amorphous mesoporous silica foam impregnated with metal oxides, where the metathesis catalyst has a pore size distribution of at least 3 nm to 40 nm and a total pore volume of at least 0.700 cm 3 /g;
at least partially cracking the metathesis-reaction product to form a cracking-reaction product comprising propylene, where the metathesis-reaction product is cracked with a cracking catalyst; and
at least partially separating propylene from the cracking-reaction product to form a product composition comprising at least 80 wt. % propylene.

18. The process of claim 17 , where the metathesis catalyst further comprises tri-block copolymer structuring agent, where the tri-block copolymer structuring agent is poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol) structure.

19. The process of claim 17 , where the pore size distribution is from at least 4 nm to 10 nm and the total pore volume is from at least 0.800 cm 3 /g to 1.5 cm 3 /g.

20. The process of claim 17 , where the metathesis catalyst has a total acidity from 0.125 mmol/g to 0.500 mmol/g, and a surface area of 400 to 500 m 2 /g.

21. The process of claim 17 , where the metal oxide is an oxide of molybdenum, rhenium, tungsten, or combinations thereof.

22. The process of claim 21 , where the metathesis catalyst has a molar ratio for silica to tungsten oxide of 1 to 50.

23. The process of claim 17 , where the metal oxide is tungsten oxide.

24. The process of claim 23 where the metathesis catalyst comprises from 5 to 15% by weight tungsten oxide.

Assignees

• Saudi Arabian Oil Co

Inventors

• Shaikh Sohel
• Jamal Aqil
• Zhang Zhonglin

Classifications

• C07C6/04 Primary

  at a carbon-to-carbon double bond · CPC title

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• C07C2521/08

  Silica · CPC title

• B01J29/005

  Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89 · CPC title

• B01J37/0201

  Impregnation · CPC title