Break-away support material for additive manufacturing

Patent metadata

Field	Value
Publication number	US-10059053-B2
Application number	US-201414532485-A
Country	US
Kind code	B2
Filing date	Nov 4, 2014
Priority date	Nov 4, 2014
Publication date	Aug 28, 2018
Grant date	Aug 28, 2018

Abstract

A support material for use in an additive manufacturing system to print a support structure for a three-dimensional part. The support material includes a base resin that is substantially miscible with a part material used to print the three-dimensional part, and has a glass transition temperature within about 10° C. of a glass transition temperature of the part material. The support material also includes a dispersed resin that is substantially immiscible with the base resin, where the base resin and the dispersed resin are each thermally stable for use in the additive manufacturing system in coordination with the part material.

First claim

The invention claimed is:

1. A support material for use in an additive manufacturing system to print a support structure for a three-dimensional part printed from a polyethermide part material, the support material comprising:
a base resin comprising one or more first polyarylethersulfones, wherein the base resin is substantially miscible with the polyethermide part material and has a glass transition temperature that ranges from about 205° C. to about 225° C.; and
a dispersed resin comprising one or more thermoplastic polymers comprises one or more second polyarylethersulfones, a blend of a polyphenyleneoxide and a polystyrene, mixtures thereof, or a polyetherimide, wherein the dispersed resin is substantially immiscible with the base resin such that the support material has non-uniform island in a sea configuration, wherein the base resin constitutes from about 85% to about 95% by weight of the base resin and the dispersed resin;
wherein the base resin and the dispersed resin each have a thermal stability such that less than 10% by weight of either of the base resin or the dispersed resin thermally degrades when the support material is exposed to 350° C. for a 5-minute duration; and
wherein the support material is configured for use in the additive manufacturing system as a filament or powder that is configured to be melted in and extruded from a print head retained by the additive manufacturing system and for printing the support structure from the support material in coordination with printing of the three-dimensional part from the part material in a layer-by-layer manner and have a relative adhesion with the polyethermide part material in the range of 2.4 and 3.1, such that the non-uniform islands of dispersed resin sufficiently disrupt the bonding between the polyethermide part material and the base resin to allow the support structure to be separated from the three-dimensional part with a force.

2. The support material of claim 1 , wherein the one or more first polyarylethersulfone of the base resin comprises a polysulfone.

3. The support material of claim 1 , wherein the one or more first polyarylethersulfone comprises a polyethersulfone.

4. The support material of claim 2 , wherein the one or more thermoplastic polymers of the dispersed resin comprises a polysulfone or a blend of a polyphenyleneoxide and a polystyrene and mixtures thereof.

5. The support material of claim 1 , wherein the one or more first polyarylethersulfones of the base resin comprise a polysulfone, and wherein the one or more thermoplastic polymers of the dispersed resin comprise a polyetherimide.

6. A support material for use in an additive manufacturing system to print a support structure for a three-dimensional part printed from a polyethermide part material, the support material comprising:
85% to about 95% by weight a first polyarylethersulfone having a glass transition temperature ranging from about 205° C. to about 225° C., wherein the first polyarylethersulfone is substantially miscible with the polyethermide part material; and
a second polyarylethersulfone that is substantially immiscible with first polyarylethersulfone and the polyethermide part material such that the support material has a non-uniform island in a sea configuration;
wherein the support material is configured for use in the additive manufacturing system as a filament or powder that is configured to be melted in and extruded from a print head retained by the additive manufacturing system and for printing the support structure from the support material in coordination with printing of the three-dimensional part from the part material in a layer by layer manner and have a relative adhesion with the polyethermide part material in the range of 2.4 and 3.1, such that the non-uniform islands of dispersed resin sufficiently disrupt the bonding between the part material and the base resin to allow the support structure to be separated from the three-dimensional part with a force.

7. The support material of claim 6 , wherein the first polyarylethersulfone comprises a polyethersulfone.

8. The support material of claim 6 , wherein the second polyarylethersulfone comprises a polysulfone.

9. The support material of claim 6 , wherein the support material is substantially free of polymers that thermally degrade by more than 5% by weight when exposed to 350° C. for a 5-minute duration and to 200° C. for a 50-hour duration.

10. The support material of claim 6 , wherein the second polyarylethersulfone constitutes from about 5% by weight to about 15% by weight of the support material.

11. A method for printing a three-dimensional part with an additive manufacturing system, the method comprising:
providing a polyethermide part material having a first glass transition temperature;
providing a support material having a base resin comprising 85% to about 95% by weight a first polyarylethersulfone having a glass transition temperature ranging from about 205° C. to about 225° C., wherein the first polyarylethersulfone is substantially miscible with the polyethermide part material and a second polyarylethersulfone that is substantially immiscible with first polyarylethersulfone and the polyethermide part material such that the support material has an non-uniform island in a sea configuration, wherein the base resin is substantially miscible with the polyethermide part material and, wherein the support material is configured for use in the additive manufacturing system as a filament or powder that is configured to be melted in and extruded from a print head retained by the additive manufacturing system;
heating a chamber of the additive manufacturing system to at least 185° C.;
melting the support material with a melt processing temperature greater than about 350° C.;
forming layers of the three-dimensional part from the polyethermide part material;
forming layers of a support structure from the molten support material in the heated chamber wherein as the layers of support structure are formed the non-uniform islands of the second polyarylsulfone form areas at an interface with the printed layer of the three-dimensional part to weaken the bond between the three-dimensional part and the layers of support material and have a relative adhesion between the support material the polyethermide part material in the range of 2.4 and 3.1;
removing the three-dimensional part and the support structure from the chamber, wherein less than 10% by weight of the support material of the removed support structure is thermally degraded; and
separating the support structure from the removed three-dimensional part utilizing a force.

12. The method of claim 11 , wherein the first polyarylethersulfone comprises a polyethersulfone and the second polyarylethersulfone comprises a polysulfone.

13. The method of claim 11 , wherein less than 5% by weight of the support material of the removed support structure is thermally degraded.

14. The method of claim 11 , wherein less than 1% by weight of the support material of the removed support structure is thermally degraded.

Assignees

• Stratasys Inc

Inventors

• Jaker Vittorio L
• Rodgers Luke M B

Classifications

• B29C64/307

  Handling of material to be used in additive manufacturing · CPC title

• G03G15/225

  using contact-printing · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• C08L71/12

  Polyphenylene oxides · CPC title

• G03G15/224

  Machines for forming tactile or three dimensional images by electrographic means, e.g. braille, 3d printing · CPC title