Active substance, nonaqueous electrolyte battery, and battery pack

Patent metadata

Field	Value
Publication number	US-10056615-B2
Application number	US-201414489716-A
Country	US
Kind code	B2
Filing date	Sep 18, 2014
Priority date	Sep 20, 2013
Publication date	Aug 21, 2018
Grant date	Aug 21, 2018

Abstract

According to one embodiment, there is provided an active substance. The active substance includes particles of niobium titanium composite oxide and a phase including a carbon material. The niobium titanium composite oxide is represented by Ti 1−x M1 x Nb 2−y M2 y O 7 . The phase is formed on at least a part of the surface of the particles. The carbon material shows, in a Raman chart obtained by Raman spectrometry, a G band observed at from 1530 to 1630 cm −1 and a D band observed at from 1280 to 1380 cm −1 . A ratio I G /I D between a peak intensity I G of the G band and a peak intensity I D of the D band is from 0.8 to 1.2.

First claim

What is claimed is:

1. An active substance comprising:
particles of niobium titanium composite oxide represented by Ti 1−x M1 x Nb 2−y M2 y O 7 (wherein 0≤x<1, 0≤y<1, and each of an element M1 and an element M2 is at least one selected from the group consisting of Nb, V, Ta, Fe, Ti, Bi, Sb, As, P, Cr, Mo, W, B, Na, Mg, Al, and Si, and the element M1 and the element M2 are identical or different from each other); and
a phase comprising a carbon material, the phase formed on at least a part of the surface of the particles;
wherein the carbon material shows, in a Raman chart obtained by Raman spectrometry using a 532-nm measuring light source, a G band observed at from 1530 to 1630 cm −1 and a D band observed at from 1280 to 1380 cm −1 , and a ratio I G /I D between a peak intensity I G of the G band and a peak intensity I D of the D band is from 0.8 to 1.2, and
wherein the active substance has a peak A present at the position of 2θ=26.37° to 26.77° and a peak B present at the position of 2θ=23.76 to 24.16° in a spectrum obtained by wide-angle X-ray scattering measurement using CuKα rays, the peak A is attributed to a crystal structure of a tetragonal oxide comprising a tetravalent niobium, the peak B is attributed to a crystal structure of a monocyclic oxide TiNb 2 O 7 , and an intensity ratio I A /I B between the peak A and the peak B is more than 0 and 0.25 or less.

2. A nonaqueous electrolyte battery comprising:
a negative electrode comprising the active substance according to claim 1 ;
a positive electrode; and
a nonaqueous electrolyte.

3. The nonaqueous electrolyte battery according to claim 2 , wherein the nonaqueous electrolyte comprises at least one selected from the group consisting of a liquid nonaqueous electrolyte, a gel-like nonaqueous electrolyte, a polymer solid nonaqueous electrolyte and an inorganic solid electrolyte.

4. A battery pack comprising at least one nonaqueous electrolyte battery comprising a negative electrode comprising the active substance according to claim 1 ; a positive electrode; and a nonaqueous electrolyte.

5. The battery pack according to claim 4 , further comprising:
an external energizing terminal; and
a protective circuit.

6. The battery pack according to claim 4 , comprising plural nonaqueous electrolyte batteries, each of the nonaqueous electrolyte batteries being the nonaqueous electrolyte battery according to claim 2 , the nonaqueous electrolyte batteries being electrically connected in series, in parallel or with a combination of series connection and parallel connection.

7. The active substance according to claim 1 , wherein the niobium titanium composite oxide has a monoclinic crystal structure.

8. The active substance according to claim 1 , wherein the phase comprising the carbon material covers the whole surface of the particles of the niobium titanium composite oxide.

9. The active substance according to claim 1 , wherein the phase comprising the carbon is supported on a part of the surface of the particles of the niobium titanium composite oxide.

10. The active substance according to claim 1 , wherein an average particle size of the particles of the niobium titanium composite oxide is from 0.1 μm to 10 μm.

11. The active substance according to claim 1 , wherein a specific surface area of the particles of the niobium titanium composite oxide is 5 m 2 /g or more and less than 200 m 2 /g.

12. An active substance comprising:
particles of niobium titanium composite oxide represented by Ti 1−x M x Nb 2 O 7 (wherein 0≤x<1 and an element M is at least one selected from the group consisting of Nb, V, Ta, Bi, Sb, As, P, Cr, Mo, W, B, Na, Mg, Al, and Si); and
a phase comprising a carbon material, the phase formed on at least a part of the surface of the particles;
wherein the carbon material shows, in a Raman chart obtained by Raman spectrometry using a 532-nm measuring light source, a G band observed at from 1530 to 1630 cm −1 and a D band observed at from 1280 to 1380 cm −1 and a ratio I G /I D between a peak intensity I G of the G band and a peak intensity I D of the D band is from 0.8 to 1.2, and
wherein the active substance has a peak A present at the position of 2θ=26.37° to 26.770 and a peak B present at the position of 2θ=23.76 to 24.16° in a spectrum obtained by wide-angle X-ray scattering measurement using CuKα rays, the peak A is attributed to a crystal structure of a tetragonal oxide comprising a tetravalent niobium, the peak B is attributed to a crystal structure of a monocyclic oxide TiNb 2 O 7 , and an intensity ratio I A /I B between the peak A and the peak B is more than 0 and 0.25 or less.

Assignees

• Toshiba Kk

Inventors

• Ise Kazuki
• Yoshida Yorikazu
• Harada Yasuhiro
• Inagaki Hiroki
• Takami Norio

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M4/485 Primary

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• H01M4/366

  as layered products · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• C01P2006/40

  Electric properties · CPC title