Electrically conductive polyamide/polyphenylene ether resin composition and molded article for vehicle using the same

Patent metadata

Field	Value
Publication number	US-10056168-B2
Application number	US-201615090917-A
Country	US
Kind code	B2
Filing date	Apr 5, 2016
Priority date	Apr 10, 2015
Publication date	Aug 21, 2018
Grant date	Aug 21, 2018

Abstract

An electrically conductive polyamide/polyphenylene ether resin composition and a molded article for vehicles using the same. The resin composition includes a polyphenylene ether; a polyamide; an olefin-based polymer; an impact modifier; a compatibilizer; and carbon fibrils, wherein the polyphenylene ether and the impact modifier form domains, and the polyamide, the olefin-based polymer and the carbon fibrils form a matrix, the domains including about 90 vol % or more of domain particles having a particle diameter of about 0.1 μm to about 2.0 μm, and wherein the electrically conductive polyamide/polyphenylene ether resin composition has a surface resistance of about 10 8 Ω/□ or less as measured on a specimen having a size of about 100 mm×about 100 mm×about 0.5 mm under conditions of about 23° C. and about 50% relative humidity (RH). The electrically conductive polyamide/polyphenylene ether resin composition and the molded article for vehicles using the same can exhibit good properties in terms of mechanical strength, heat resistance, impact resistance and electrical conductivity.

First claim

What is claimed is:

1. An electrically conductive polyamide/polyphenylene ether resin composition comprising:
a polyphenylene ether;
a polyamide;
an olefin-based polymer comprising a maleic anhydride modified ethylene-propylene copolymer and/or a maleic anhydride modified low density polyethylene;
an impact modifier comprising a styrene-ethylene-butylene-styrene copolymer;
a compatibilizer comprising maleic anhydride; and
carbon fibrils,
wherein the polyphenylene ether and the impact modifier form domains, and the polyamide, the olefin-based polymer and the carbon fibrils form a matrix, the domains comprising about 90 vol % or more of domain particles having a particle diameter of 0.1 μm to 2.0 μm, and
wherein the electrically conductive polyamide/polyphenylene ether resin composition has a surface resistance of about 10 8 Ω/square or less as measured on a specimen having a size of about 100 mm×about 100 mm×about 0.5 mm under conditions of about 23° C. and about 50% relative humidity (RH),
wherein the electrically conductive polyamide/polyphenylene ether resin composition is prepared by melt kneading a portion or the entirety of the polyamide and a portion or the entirety of the carbon fibrils with a portion or the entirety of at least one of the olefin-based polymer and the impact modifier to form an electrically conductive master batch, adding remaining components not included in the electrically conductive master batch, and melt kneading, wherein the electrically conductive polyamide/polyphenylene ether resin composition comprises about 100 parts by weight of a base resin comprising about 10 wt % to about 65 wt % of the polyphenylene ether and about 35 wt % to about 90 wt % of the polyamide; about 1 to about 15 parts by weight of the olefin-based polymer; about 1 to about 15 parts by weight of the impact modifier; about 0.2 to about 10 parts by weight of the compatibilizer; and about 0.1 to about 5 parts by weight of the carbon fibrils.

2. The electrically conductive polyamide/polyphenylene ether resin composition according to claim 1 , wherein the polyphenylene ether comprises at least one of poly(2,6-dimethyl-1,4-phenylene) ether, poly(2,6-diethyl-1,4-phenylene) ether, poly(2,6-dipropyl-1,4-phenylene) ether, poly(2-methyl-6-ethyl-1,4-phenylene) ether, poly(2-methyl-6-propyl-1,4-phenylene) ether, poly(2-ethyl-6-propyl-1,4-phenylene) ether, poly(2,6-diphenyl-1,4-phenylene) ether, a copolymer of poly(2,6-dimethyl-1,4-phenylene) ether and poly(2,3,6-trimethyl-1,4-phenylene) ether, and a copolymer of poly(2,6-dimethyl-1,4-phenylene) ether and poly(2,3,6-triethyl-1,4-phenylene) ether.

3. The electrically conductive polyamide/polyphenylene ether resin composition according to claim 1 , wherein the polyamide comprises at least one of Polyamide 6, Polyamide 66, Polyamide 46, Polyamide 11, Polyamide 12, Polyamide 610, Polyamide 612, Polyamide 6/66, Polyamide 6/612, Polyamide MXD6, Polyamide 6/MXD6, Polyamide 66/MXD6, Polyamide 6T, Polyamide 61, Polyamide 6/6T, Polyamide 6/61, Polyamide 66/6T, Polyamide 66/61, Polyamide 6/6T/6I, Polyamide 66/6T/6I, Polyamide 9T, Polyamide 91, Polyamide 6/9T, Polyamide 6/91, Polyamide 66/9T, Polyamide 6/12/9T, Polyamide 66/12/9T, Polyamide 6/12/91, and Polyamide 66/12/61.

4. The electrically conductive polyamide/polyphenylene ether resin composition according to claim 1 , wherein the impact modifier further comprises at least one of a block copolymer composed of an aromatic vinyl compound and a conjugated diene compound, a hydrogenated block copolymer obtained by hydrogenation of the block copolymer composed of the aromatic vinyl compound and the conjugated diene compound, a modified block copolymer obtained by modification of the block copolymer with at least one compound of α,β-unsaturated dicarboxylic acids and α,β-unsaturated dicarboxylic acid derivatives, and a modified hydrogenated block copolymer obtained by modification of the hydrogenated block copolymer with at least one compound of α,β-unsaturated dicarboxylic acids and α,β-unsaturated dicarboxylic acid derivatives.

5. The electrically conductive polyamide/polyphenylene ether resin composition according to claim 1 , wherein the compatibilizer further comprises at least one of maleic acid, maleic hydrazide, dichloro maleic anhydride, fumaric acid, citric acid, citric acid anhydride, malic acid and agaric acid.

6. The electrically conductive polyamide/polyphenylene ether resin composition according to claim 1 , wherein the carbon fibrils have a pH of about 4 to about 8.

7. The electrically conductive polyamide/polyphenylene ether resin composition according to claim 1 , wherein the carbon fibrils comprise about 0.1 wt % to about 5 wt % of an aromatic compound having a molecular weight of about 120 g/mol to about 1,000 g/mol.

8. The electrically conductive polyamide/polyphenylene ether resin composition according to claim 1 , wherein the domains comprise about 93 vol % to about 99 vol % of domain particles having a particle diameter of 0.1 μm to 2.0 μm.

9. The electrically conductive polyamide/polyphenylene ether resin composition according to claim 8 , wherein the domains comprise about 93 vol % to about 99 vol % of domain particles having a particle diameter of 0.3 μm to 1.0 μm.

10. The electrically conductive polyamide/polyphenylene ether resin composition according to claim 1 , wherein the domains comprise about 96 vol % to about 99 vol % of domain particles having a particle diameter of 0.1 μm to 2.0 μm.

11. The electrically conductive polyamide/polyphenylene ether resin composition according to claim 10 , wherein the domains comprise about 96 vol % to about 99 vol % of domain particles having a particle diameter of 0.3 μm to 1.0 μm.

12. The electrically conductive polyamide/polyphenylene ether resin composition according to claim 1 , wherein the olefin-based polymer is a maleic anhydride modified low density polyethylene.

13. A molded article for vehicles manufactured using the electrically conductive polyamide/polyphenylene ether resin composition according to claim 1 .

Assignees

• Lotte Advanced Mat Co Ltd

Inventors

• Choi Won Young
• Kim Doo Young
• Ko Won
• Lee Jung Hun

Classifications

• C08L77/06

  Polyamides derived from polyamines and polycarboxylic acids (C08L77/10 takes precedence) · CPC title

• C08K3/04

  Carbon · CPC title

• C08L51/06

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title

• C08L71/12

  Polyphenylene oxides · CPC title

• C08L53/02

  of vinyl-aromatic monomers and conjugated dienes · CPC title