Method of producing a micro-channeled material at atmospheric pressure

Patent metadata

Field	Value
Publication number	US-10056063-B2
Application number	US-201615189589-A
Country	US
Kind code	B2
Filing date	Jun 22, 2016
Priority date	Jun 22, 2016
Publication date	Aug 21, 2018
Grant date	Aug 21, 2018

Abstract

A micro-channeled material is fabricated from a bundle of metal-plated polymer fibers by a process wherein the polymer fibers are heated to a first temperature and pyrolyzed in the presence of an inert gas at atmospheric pressure.

First claim

The invention claimed is:

1. A method for producing a micro-channeled material from a plurality of metal-plated polymer fibers, comprising:
consolidating the metal-plated polymer fibers into a bundle, the metal-plated polymer fibers extending in parallel along a longitudinal direction of the bundle; and
heating the bundle to a first temperature in presence of an inert first gas at atmospheric pressure, thereby pyrolyzing the polymer fibers and obtaining a plurality of metal channels, a carbonaceous residue remaining in the bundle.

2. The method according to claim 1 , further comprising a cooling step after the heating, wherein the bundle is cooled to ambient temperature in the presence of the inert first gas.

3. The method according to claim 2 , further comprising a sectioning step after the cooling step wherein the bundle is shaped by cutting or grinding substantially transversely to a longitudinal direction of the bundle, thereby producing a plurality of bundles.

4. The method according to claim 1 , wherein the first temperature is between 500° C. and 700° C.

5. The method according to claim 4 , wherein the first temperature is approximately 600° C.

6. The method according to claim 1 , wherein during heating to the first temperature, the bundle is first heated to an intermediate temperature at a first rate, and then to the first temperature at a second rate that is less than the first rate.

7. The method according to claim 1 , wherein heating the bundle to the first temperature is performed in a radiatively-heated furnace.

8. The method according to claim 7 , wherein the inert first gas is streamed past the bundle from a gas input to an exit of the furnace.

9. The method according to claim 8 , wherein a flow rate of the inert first gas is a function of the differential in carbon dioxide content between the gas streamed into the gas input and the gas issuing from the exit of the furnace.

10. The method according to claim 1 , further comprising:
heating the bundle to a second temperature;
oxidizing at the second temperature the carbonaceous residue of the pyrolyzed polymer fibers in presence of a reactive second gas at atmospheric pressure, thereby producing carbon dioxide gas;
reducing the carbon dioxide gas to carbon monoxide gas at the second temperature in the presence of the reactive second gas at atmospheric pressure; and
sintering the metal channels at the second temperature.

11. The method according to claim 10 , wherein the reactive second gas is carbon dioxide.

12. The method according to claim 10 , wherein during heating the bundle to the second temperature, the bundle is surrounded by nitrogen gas until the second temperature is reached.

13. The method according to claim 10 , wherein heating the bundle to the second temperature is performed in a radiatively-heated furnace.

14. The method according to claim 13 , wherein the reactive second gas is streamed past the bundle from a gas input to an exit of the furnace.

15. The method according to claim 14 , wherein a flow rate of the reactive second gas is a function of the differential in carbon dioxide content between the gas streamed into the gas input and the gas issuing from the exit of the furnace.

16. The method according to claim 9 , wherein the second temperature is between 700° C. and 900° C.

17. The method according to claim 16 , wherein the second temperature is approximately 890° C.

18. The method according to claim 1 , wherein the polymer is nylon and the metal is nickel.

19. A micro-channeled material produced by a method for producing a micro-channeled material from a plurality of metal-plated polymer fibers, the method comprising:
consolidating the metal-plated polymer fibers into a bundle, the metal-plated polymer fibers extending in parallel along a longitudinal direction of the bundle; and
heating the bundle to a first temperature in presence of an inert first gas at atmospheric pressure, thereby pyrolyzing the polymer fibers and obtaining a plurality of metal channels, a carbonaceous residue remaining in the bundle.

20. The micro-channeled material according to claim 19 , wherein the metal channels are open-ended at both sides thereof.

21. An array comprising a plurality of micro-channeled materials according to claim 19 .

22. The array according to claim 21 , wherein the plurality of micro-channeled materials are arranged on a surface, wherein the surface is a three-dimensionally curved surface or a cylindrical surface.

Assignees

• Airbus Operations Sas
• Georgia Tech Res Inst

Inventors

• Lavieille Maud
• Nadler Jason H
• Beckert Michael

Classifications

• D01F9/28

  from polyamides · CPC title

• G10K11/162 Primary

  Selection of materials · CPC title

• G10K11/16

  Methods or devices for protecting against, or for damping, noise or other acoustic waves in general (G10K11/36 takes precedence) · CPC title