Method for depositing an anti-corrosion coating

Patent metadata

Field	Value
Publication number	US-10053780-B2
Application number	US-201415024582-A
Country	US
Kind code	B2
Filing date	Sep 17, 2014
Priority date	Sep 24, 2013
Publication date	Aug 21, 2018
Grant date	Aug 21, 2018

Abstract

Process for depositing a corrosion-protection coating on at least one portion of the surfaces of a metallic substrate having at least one cavity with an equivalent diameter emm<2 mm and a length/width ratio of greater than 150, using an aqueous suspension comprising powder of the metal to be deposited on the substrate combined with an agent for protecting the surface of the metal powder, a diluent, and at least one additive, the particles of the suspension each having an equivalent diameter d such that d≤emm/10.

First claim

What is claimed is:

1. A process for depositing a corrosion-protection coating on a metallic substrate, the metallic substrate having at least one cavity having an equivalent diameter e mm <2 mm and a length/width ratio of greater than 150, comprising the step of:
depositing, on at least one portion of at least one of said at least one cavity, an aqueous suspension to form a substrate-suspension assembly, said aqueous suspension comprising powder of a metal to be deposited on said substrate, a protective agent for protecting surfaces of the metal powder, a diluent, an aqueous solvent, and at least one additive promoting wetting of said aqueous suspension on said substrate, wherein the particles of the suspension each have an equivalent diameter d such that d≤e mm /10 and the additive is at least one organic compound selected from the group consisting of binder, dispersant, complexing agent, wetting agent, and plasticizer,
prior to said deposition, combining said metal powder, diluent, aqueous solvent, and at least one additive;
heating said substrate-suspension assembly to a temperature below 150° C. so as to eliminate said aqueous solvent;
following elimination of said aqueous solvent, maintaining said substrate-suspension assembly to a temperature between 400° C. and 500° C. for 1 to 10 hours under an inert gas or a reducing gas or under vacuum so as to eliminate said at least one organic compound to produce a coated substrate;
following said elimination of said at least one organic compound, performing a diffusion heat treatment of said metal toward said substrate by maintaining said coated substrate at a temperature between 500° C. and 700° C. for 1 to 10 hours under an inert gas or a reducing gas or under vacuum;
following said diffusion heat treatment, eliminating any residues of diluent from said coated substrate; and
following said elimination of residues, maintaining said coated substrate at a temperature between 900 and 1100° C. for 1 to 5 hours, thereby producing a substrate whose cavities are coated with a corrosion-protection coating.

2. The process of claim 1 , wherein said metal is aluminum.

3. The process of claim 1 , wherein said aqueous suspension further comprises an activating agent.

4. The process of claim 1 , wherein said aqueous suspension deposition is performed using a brush, roller, or spray gun, or by immersion of the substrate in the aqueous suspension.

5. The process of claim 1 , further comprising the step of introducing dry air inside said at least one cavity.

6. The process of claim 1 , wherein said elimination of residues is carried out by washing said coated substrate with an aqueous solution.

7. The process of claim 1 , further comprising the sequential steps of, prior to said depositing, cleaning said substrate with at least one aqueous solution, subjecting said substrate to ultrasonic waves, and drying said substrate under a stream of dry air.

8. The process of claim 7 , wherein said suspension further comprises an activating agent and said process further comprises pickling surfaces of the substrate to be coated prior to said cleaning.

9. The process of claim 7 , wherein said aqueous suspension application is performed by: immersing said substrate in said aqueous suspension, injecting said aqueous suspension onto said substrate, or brush application of said aqueous suspension onto said substrate.

Assignees

• Air Liquide
• Centre Nat Rech Scient
• Univ Limoges
• Univ De Lorraine
• Air Liquide
• Univ De Lorraine
• Univ Limoges

Inventors

• Chartier Thierry
• Del-Gallo Pascal
• Doublet Sebastien
• Mazet Thierry
• Prost Laurent
• Ramenatte Nicolas
• Rossignol Fabrice
• Vilasi Michel

Classifications

• F28F19/02

  by using coatings, e.g. vitreous or enamel coatings · CPC title

• F28D2021/0022

  for chemical reactors · CPC title

• F28D9/0075

  the plates having openings therein for circulation of the heat-exchange medium from one conduit to another · CPC title

• C23C10/20

  only one element being diffused · CPC title

• B01J2219/0236

  Metal based · CPC title