Production of low cloud point diesel fuels and low freeze point jet fuels

Patent metadata

Field	Value
Publication number	US-10053639-B2
Application number	US-201414506790-A
Country	US
Kind code	B2
Filing date	Oct 6, 2014
Priority date	Nov 4, 2013
Publication date	Aug 21, 2018
Grant date	Aug 21, 2018

Abstract

Methods are provided for dewaxing a distillate fuel boiling range feed to improve one or more cold flow properties of the distillate fuel feed, such as cloud point, where the distillate fuel feed is fractionated to produce both a jet fuel product and an arctic diesel fuel product. The decrease of cloud point is achieved by using a feedstock having a concentration of nitrogen of less than about 50 wppm and a concentration of sulfur of less than about 15 wppm. Further, the dewaxing catalyst may have a reduced content of hydrogenation metals, such as a content of Pt or Pd of from about 0.05 wt % to about 0.35 wt %. A distillate fuel feed can be dewaxed to achieve a desired cloud point differential using a reduced metals content dewaxing catalyst under the same or similar conditions to those required for a dewaxing catalyst with higher metals content.

First claim

We claim:

1. A method for producing multiple distillate products from a single mineral oil feedstock, the method comprising:
exposing a distillate fuel boiling range mineral oil feedstock having a boiling point range of about 200° F. to about 680° F. and a sulfur content of less than about 10 wppm and a nitrogen content of less than about 5 wppm to a dewaxing catalyst comprising a molecular sieve, wherein the molecular sieve comprises ZSM-48 with a silica to alumina ratio of 70 to 1 to about 110 to 1, and a Group VIII noble metal hydrogenation component comprising about 0.05 wt % to about 0.35 wt % of a Group VIII noble metal under effective dewaxing conditions to produce a dewaxed effluent having a cloud point that is reduced by at least about 25° F. (14° C.) relative to a feedstock cloud point; and
fractionating the dewaxed effluent to produce at least a diesel fuel product having a cloud point of about −4° F. (−20° C.) or less and a jet fuel product having a lower boiling range than the diesel fuel product and having a freeze point of less than about −40° F. (−40° C.), a fractionation cut point temperature between the diesel fuel product and the jet fuel product having the lower boiling range being at least 500° F. (260° C.).

2. The method of claim 1 , wherein the effective dewaxing conditions comprise a pressure of from about 200 psig (1.4 MPa) to about 1500 psig (10.4 MPa), a temperature of from about 321° C. (610° F.) to about 399° C. (750° F.), a hydrogen treat gas rate of about 500 scf/bbl (84 Nm 3 /m 3 ) to about 4000 scf/bbl (674 Nm 3 /m 3 ) or less, and a space velocity of from about 0.3 hr −1 to about 4.9 hr −1 .

3. The method of claim 1 , wherein the metal hydrogenation component comprises Pt, Pd, or a combination thereof.

4. The method of claim 1 , wherein the molecular sieve has a silica to alumina ratio of about 90 to 1.

5. The method of claim 1 , wherein the feedstock has the sulfur content of less than about 5 wppm or less and the nitrogen content of less than about 1 wppm or less.

6. The method of claim 1 , wherein the effective dewaxing conditions produce a dewaxed effluent having a cloud point that is reduced relative to a cloud point of the feedstock by at least about 80° F. (44° C.).

7. The method of claim 1 , wherein the effective dewaxing conditions produce a dewaxed effluent having a cloud point that is reduced relative to a cloud point of the feedstock by at least about 100° F. (56° C.).

8. The method of claim 1 , wherein the fractionation cut point temperature between the distillate product having the lower boiling range and the diesel fuel product is at least about 545° F. (285° C.).

9. The method of claim 1 , wherein a T5 boiling point for the diesel fuel product is at least about 550° F. (288° C.).

10. The method of claim 1 , wherein the distillate fuel boiling range feedstock has a T5 boiling point of at least about 280° F. (140° C.).

11. The method of claim 1 , wherein the diesel fuel product has a cloud point of about −76° F. (−60° C.) or less.

12. The method of claim 1 , further comprising exposing the dewaxed effluent to a hydrofinishing catalyst under effective hydrofinishing conditions, wherein the effective hydrofinishing conditions comprise a pressure of from about 200 psig (1.4 MPa) to about 1500 psig (10.4 MPa), a temperature of from about 500° F. (260° C.) to about 750° F. (399° C.), a hydrogen treat gas rate of about 500 scf/bbl (84 Nm 3 /m 3 ) to about 4000 scf/bbl (674 Nm 3 /m 3 ) or less, and a space velocity of from about 0.3 hr −1 to about 5.0 hr −1 .

13. A method for producing a diesel fuel product and a jet fuel product from a single mineral oil feedstock, the method comprising:
exposing a distillate fuel boiling range mineral oil feedstock having a boiling point range of about 200° F. to about 680° F. and a sulfur content of less than about 15 wppm and a nitrogen content of less than about 50 wppm to a dewaxing catalyst comprising a 10-member ring 1-D molecular sieve, wherein the molecular sieve comprises ZSM-48 with a silica to alumina ratio of 70 to 1 to about 110 to 1, and a metal hydrogenation component under effective dewaxing conditions to produce a dewaxed effluent,
wherein the effective dewaxing conditions comprise a pressure of from about 200 psig (1.4 MPa) to about 1500 psig (10.4 MPa),
wherein the dewaxing catalyst has an amount of metal hydrogenation component comprising about 0.05 wt % to about 0.35 wt % of a Group VIII noble metal, and
wherein the dewaxed effluent, when fractionated, produces the diesel fuel product and the jet fuel product; and
fractionating the dewaxed effluent to produce at least the diesel fuel product having a cloud point of about 14° F. (−10° C.) or less and the jet fuel product having a lower boiling range than the diesel fuel product and having a freeze point of less than about −40° F. (−40° C.), a fractionation cut point temperature between the diesel fuel product and the jet fuel product having the lower boiling range being at least 500° F. (260° C.).

14. The method of claim 1 , wherein the mineral oil feedstock has a boiling point range of about 200° F. to about 650° F.

15. The method of claim 13 , wherein the effective dewaxing conditions comprise a temperature of from about 321° C. (610° F.) to about 399° C. (750° F.), a hydrogen treat gas rate of about 500 scf/bbl (84 Nm 3 /m 3 ) to about 4000 scf/bbl (674 Nm 3 /m 3 ) or less, and a space velocity of from about 0.3 hr −1 to about 4.9 hr −1 .

16. The method of claim 13 , wherein the mineral oil feedstock has a boiling point range of about 200° F. to about 650° F.

17. A method for producing multiple distillate products from a single feedstock, the method comprising:
exposing a distillate fuel boiling range feedstock having a boiling point range of about 200° F. to about 680° F. and a sulfur content of less than about 10 wppm and a nitrogen content of less than about 5 wppm to a dewaxing catalyst comprising a molecular sieve, wherein the molecular sieve comprises ZSM-48 with a silica to alumina ratio of 70 to 1 to about 110 to 1, and a Group VIII noble metal hydrogenation component comprising about 0.05 wt % to about 0.35 wt % of a Group VIII noble metal under effective dewaxing conditions to produce a dewaxed effluent having a cloud point that is reduced by at least about 25° F. (14° C.) relative to a feedstock cloud point, wherein the effective dewaxing conditions comprise a pressure of from about 200 psig (1.4 MPa) to about 1500 psig (10.4 MPa); and
fractionating the dewaxed effluent to produce at least a diesel fuel product having a cloud point of about −7.6° F. (−22° C.) or less and a jet fuel product having a lower boiling range than the diesel fuel product and having a freeze point of less than about −40° F. (−40° C.), a fractionation cut point temperature between the diesel fuel product and the jet fuel product having the lower boiling range being at least 500° F. (260° C.).

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Shih Stuart S
• Xu Xiaochun
• Novak William J
• Lopez Carlos N
• Hilbert Timothy Lee
• Mccarthy Stephen John

Classifications

• C10G45/06

  containing nickel or cobalt metal, or compounds thereof · CPC title

• C10G2300/1055

  Diesel having a boiling range of about 230 - 330 °C · CPC title

• C10G2300/1059

  Gasoil having a boiling range of about 330 - 427 °C · CPC title

• C10G45/62

  containing platinum group metals or compounds thereof · CPC title

• C10G65/043

  at least one step being a change in the structural skeleton · CPC title