Multi-layer product

Patent metadata

Field	Value
Publication number	US-10053600-B2
Application number	US-201415100762-A
Country	US
Kind code	B2
Filing date	Nov 19, 2014
Priority date	Dec 3, 2013
Publication date	Aug 21, 2018
Grant date	Aug 21, 2018

Abstract

Multilayer product comprising at least one layer of an acrylate-based foam carrier (S); and a multiphase polymer composition (P) applied to this layer; the multiphase polymer composition (P) comprising:
a comb copolymer (A) which is obtainable by polymerization of at least one (meth)acrylate monomer in the presence of at least one macromer selected from the group consisting of polymerizable ethylene-butylene, ethylene-propylene, ethylene-butylene-propylene and isobutylene macromers, and which forms a continuous acrylate phase and a discontinuous hydrocarbon phase Kw; and at least one hydrocarbon component (B) which is soluble in the hydrocarbon phase Kw of the comb copolymer (A) and comprises at least one plasticizer resin and at least one solid resin;

the multiphase polymer composition (P) having a continuous acrylate phase with a static glass transition temperature Tg(Ac), measured by the DSC method, and a discontinuous hydrocarbon phase Kw 1 , comprising the hydrocarbon component (B) and having a static glass transition temperature Tg(Kw 1 ), measured by the DSC method, where Tg(Kw 1 ) is higher than Tg(Ac) by 35 to 60 kelvins.

First claim

The invention claimed is:

1. Multilayer product comprising
at least one layer of an acrylate-based foam carrier (S); and
a multiphase polymer composition (P) applied to this layer;
the multiphase polymer composition (P) comprising:
a comb copolymer (A) obtained by polymerization of at least one (meth)acrylate monomer in the presence of at least one macromer selected from the group consisting of polymerizable ethylene-butylene, ethylene-propylene, ethylene-butylene-propylene and isobutylene macromers, and which forms a continuous acrylate phase and a discontinuous hydrocarbon phase Kw;
a hydrocarbon component (B) which is soluble in the hydrocarbon phase Kw of the comb copolymer (A) and comprises at least one plasticizer resin and at least one solid resin;

the multiphase polymer composition (P) having a continuous acrylate phase with a static glass transition temperature Tg(Ac), measured by the DSC method, and a discontinuous hydrocarbon phase Kw 1 , comprising the hydrocarbon component (B) and having a static glass transition temperature Tg(Kw 1 ), measured by the DSC method, where Tg(Kw 1 ) is higher than Tg(Ac) by 35 to 60 kelvins.

2. Multilayer product according to claim 1 , wherein the acrylate-based foam carrier (S) is a viscoelastic foam carrier.

3. Multilayer product according to claim 1 , wherein, the acrylate forming the layer of the foam carrier (S) is a polyacrylate obtained by free or controlled radical polymerization of one or more acrylates and alkyl acrylates.

4. Multilayer product according to claim 1 , wherein, the acrylate forming the layer of the foam carrier (S) is a crosslinked polyacrylate.

5. Multilayer product according to claim 1 , wherein, the acrylate forming the layer of the foam carrier (S) is a polyacrylate obtained by polymerization of monomers consisting of monomers of the following groups (a1) to (a3):
(a1) 70 to 100 wt % of acrylic esters and/or methacrylic esters and/or a free acid as per structural formula (I):

where R 1 is H or CH 3 and R 2 represents H or C 1 -C 14 alkyl;
(a2) 0 to 30 wt % of olefinically unsaturated monomers which are copolymerizable with the monomers of group (a1) and have at least one functional group; and
(a3) optionally further acrylates and/or methacrylates and/or olefinically unsaturated monomers, which are copolymerizable with the monomers of group (a1) and have at least one functional group which leads by means of a coupling reagent to covalent crosslinking.

6. Multilayer product according to claim 5 , wherein the monomers of group (a1) are selected from the group consisting of methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, n-pentyl acrylate, n-hexyl acrylate, n-hexyl methacrylate, n-heptyl acrylate, n-octyl acrylate, n-nonyl acrylate, lauryl acrylate, stearyl acrylate, stearyl methacrylate, behenyl acrylate and their branched isomers and mixtures thereof;
and/or the monomers of group (a2) are selected from the group consisting of maleic anhydride, itaconic anhydride, glycidyl methacrylate, benzyl acrylate, benzyl methacrylate, phenyl acrylate, phenyl methacrylate, tert-butylphenyl acrylate, tert-butylphenyl methacrylate, phenoxyethyl acrylate, phenoxyethyl methacrylate, 2-butoxyethyl methacrylate, 2-butoxyethyl acrylate, dimethylaminoethyl methacrylate, dimethylaminoethyl acrylate, diethylaminoethyl methacrylate, diethylaminoethyl acrylate, tetrahydrofurfuryl acrylate, and mixtures thereof;
and/or the monomers of group (a3) are selected from the group consisting of hydroxyethyl acrylate, 3-hydroxypropyl acrylate, hydroxyethyl methacrylate, 3-hydroxypropyl methacrylate, 4-hydroxybutyl acrylate, 4-hydroxybutyl methacrylate, allyl alcohol, itaconic acid, acrylamide and cyanoethyl methacrylate, cyanoethyl acrylate, 6-hydroxyhexyl methacrylate, N-tert-butylacrylamide, N-methylolmethacrylamide, N-(butoxymethyl)methacrylamide, N-methylolacrylamide, N-(ethoxymethyl)acrylamide, N-isopropylacrylamide, vinylacetic acid, β-acryloyloxypropionic acid, trichloroacrylic acid, fumaric acid, crotonic acid, aconitic acid, dimethylacrylic acid, 4-vinylbenzoic acid, and mixtures thereof.

7. Multilayer product according to claim 1 , wherein, the multilayer product is an adhesive tape; and/or the layer of the foam carrier (S) is foamed through use of microballoons.

8. Multilayer product according to claim 1 , wherein, the static glass transition temperature of the discontinuous hydrocarbon phase within the polymer composition (P), Tg(Kw 1 ), is in a range from −5 to +15° C., and/or the static glass transition temperature of the continuous acrylate phase within the polymer composition (P), Tg(Ac), is below −10° C.

9. Multilayer product according to claim 1 , wherein, the fraction of the comb copolymer (A) makes up 30-64 weight percent, based on the total weight of the comb copolymer (A) and of the at least one hydrocarbon component (B) within the polymer composition (P); and/or the macromer units within the comb copolymer (A) make up 5-25 weight percent, based on the total weight of the comb copolymer (A).

10. Multilayer product according to claim 1 , wherein, the at least one (meth)acrylate monomer which can be used for preparing the comb copolymer (A) comprises at least one monomer selected from the group consisting of acrylic acid, methacrylic acid, 2-ethylhexyl acrylate, methyl acrylate, butyl acrylate, isobornyl acrylate, stearyl acrylate, isostearyl acrylate, amyl acrylate, isooctyl acrylate, decyl acrylate, hydroxyethyl acrylate, hydroxyethyl methacrylate and 4-hydroxybutyl acrylate, preferably from the group consisting of acrylic acid, methacrylic acid, 2-ethylhexyl acrylate, methyl acrylate, butyl acrylate, isobornyl acrylate, stearyl acrylate, isostearyl acrylate, amyl acrylate, isooctyl acrylate and decyl acrylate.

11. Multilayer product according to claim 1 , wherein, the polymerization of the at least one (meth)acrylate monomer which can be used for preparing the comb copolymer (A) is carried out in the presence of at least one further copolymerizable monomer, this at least one further copolymerizable monomer being selected from the group consisting of itaconic acid, itaconic anhydride, maleic acid, maleic anhydride, vinyl acetate, vinyl butyrate, vinyl propionate, vinyl isobutyrate, vinyl valerate, vinyl versatates, N-vinylpyrrolidone and N-vinylcaprolactam.

12. Multilayer product according to claim 1 , wherein, the plasticizer resin and the solid resin of the hydrocarbon component (B) have a number-average molecular weight Mn of 1000 g/mol or less, measured by the GPC method.

13. Multilayer product according to claim 12 , wherein the polymer composition (P) further comprises a further hydrocarbon compound (C), whose number-average molecular weight Mn, measured by the GPC method, is more than 1000 g/mol, and the polymer composition optionally has a static glass transition temperature Tg(C) which lies between the glass transition temperatures of the continuous acrylate phase, Tg(Ac), and of the discontinuous hydrocarbon phase, Tg(Kw 1 ).

14. Multilayer product according to claim 1 , wherein, the polymer composition (P) is a pressure-sensitive adhesive; and/or the multiphase polymer composition (P) applied to the layer of the foam carrier (S) is applied in the form of a layer having a weight per unit area of 40 to 100 g/m 2 .

15. Method for producing a multilayer product according to claim 1 , comprising the steps of:
(i) providing a

Assignees

• Tesa Se

Inventors

• Papenbroock Marten
• Prenzel Alexander

Classifications

• C08F279/02

  on to polymers of conjugated dienes · CPC title

• C09J7/38 Primary

  Pressure-sensitive adhesives [PSA] · CPC title

• C09J7/26

  Porous or cellular plastics · CPC title

• C09J133/06

  of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical · CPC title

• C09J2433/006

  in the substrate · CPC title