Methods and systems for treating spent caustic and regenerating media

Patent metadata

Field	Value
Publication number	US-10053375-B2
Application number	US-201314436918-A
Country	US
Kind code	B2
Filing date	Oct 22, 2013
Priority date	Oct 26, 2012
Publication date	Aug 21, 2018
Grant date	Aug 21, 2018

Abstract

Methods and systems for applying separation processes to a spent caustic stream are disclosed. Methods and systems for regenerating media utilized in spent caustic separation processes are disclosed.

First claim

What is claimed is:

1. A method for treating a spent caustic stream from a petrochemical or petroleum refinery process and regenerating adsorbent media, the method comprising:
during a spent caustic treatment stage, mixing a first portion of the spent caustic stream with an acid to provide a mixed stream with a reduced pH;
introducing the mixed stream to a separator or separation zone to separate the mixed stream into a bottoms layer, a brine layer, and an oils layer;
separating out the bottoms layer and the oils layer and directing the brine layer from the separator or separation zone, the brine layer being an acidified stream;
introducing the acidified stream to a first inlet of a first vessel comprising adsorbent media and passing the acidified stream through said first vessel so as to remove organic species and other contaminants from said acidified stream to produce a polished stream exiting the first vessel; and
during a regeneration stage, introducing a second portion of the spent caustic stream to a second inlet of the first vessel to regenerate the adsorbent media in the first vessel;
wherein the mixing of the first portion of the spent caustic stream with an acid comprises reducing the pH to a range of about 1 to about 3.

2. The method of claim 1 , further comprising introducing the acidified stream to an inlet of a walnut shell filter apparatus prior to introducing the acidified stream to the first inlet of the first vessel comprising adsorbent media.

3. The method of claim 2 , further comprising:
introducing at least one of a third portion of the spent caustic stream, a portion of the acidified stream, and a portion of the polished stream to a second inlet of the walnut shell filter apparatus; and
backwashing the walnut shell filter apparatus with at least one of the third portion of the spent caustic stream, the portion of the acidified stream, and the portion of the polished stream.

4. The method of claim 1 , further comprising ceasing introduction of the acidified stream to the first inlet of the first vessel prior to introducing the second portion of the spent caustic stream to the second inlet of the first vessel.

5. The method of claim 4 , further comprising introducing the acidified stream to a first inlet of a second vessel comprising the adsorbent media, wherein introducing the acidified stream to the second vessel and introducing the second portion of the spent caustic stream to the first inlet of the first vessel occur simultaneously.

6. The method of claim 5 , further comprising introducing the second portion of the spent caustic stream to a second inlet of the second vessel to regenerate the adsorbent media in the second vessel, wherein introducing the second portion of the spent caustic stream to the second vessel and introducing the acidified stream to the first vessel occur simultaneously.

7. The method of claim 1 , wherein introducing the acidified stream to a first inlet of a first vessel comprises passing the acidified stream through the first vessel comprising adsorbent media at a flow rate in a range of about 1 m 3 /hr to about 4 m 3 /hr.

8. The method of claim 1 , wherein the adsorbent media comprise at least one of granular activated carbon and a polymeric adsorbent.

9. The method of claim 1 , wherein a chemical oxygen demand of the spent caustic stream is from about 15 g/L to about 500 g/L.

10. The method of claim 1 , wherein introducing the portion of the spent caustic stream to the second inlet of the first vessel to regenerate the adsorbent media in the first vessel comprises regenerating the adsorbent media to at least 80% of a virgin adsorption capacity of the adsorbent media.

Assignees

• Siemens Energy Inc

Inventors

• Kumfer Bryan J
• Larson Andrea J
• Felch Chad L
• Clark Mark

Classifications

• C10G19/08

  Recovery of used refining agents · CPC title

• C02F2209/08

  Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD] · CPC title

• C02F1/285

  using synthetic organic sorbents · CPC title

• C02F2101/345

  Phenols · CPC title

• C10G25/12

  Recovery of used adsorbent · CPC title