3D multi-stage method

Patent metadata

Field	Value
Publication number	US-10052682-B2
Application number	US-201314435269-A
Country	US
Kind code	B2
Filing date	Oct 10, 2013
Priority date	Oct 12, 2012
Publication date	Aug 21, 2018
Grant date	Aug 21, 2018

Abstract

The present invention relates to a multi-stage method for producing one or multiple molded bodies, the method comprising the following steps: a) constructing one or multiple molded bodies in layers by repeatedly applying particulate material by the 3D printing method; b. a presolidification step for achieving a presolidification of the molded body; c. an unpacking step, wherein the unsolidified particulate material is separated from the presolidified molded body; d. a final solidification step, in which the molded body receives its final strength due to the action of thermal energy. The invention also relates to a device which may be used for this method.

First claim

What is claimed is:

1. A method for producing one or multiple molded bodies, wherein the method comprises the following steps:
a. constructing one or multiple molded bodies in layers by repeatedly applying particulate material including a casing or coating and selectively printing a fluid including a solvent on the particulate material, wherein the casing or coating includes a soluble polymer;
b. a pre-solidification step for achieving a pre-solidification of the molded body, wherein the pre-solidification step includes forming a bridge between two adjacent particles of the particulate material by liquefying the soluble polymer with the solvent and then solidifying by removing the solvent from the bridge;
c. an unpacking step, wherein the unsolidified particulate material is separated from the pre-solidified molded body; and
d. a final solidification step, after the unpacking step, in which the pre-solidified molded body receives its final strength due to the action of thermal energy;
wherein the action of thermal energy includes a chemical mechanism.

2. The method according to claim 1 , wherein the final solidification step includes heating to a temperature from 110° C. to 200° C.

3. The method according to claim 2 , wherein the the casing or coating includes a binder.

4. The method according to claim 2 , wherein the casing or coating comprises or includes thermoplastic polymers, soluble polymers, waxes, synthetic and natural resins, sugars, salts, inorganic network formers or water glasses.

5. The method according to claim 1 , wherein the pre-solidification step takes place using a solvent comprising water, hydrocarbons, alcohols, esters, ethers, ketones, aldehydes, acetates, succinates, monomers, formaldehyde, phenol and mixtures thereof.

6. The method according to claim 3 , wherein the binder contains polymerizable monomers.

7. The method according to claim 2 , wherein the pre-solidified molded body has a flexural strength of more than 120 N/cm 2 and the molded body has a flexural strength of more than 250 N/cm 2 after the final solidification step;
wherein the material contained in the casing or coating contributes to the final strength or to the preliminary strength in the pre-solidification step and to the final strength in the final solidification step.

8. The method of claim 1 , wherein the molded body is subjected to one or multiple additional processing steps;
the molded body is solidified in the pre-solidification step to the extent that an unpacking from the unsolidified particulate material is possible, and the molded body essentially retains its shape defined in the 3D printing method;
the unpacking takes place manually or mechanically or in a robot-assisted manner;
the pre-solidified molded body (green body) has a flexural strength of more than 120 N/cm 2 following the pre-solidification step;
the molded body has a flexural strength of more than 250 N/cm 2 after the final solidification step;
the pre-solidification step takes place without the introduction of additional thermal energy;
the pre-solidification step takes place using a solvent and/or a polymerization reaction;
the final solidification step takes place with the aid of heat treatment; and
the body is heat-treated with the assistance of an inert material.

9. The method of claim 8 , wherein the presolidified molded body (green body) has a flexural strength of 120 to 400 N/cm 2 following the presolidification step; and the molded body has a flexural strength of more than 750 N/cm 2 after the final solidification step.

10. The method of claim 1 , wherein a temperature in the final solidification step is from 130° C. to 200° C.

11. The method of claim 2 , wherein the temperature at the component is maintained within a time range of 2 to 24 hours.

12. The method of claim 11 , wherein natural silica sand, kerphalite, cera beads, zircon sand, chromite sand, olivine sand, chamotte, corundum or glass spheres are used as the particulate material.

13. The method of claim 6 , wherein the coating or casing contains materials for starting a polymerization with the binder.

14. The method of claim 8 , wherein the casing or coating includes one or multiple materials;
the casing or coating includes a binder;
the casing or coating comprises or includes thermoplastic polymers, soluble polymers, waxes, synthetic and natural resins, sugars, salts, inorganic network formers or water glasses;
the pre-solidification step takes place using a solvent comprising water, hydrocarbons, alcohols, esters, ethers, ketones, aldehydes, acetates, succinates, monomers, formaldehyde, phenol and mixtures thereof;
the casing or coating contains materials for starting a polymerization with the binder;
the pre-solidified molded body has a flexural strength of more than 120 N/cm 2 and the molded body has a flexural strength of more than 250 N/cm 2 after the final solidification step;
the material contained in the casing or coating contributes to the final strength or to the preliminary strength in the pre-solidification step and to the final strength in the final solidification step; and
two different materials are contained in the casing or coating, the one material being essentially destined for the pre-solidification step and the other material essentially being destined for the final solidification step.

15. The method of claim 1 , wherein only the fluid including the solvent is printed on the particulate material.

16. A method for producing one or multiple molded bodies, wherein the method comprises the following steps:
a. constructing one or multiple molded bodies in layers by repeatedly applying particulate material by the 3D printing method;
b. a pre-solidification step for achieving a pre-solidification of the molded body;
c. an unpacking step, wherein the unsolidified particulate material is separated from the pre-solidified molded body; and
d. a final solidification step, in which the pre-solidified molded body receives its final strength due to the action of thermal energy;
wherein the particulate material includes a base material and a coating or casing; and
the coating or casing contains a color indicator which is activated by a binder.

17. The method of claim 16 , wherein the molded body is subjected to polishing, dyeing, or both.

18. A method for producing one or multiple molded bodies, wherein the method comprises the following steps:
a. constructing one or multiple molded bodies in layers by repeatedly applying particulate material by the 3D printing method;
b. a pre-solidification step for achieving a pre-solidification of the molded body;
c. an unpacking step, wherein the unsolidified particulate material is separated from the pre-solidified molded body;
d. a step of repacking the pre-solidified molded body in an inert material; and
e. a final solidification step, after the repacking step, in which the pre-solidified molded body receives its final strength due to the action of thermal energy while supported by the inert material;
wherein the particulate material includes a base material and a coating or casing having one or multiple materials for the pre-solidification step and for the final solidification step.

19. The method of claim 18 , wherein two different materials are contained in the casing or coating, the one material being essentially destined for the pre-solidification step and the other material essentially being destined for the final solidification step.

20. The method according to claim 19 , wherei

Assignees

• Voxeljet Ag

Inventors

• Ederer Ingo
• Günther Daniel

Classifications

• B22C1/22

  of resins or rosins · CPC title

• B29C64/171

  specially adapted for manufacturing multiple 3D objects · CPC title

• B29C64/165 Primary

  using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber · CPC title

• B22C9/02 Primary

  Sand moulds or like moulds for shaped castings · CPC title

• B22C1/18

  of inorganic agents {(B22C1/162 takes precedence)} · CPC title