Multilayer dental appliances and related methods and systems

Patent metadata

Field	Value
Publication number	US-10052176-B2
Application number	US-201715476622-A
Country	US
Kind code	B2
Filing date	Mar 31, 2017
Priority date	May 14, 2012
Publication date	Aug 21, 2018
Grant date	Aug 21, 2018

Abstract

A dental appliance for positioning a patient's teeth includes a removable orthodontic tooth positioning appliance having teeth receiving cavities shaped to directly receive at least some of the patient's teeth and apply a resilient positioning force to the patient's teeth. The appliance includes a hard polymer layer having a hard polymer layer elastic modulus disposed between a first soft polymer layer having a first soft polymer layer elastic modulus and a second soft polymer layer having a second soft polymer layer elastic modulus. The hard polymer layer elastic modulus is greater than each of the first soft polymer layer elastic modulus and the second soft polymer layer elastic modulus. At least one of the first soft polymer layer and the second soft polymer layer has a flexural modulus of greater than about 35,000 psi.

First claim

What is claimed is:

1. A removable orthodontic tooth positioning appliance having teeth receiving cavities shaped to directly receive at least some of a patient's teeth and apply a resilient positioning force to the patient's teeth, the appliance comprising:
a first soft outer polymer layer comprising a first soft polymeric material and a second soft outer polymer layer comprising a second soft polymeric material, each of the first and second soft polymer layers having a flexural modulus of greater than about 35,000 psi, a hardness of about 60 A to about 85 D, and a thickness in a range from 25 μm to 100 μm; and
a hard inner polymer layer comprising a co-polyester disposed between the first soft outer polymer layer and the second soft outer polymer layer so as to reduce degradation of the resilient positioning force applied to the teeth when the appliance is worn.

2. The appliance of claim 1 , wherein:
the first soft polymeric material comprises a material selected from: a thermoplastic polyurethane elastomer, a silicone rubber, an elastomeric alloy, a thermoplastic elastomer (TPE), a thermoplastic vulcanizate (TPV) elastomer, a block copolymer elastomer, a polyolefin blend elastomer, a thermoplastic co-polyester elastomer, a thermoplastic polyamide elastomer, or a combination thereof; and
the second soft polymeric material comprises a material selected from: a thermoplastic polyurethane elastomer, a silicone rubber, an elastomeric alloy, a thermoplastic elastomer (TPE), a thermoplastic vulcanizate (TPV) elastomer, a block copolymer elastomer, a polyolefin blend elastomer, a thermoplastic co-polyester elastomer, a thermoplastic polyamide elastomer, or a combination thereof.

3. The appliance of claim 2 , wherein the first soft polymeric material and the second soft polymeric material are the same.

4. The appliance of claim 2 , wherein the first soft polymeric material and the second soft polymeric material are different.

5. The appliance of claim 2 , wherein the first and second soft polymeric materials each comprises a blend of polymeric materials, each respective blend including two or more materials selected from the group consisting of: a thermoplastic polyurethane elastomer, a silicone rubber, an elastomeric alloy, a thermoplastic elastomer (TPE), a thermoplastic vulcanizate (TPV) elastomer, a block copolymer elastomer, a polyolefin blend elastomer, a thermoplastic co-polyester elastomer, and a thermoplastic polyamide elastomer.

6. The appliance of claim 2 , wherein at least one of the first soft outer polymer layer and the second soft outer polymer layer comprises at least two layers.

7. The appliance of claim 1 , wherein the hard inner polymer layer comprises a blend of polymeric materials including the co-polyester and one or more of: a polyester, a thermoplastic polyurethane, a polypropylene, a polyethylene, a polypropylene and polyethylene copolymer, an acrylic, a polyetheretherketone, a polyamide, a polyethylene terephthalate, a polybutylene terephthalate, a polyetherimide, a cyclic block copolymer, a polyethersulfone, a polytrimethylene terephthalate, or a combination thereof.

8. The appliance of claim 1 , wherein the hard inner polymer layer comprises at least two layers including a first layer comprising the co-polyester and a second layer comprising one or more of: a polyester, a co-polyester, a thermoplastic polyurethane, a polypropylene, a polyethylene, an acrylic, a polyetheretherketone, a polyamide, a polyethylene terephthalate, a polybutylene terephthalate, a polyetherimide, a cyclic block copolymer, a polyethersulfone, or a polytrimethylene terephthalate.

9. The appliance of claim 1 , wherein the hard inner polymer layer has a thickness in a range from 400 μm to 1100 μm.

10. The appliance of claim 1 , wherein the hard inner polymer layer, the first soft outer polymer layer, and the second soft outer polymer layer combined have a thickness of 500 μm to 1200 μm.

11. The appliance of claim 1 , wherein the hard inner polymer layer comprises at least one of: a tensile strength at yield of between about 4000 pounds per square inch (psi) and 6500 psi, an elongation at yield of greater than about 4%, an elongation at break of greater than about 70%, a tensile modulus of greater than about 150,000 psi, a flexural modulus greater than about 150,000 psi, a stress relaxation of greater than about 10% at 24 hours testing in a high humidity environment, or a light transmission between 400 nm and 800 nm of greater than about 75%.

12. The appliance of claim 1 , wherein the first soft outer polymer layer and the second soft outer polymer layer each independently comprises at least one of: an ultimate tensile strength of greater than about 5000 psi, an elongation at break of greater than about 200%, a compression set at about 70° C. of greater than 40% after 24 hours, or a light transmission between 400 nm and 800 nm of greater than about 75%.

13. A plurality of incremental position adjustment appliances having teeth receiving cavities shaped to directly receive at least some of a patient's teeth and apply a resilient positioning force to the patient's teeth, wherein the appliances are shaped to move teeth from one arrangement to a successive arrangement when successively worn by the patient, and wherein at least one of the appliances comprises:
a first soft outer polymer layer comprising a first soft polymeric material and a second soft outer polymer layer comprising a second soft polymeric material, each of the first and second soft polymer layers having a flexural modulus of greater than about 35,000 psi, a hardness of about 60 A to about 85 D, and a thickness in a range from 25 μm to 100 μm; and
a hard inner polymer layer comprising a co-polyester disposed between the first soft outer polymer layer and the second soft outer polymer layer so as to reduce degradation of the resilient positioning force applied to the teeth when the appliance is worn.

14. The plurality of appliances of claim 13 , wherein
the first soft polymeric material comprises a material selected from: a thermoplastic polyurethane elastomer, a silicone rubber, an elastomeric alloy, a thermoplastic elastomer (TPE), a thermoplastic vulcanizate (TPV) elastomer, a block copolymer elastomer, a polyolefin blend elastomer, a thermoplastic co-polyester elastomer, a thermoplastic polyamide elastomer, or a combination thereof; and
the second soft polymeric material comprises a material selected from: a thermoplastic polyurethane elastomer, a silicone rubber, an elastomeric alloy, a thermoplastic elastomer (TPE), a thermoplastic vulcanizate (TPV) elastomer, a block copolymer elastomer, a polyolefin blend elastomer, a thermoplastic co-polyester elastomer, a thermoplastic polyamide elastomer, or a combination thereof.

15. A method of moving a patient's teeth from an initial configuration to a target configuration, the method comprising providing a removable orthodontic tooth positioning appliance having teeth receiving cavities shaped to directly receive at least some of a patient's teeth and apply a resilient positioning force to the patient's teeth, wherein providing the removable orthodontic tooth positioning appliance comprises placing the removable orthodontic tooth positioning appliance on the teeth of the patient, the appliance comprising:
a first soft outer polymer layer comprising a first soft polymeric material and a second soft outer polymer layer comprising a second soft polymeric material, each of the first and second soft polymer layers having a flexural modulus of greater than about 35,000 psi, a hardness of about 60 A to about 85 D, and a thickness in

Assignees

• Align Technology Inc

Inventors

• Li Chunhua
• Chen Yan
• Pudleiner Heinz
• Meyer Klaus
• Nickel Joerg
• Pehlert Craig

Classifications

• B32B2307/54

  Yield strength; Tensile strength · CPC title

• B32B7/02

  Physical, chemical or physicochemical properties · CPC title

• B32B2535/00

  Medical equipment, e.g. bandage, prostheses or catheter · CPC title

• A61C7/08 Primary

  Mouthpiece-type retainers {or positioners, e.g. for both the lower and upper arch (arch-shaped medicament applicators for teeth or gums A61C19/063; mouthguards for protecting the teeth of sportsmen A63B71/085)} · CPC title

• B32B2307/546

  Flexural strength; Flexion stiffness · CPC title