Negative electrode active material for non-aqueous electolyte secondary battery and method of producing the same

Patent metadata

Field	Value
Publication number	US-10050272-B2
Application number	US-201415104089-A
Country	US
Kind code	B2
Filing date	Dec 2, 2014
Priority date	Dec 25, 2013
Publication date	Aug 14, 2018
Grant date	Aug 14, 2018

Abstract

A negative electrode active material for a non-aqueous electrolyte secondary battery, wherein the negative electrode active material is represented by an elemental composition formula of Met 1 -Si—O—C—H (wherein Met 1 represents one alkali metal element or a mixture of alkali metal elements), including: a silicate salt made of a silicon-based inorganic compound and the alkali metal, and fine particles composed of silicon, silicon alloy, or silicon oxide being dispersed in the silicate salt; and a negative electrode active material for a non-aqueous electrolyte secondary battery, wherein the negative electrode active material is represented by an elemental composition formula of Met 2 -Si—O—C—H (wherein Met 2 represents one alkaline earth metal element or a mixture of alkaline earth metal elements), including: a silicate salt made of a silicon-based inorganic compound and the alkaline earth metal.

First claim

The invention claimed is:

1. A negative electrode active material for a non-aqueous electrolyte secondary battery, wherein the negative electrode active material is represented by an elemental composition formula of Met 1 -Si—O—C—H (wherein Met 1 represents one alkali metal element or a mixture of alkali metal elements), comprising:
a silicate salt made of a silicon-based inorganic compound and the alkali metal, and
fine particles composed of silicon, silicon alloy, or silicon oxide being dispersed in the silicate salt.

2. The negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the alkali metal element is Li or Na.

3. A negative electrode active material for a non-aqueous electrolyte secondary battery, wherein the negative electrode active material is represented by an elemental composition formula of Met 2 -Si—O—C—H (wherein Met 2 represents one alkaline earth metal element or a mixture of alkaline earth metal elements), comprising:
a silicate salt made of a silicon-based inorganic compound and the alkaline earth metal.

4. The negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 3 , wherein the alkaline earth metal element is Mg or Ca.

5. The negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 3 , further comprising fine particles composed of silicon, silicon alloy, or silicon oxide being dispersed in the silicate salt.

6. The negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the silicate salt further contains group 3 to group 13 metal.

7. The negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 3 , wherein the silicate salt further contains group 3 to group 13 metal.

8. The negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 6 , wherein the group 3 to group 13 metal is first row transition metal or second row transition metal.

9. The negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 7 , wherein the group 3 to group 13 metal is first row transition metal or second row transition metal.

10. The negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein carbon particles are dispersed in the silicate salt.

11. The negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 3 , wherein carbon particles are dispersed in the silicate salt.

12. A negative electrode for a non-aqueous electrolyte secondary battery, comprising the negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 .

13. A negative electrode for a non-aqueous electrolyte secondary battery, comprising the negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 3 .

14. A non-aqueous electrolyte secondary battery, comprising the negative electrode for a non-aqueous electrolyte secondary battery according to claim 12 .

15. A non-aqueous electrolyte secondary battery, comprising the negative electrode for a non-aqueous electrolyte secondary battery according to claim 13 .

16. A method of producing a negative electrode active material for a non-aqueous electrolyte secondary battery, comprising the steps of:
mixing a compound of alkali metal, a composition containing a curable organic silicon compound, and fine particles composed of silicon, silicon alloy, or silicon oxide to form a raw material mixture;
curing the curable organic silicon compound to cure the raw material mixture; and
baking the cured raw material mixture to make the curable organic silicon compound to be inorganic material.

17. A method of producing a negative electrode active material for a non-aqueous electrolyte secondary battery, comprising the steps of:
mixing a compound of alkaline earth metal, a composition containing a curable organic silicon compound to form a raw material mixture;
curing the curable organic silicon compound to cure the raw material mixture; and
baking the cured raw material mixture to make the curable organic silicon compound to be inorganic material.

18. The method of producing a negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 17 , wherein the raw material mixture is further mixed with fine particles composed of silicon, silicon alloy, or silicon oxide.

19. The method of producing a negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 16 , wherein the raw material mixture is further mixed with a compound of group 3 to group 13 metal.

20. The method of producing a negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 17 , wherein the raw material mixture is further mixed with a compound of group 3 to group 13 metal.

21. The method of producing a negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 16 , wherein the raw material mixture is further mixed with carbon particles.

22. The method of producing a negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 17 , wherein the raw material mixture is further mixed with carbon particles.

23. The method of producing a negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 21 , wherein the carbon particles are composed of any of natural graphite, synthetic graphite, and carbon fiber.

24. The method of producing a negative electrode active material for a non-aqueous electrolyte secondary battery according to claim 22 , wherein the carbon particles are composed of any of natural graphite, synthetic graphite, and carbon fiber.

Assignees

• Shinetsu Chemical Co

Inventors

• Nakanishi Tetsuo
• Taniguchi Kazuyuki
• Aoki Yoshitaka
• Yamada Yoshiyasu

Classifications

• H01M4/483

  for non-aqueous cells (H01M4/485 takes precedence) · CPC title

• H01M4/5825 Primary

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title