Activated carbon for electrode of power storage device and method for manufacturing activated carbon for electrode of power storage device

Patent metadata

Field	Value
Publication number	US-10049824-B2
Application number	US-201314384279-A
Country	US
Kind code	B2
Filing date	Feb 22, 2013
Priority date	Mar 23, 2012
Publication date	Aug 14, 2018
Grant date	Aug 14, 2018

Abstract

An activated carbon for an electrode of a power storage device of the present invention has uniform consecutive macropores, and a pore size distribution centered within a range of 1.5 to 25 μm, a specific surface area within a range of 1,500 to 2,300 m2/g, a micropore volume within a range of 0.4 to 1.0 mL/g, and an average micropore width within a range of 0.7 to 1.2 nm. Provided is an activated carbon for an electrode of a power storage device suitable for an electric double layer capacitor that has high capacitance during charging and discharging at high current density and excellent endurance against charging at a high voltage of 3 V or more and a lithium-ion capacitor having excellent endurance against charging at a high voltage of 4 V or more.

First claim

The invention claimed is:

1. An activated carbon for an electrode of a power storage device having
uniform consecutive macropores and a pore size distribution centered within a range of 1.5 to 25 μm,
a specific surface area within a range of 1,500 to 2,300 m 2 /g,
a micropore volume within a range of 0.6 to 0.93 mL/g, and
an average micropore width within a range of 0.7 to 1.2 nm.

2. A method for manufacturing an activated carbon for an electrode of a power storage device comprising:
adding and mixing a pore forming agent and a cross-linker in an aqueous solution prepared by mixing a phenolic resin and polyvinyl alcohol,
adding and mixing a catalyst for curing this mixed solution in the mixed solution, adding and mixing water in the mixture to obtain a reaction solution, injecting the reaction solution into a block-shaped mold made of a synthetic resin, heating the reaction solution to cause a reaction for a predetermined time, taking the resulting reaction product from the mold, washing the reaction product with water to remove the pore forming agent and the unreacted substance, drying the reaction product, to obtain a block of porous phenolic resin in which uniform consecutive macropores with an average pore size within a range of 3 to 35 μm are formed in a three-dimensional network form,
cutting the block of the porous phenolic resin into a plate shape,
heating the cut plate-shaped body in an inert gas atmosphere from room temperature to a range of 800 to 900° C., and holding the plate-shaped body in the inert gas atmosphere at the increased temperature, resulting in a carbonization treatment, to obtain a plate-shaped carbonized material, and
carrying out an activation treatment of the plate-shaped carbonized material so that the activation yield falls within a range of 40 to 70% and a micropore volume within a range of 0.6 to 0.93 mL/g, to obtain a plate-shaped activated carbon.

3. The method for manufacturing an activated carbon for an electrode of a power storage device according to claim 2 , wherein the activation treatment is carried out by
heating the plate-shaped carbonized material in an inert gas atmosphere from room temperature to a range of 800 to 900° C., and
holding the material under passing of carbon dioxide at the increased temperature.

4. An electric double layer capacitor using the activated carbon according to claim 1 for an electrode.

5. A lithium-ion capacitor using the activated carbon according to claim 1 for an electrode.

6. An electric double layer capacitor using the activated carbon manufactured by the method according to claim 2 for an electrode.

7. A lithium-ion capacitor using the activated carbon manufactured by the method according to claim 2 for an electrode.

Assignees

• Aion Co Ltd
• Univ Gunma Nat Univ Corp

Inventors

• Tsukada Hidehiko
• Onda Kimiyasu
• Miyaji Hiroshi
• Shiraishi Soshi
• Endo Yukiko

Classifications

• H01G11/06

  with one of the electrodes allowing ions to be reversibly doped thereinto, e.g. lithium ion capacitors [LIC] · CPC title

• C01B32/366

  by physical processes, e.g. by irradiation, by using electric current passing through carbonaceous feedstock or by using recyclable inert heating bodies · CPC title

• C01B32/336 Primary

  characterised by gaseous activating agents · CPC title

• C01B32/312

  Preparation · CPC title

• H01G11/24

  characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor · CPC title